• Journal of the Korean Magnetics Society
• /
• v.24 no.1
• /
• pp.18-21
• /
• 2014

The microwave absorption ($P_{tot}$), which is the double integration value of ferromagnetic resonance signal, propositional to the saturation magnetization, and the increase of the $P_{tot}$ measured during the thermal reaction time expect the growth process of the nanoparticles. Therefore, in this work, we measured the $P_{tot}$ in order to obtain the growth time of iron oxide nanoparticles after thermal decomposition of $Fe(acac)_3$ precursor at aging temperature $T_a=273$, 300 and $324^{\circ}C$, respectively. The best condition for monodisperse nanoparticles was obtained at $T_a=300^{\circ}C$, which condition showed the most rapid increase of $P_{tot}$ with thermal reaction time. Finally, the rapid growth rate was necessary condition for the synthesis of iron-oxide monodisperse nanoparticles.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
• /
• v.16 no.5
• /
• pp.223-229
• /
• 2023

This Paper propose the method that measure main system parameters for PI(proportional-integral) current control of a.c. motor adopting the vector control technique. For current control, the PI control input is could be tuning by several selective methods. Among the several methods, the method that using the main system parameters, wire resistance and inductance, are frequently used. In this study, the technique to dissect and measure these two system parameters through the results of simple feedback control. This analytic measurement method is measuring parameters step by step dissecting the results of P control using simple proportional feedback gain about the unit step or multiple step reference command. This strategy is an real time analytic measurement method that calculate current control gains of torque component and flux component both for vector control of A.C. motor without introducing the further measurement circuits and complex measuring algorithms.

• Journal of Bio-Environment Control
• /
• v.8 no.3
• /
• pp.152-163
• /
• 1999

It is required to analyze the controlled response of air temperature in greenhouse according to control techniques for precise control. In this study, a mathematical model was established for air heating of greenhouse with hot-water heating system The parameters of the model were decided by regression analysis using reference data measured at the greenhouse being heated In the simulation for the digital control of air temperature in the greenhouse, the mathematical model to evaluate the control performances was used. Tested control methods were ON-OFF contpol, p control, rl control and PID control. The mathematical model represented by inside air temperature ( T$_{i}$), hot-water temperature (T$_{w}$) in heating pipe and outside air temperature (T$_{o}$) was expressed as a following discrete time equation ; T$_{i}$($textsc{k}$＋1)＝ 0.851.T$_{i}$($textsc{k}$)＋0.055.T$_{w}$($textsc{k}$)＋0.094.T$_{o}$($textsc{k}$) Control simulations for various control methods showed the settling time, the overshoot and the steady state nor as follows; infinite time, 3.5$0^{\circ}C$, 3.5$0^{\circ}C$ for ON-OFF control : 30min 2.37$^{\circ}C$, 0.51$^{\circ}C$ for P control; 21min, 0.0$0^{\circ}C$, 0.23$^{\circ}C$ for PI control; 18min 0.0$0^{\circ}C$, 0.23$^{\circ}C$ for PID control, respectively. PI and PID controls appeared to be optimal control methods. There was no effect of differential gain on the heating process but much effect of integral gain on it.on it.

• Microbiology and Biotechnology Letters
• /
• v.7 no.3
• /
• pp.141-147
• /
• 1979

Naringinase from Atpergillus nidulans was immobillized on DEAE-Sephadex A-25 and its characteristics were studied. The optimal conditions for the preparation of the immobilized enzyme were as follow; optimal pH, incubation time and the suitable amount of enzyme were 6.0, 30 min. and 110 units per gram of the dried ion exchage resin, respectively. The optimal pH of the immobilized enzyme was higher than that of the native enzyme. The optimal temperature increased from 4$0^{\circ}C$ to 5$0^{\circ}C$. The heat and pH stability of the immobillized enzyme were better than those of the native enzyme. No significant difference in the Michaelis constant was detected. Activation energy of the immobilized enzyme was 7.96 Kcal/mole, and the apparent Michaelis rate equation was used to describe the action of this material. The degree of hydrolysis was dependant on the flow rate at low rate of perfusion through the column. As the flow rate increased, the value of the apparent Km decreased.

• Transactions of the KSME C: Technology and Education
• /
• v.3 no.3
• /
• pp.183-191
• /
• 2015

In this study, the finite element analysis was carried out to investigate dynamic characteristics of the AGF(Active Gurney Flap) which is under development for reducing vibration and noise of the helicopter rotor system. The Gurney flap is a kind of small flat plate, mounted normal to the lower surface of the airfoil near to the trailing edge. An electric motor, L-shaped linkages and flap parts were integrated into a rotor bade, and 3~5/rev control was given to the AGF to reduce the vibration in the fixed frame. Thus, an explicit time integration method was adopted to investigate the dynamic response of the AGF with considering both centrifugal force due to the rotor rotation and active control input, and it can be seen that the vertical displacement of the AGF was satisfied to meet the design requirement.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.9 no.5
• /
• pp.539-547
• /
• 1985

The low-cycle fatigue crack growth behavior of SUS 304 Stainless steel was investigated at 650.deg. C by the nonlinear fracture mechanics. Crack Propagation can be separated in to cycle-dependent and time-dependent, the former is correlated with .DELTA. $J_{f}$ , J-intergral range and the latter is correlated with J', modified J integral. Transition from cycle-dependent to time-dependent crack growth was successfully predicted using the .betha. hypothesis, which was proposed by the authors on the basis of an analysis on the interaction of elastic and creep strain. To investigate the reliability of .betha.-hypothesis, experimenting by the change of stress-level, stress rate and frequency, following conclusions were obtained. (1) High temperature fatigue crack propagation was separated into cycle-dependent and time-dependent. (2) Transition of crack propagation was predicted by .DELTA. $J_{c}$/.DELTA.$_{f}$ or .betha. (3) Lower limit in cycle-dependent crack propagation was obtained..

• Journal of Korea Water Resources Association
• /
• v.32 no.6
• /
• pp.731-740
• /
• 1999

Autocorrelation function is widely used as a tool measuring linear dependence of hydrologic time series. However, it may not be appropriate for choosing decorrelation time or delay time ${\tau}_d$ which is essential in nonlinear dynamics domain and the mutual information have recommended for measuring nonlinear dependence of time series. Furthermore, some researchers have suggested that one should not choose a fixed delay time ${\tau}_d$ but, rather, one should choose an appropriate value for the delay time window ${\tau}_d={\tau}(m-1)$, which is the total time spanned by the components of each embedded point for the analysis of chaotic dynamics. Unfortunately, the delay time window cannot be estimated using the autocorrelation function or the mutual information. Basically, the delay time window is the optimal time for independence of time series and the delay time is the first locally optimal time. In this study, we estimate general dependence of hydrologic time series using the C-C method which can estimate both the delay time and the delay time window and the results may give us whether hydrologic time series depends on its linear or nonlinear characteristics which are very important for modeling and forecasting of underlying system.

• Applied Chemistry for Engineering
• /
• v.7 no.5
• /
• pp.888-901
• /
• 1996

Oxidations of cyclopentene and of 1-pentene with air have been studied on a V/Mo/P/Al/Ti-mixed oxide catalyst in a fixed bed integral reactor. At high levels of conversion maleic anhydride was in each case produced as the major organic product, along with minor amounts of phthalic anhydride and, only starting from 1-pentene, also of citraconic anhydride. At lower levels of conversion a total of 30 organic products have been identified, some of which may be intermediates on the way from the substrates to the three anhydrides mentioned above. Based on the dependence of selectivities of the organic products on conversion, reaction schemes for the formation of maleic anhydride, phthalic anhydride and citraconic anhydride have been proposed. Oxidation at $310^{\circ}C$ led to increasing conversions and selectivities for maleic anhydride with decreasing space velocities. The highest selectivities for maleic anhydride were obtained at conversion of ca. 100%. Oxidation at a constant space velocity of $2{\cdot}10^4h^{-1}$ led to increasing conversions with increasing temperatures in the range of $300^{\circ}C{\sim}420^{\circ}C$, while the selectivity for maleic anhydride passed through a maximum value of ca. 39% at $370^{\circ}C$ in the oxidation of cyclopentene and a maximum value of ca. 30% at $400^{\circ}C$ in the oxidation of 1-pentene.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.134-135
• /
• 2011

양자점은 전자와 양공을 3차원으로 속박 시키므로 기존의 bulk나 양자우물보다 양자점을 이용한 레이저 다이오드의 경우 낮은 문턱 전류, 높은 미분이득 및 온도 안전성의 장점이 있을 거라 기대되고 있다. 그러나, 양자점은 낮은 areal coverage 때문에 높은 속박효율을 얻지 못하고 있다. 이러한 양자점의 문제점을 해결하기 위해 양자점을 양자우물 안에 성장시켜 운반자들의 포획을 향상시키는 방법들이 연구되고 있다. 양자우물 안에 양자점을 넣으면 양자우물이 운반자들의 포획을 증가 시키고, 열적 방출도 억제하여 온도 안정성이 향상 되는 것으로 알려져 있다. 광통신 대역의 1.3 ${\mu}m$ 경우, GaAs계를 이용하여 InAs 양자점을 strained InGaAs 박막을 우물층으로 한 dot-in-a-well 구조의 연구는 몇몇 보고된 바 있다. 그러나 InP계를 사용하는 1.55 ${\mu}m$ 대역에서 dot-in-a-well구조의 연구는 아직 미미하다. 본 연구에서는 유기 금속 화학 증착법(metal organic chemical vapor deposition)을 이용하여 InP 기판 위에 InAs 양자점을 자발성장법으로 성장하였으며 dot-in-a-well 구조에서 우물층으로 1.35 ${\mu}m$ 파장의 $In_{0.69}Ga_{0.31}As_{0.67}P_{0.33}$ (1.35Q)를, 장벽층으로는 1.1 ${\mu}m$ 파장의 $In_{0.85}Ga_{0.15}As_{0.32}P_{0.68}$(1.1Q)를 사용하였다. 양자우물층과 장벽층은 모두 InP 기판과 격자가 일치하는 조건으로 성장하였다. III족 원료로는 trimethylindium (TMI)와 trimethylgalium (TMGa)을 사용하였으며 V족 원료 가스로는 $PH_3$ 100%, $AsH_3$ 100%를, carrier gas로는 $H_2$를 사용하였다. InP buffer층의 성장 온도는 640$^{\circ}C$이며 양자점 성장 온도는 520$^{\circ}C$이다. 양자점 형성은 원자력간 현미경(Atomic force microscopy)를 이용하여 확인하였으며, 박막의 결정성은 쌍결정 회절분석(Double crystal x-ray deffractometry)를 이용하여 확인하였다. 확인된 성장 조건을 이용하여 양자점 시료를 성장하였으며 광여기분광법(Photoluminescence)을 이용하여 광특성을 분석하였다. Fig. 1은 dot in a barrier 와 dot-in-a-well 시료의 성장구조이다. Fig. 1(a)는 일반적인 dot-in-a-barrier 구조로 InP buffer층을 성장하고 1.1Q를 100 nm 성장한 후 양자점을 성장하였다. 그 후 1.1Q 100 nm와 InP 100 nm로 capping하였다. Fig. 1(b)는 dot-in-a-well 구조로 InP buffer층을 성장하고 1.1Q를 100 nm 성장 후 1.35Q 우물층을 4 nm 성장하였다. 그 위에 InAs 양자점을 성장하였다. 그 후에 1.35Q 우물층을 4 nm 성장하고 1.1Q 100 nm와 InP 100 nm로 capping하였다. Fig. 2는 dot-in-a-barrier 시료와 dot-in-a-well 시료의 상온 PL data이다. Dot-in-a-barrier 시료의 PL 파장은 1544 nm이며 반치폭은 79.70 meV이다. Dot-in-a-well 시료의 파장은 1546 nm이며 반치폭은 70.80 meV이다. 두 시료의 PL 파장 변화는 없으며, 반치폭은 dot-in-a-well 시료가 8.9 meV 감소하였다. Dot-in-a-well 시료의 PL peak 강도는 57% 증가하였으며 적분강도(integration intensity)는 45%가 증가하였다. PL 데이터에서 높은 에너지의 반치폭 변화는 없으며 낮은 에너지의 반치폭은 8 meV 감소하였다. 적분강도 증가에서 dot-in-a-well 구조가 dot-in-a-barrier 구조보다 전자-양공의 재결합이 증가한다는 것을 알 수 있으며, 반치폭 변화로부터 특히 높은 에너지를 갖는 작은 양자점에서의 재결합이 증가 된 것을 알 수 있다. 이는 양자우물이 장벽보다 전자-양공의 구속력을 증가시키기 때문에 양자점에 전자와 양공의 공급을 증가시키기 때문이다. 따라서 낮은 에너지를 가지는 양자점을 모두 채우고 높은 에너지를 가지는 양자점까지 채우게 되므로, 높은 에너지를 가지는 양자점에서의 전자-양공 재결합이 증가되었기 때문이다. 뿐만 아니라 파장 변화 없이 PL peak 강도와 적분강도가 증가하고 낮은 에너지 쪽의 반치폭이 감소한 것으로부터 에너지가 낮은 양자점보다는 에너지가 높은 양자점에서의 전자-양공 재결합율이 급증하였음을 알 수 있다. 우리는 이와 같은 연구에서 InP계를 이용해 1.55 ${\mu}m$에서도 dot in a well구조를 성장 하여 더 좋은 특성을 낼 수 있으며 앞으로 많은 연구가 필요할 것이라 생각한다.

• Elastomers and Composites
• /
• v.34 no.2
• /
• pp.135-146
• /
• 1999

The thermal degradation kinetics of SBR and tire were studied using a conventional thermogravimetric analysis in the stream nitrogen at a heating rate of 5, 10, 15, $20^{\circ}C/min$, respectively. Thermogravimetric curves and their derivatives were analyzed using various analytical methods to determine the kinetic parameters. The degradation of the SBR and tire was found to be a complex process which has multi-stages. The Friedman method gave average activation energies for the SBR and tire of 247.53kJ/mol and 230.00kJ/mol, respectively. Mean-while, the Ozawa method Eave 254.80kJ/mol and 215.76kJ/mol. It would appear that either. Friedman's differential method or Ozawa's integral method provided satisfactory mathematical approaches to determine the kinetic parameters for the degradation of the SBR and tire. Approximately 86% and 55% of oil products were obtained at a final temperature of $700^{\circ}C$ and a heating rate of $20^{\circ}C/min$ for the SBR and tire respectively.