• 제목/요약/키워드: $Bi_2Sr_2CaCu_2O_y$

검색결과 231건 처리시간 0.024초

BSCCO 초전도 전구체의 합성 (Fabrication of BSCCO High Tc Superconducting Precursor)

  • 이상헌
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.290-291
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_Y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h. the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factor in determining whether it is easy to form the high Tc phase or not. because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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열분해법에 의한 고온 초전도 합성 (Fabrication of High Tc Superconductor Using Thermal Pyrolysis)

  • 이상헌
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.85-86
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    • 2006
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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로울링법을 이용한 고온 초전도 다심선재 제조 (Fabrication of multi-layer $high-T_c$ superconducting tapes by a rolling process)

  • 김민기;허원일;최명호;한병성
    • E2M - 전기 전자와 첨단 소재
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    • 제9권6호
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    • pp.600-604
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    • 1996
  • High-T$_{c}$, superconducting wire is very important element for the application of electrical power systems. But it is very difficult to develope the long high T, wire with excellent properties. BiSrCaCuO multi-layer tapes are fabricated by a rolling method and pressing method sintered for several step at 840.deg. C. The critical current densities of 637 filament multi-layer tapes sintering 100 hours fabricated by the rolling method and pressing method are 1.3*10$^{4}$ A/cm$^{2}$ and 5.5*10$^{3}$ A/cm$^{2}$. The critical cur-rent densites of multi-layer tapes made by rolling method are found to be better than those fabricated by the powder-in-tube method and pressing process. As result, the rolling method is the best way to fabricated the multi-layer filament.t.

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Josephson plasma excitation in vortex states

  • Kadowaki, K.
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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    • pp.21-21
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    • 2000
  • The Josephson Plasma resonance in single crystalling Bi2Sr2CaCu2O8 has been investigated at a microwave frequency of 35 GHz in a cavity resonator. A sharp resonance is observed in a perpendicular oscillating magnetic field. The former is independent of the sample dimension, shile the latter shift to higher field as the sample size L is reduced, and it disappears when L becomes smaller than the critical length. The longitudinal plasma mode is a Nambu-Goldston mode in a superconductor, the experimental distinction between the longitudinal and the transverse mode leads to the conclusion that the existence of the Nambu-Goldston mod as predicted by Anderson was experimentally confirmed by direct observation of the Josephson plasma resonance with longitudinal excitations. The finite gap found in Josephson plasma resonance also provides a direct proof of the Anderson-Higgs mechanism within the context of the spontaneously broken phase symmetry of the Gauge-field theory in a superconductor.

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Fabrication Condition for Single Phase of BSCCO Thin Film

  • An, In-Soon;Chun, Min-Woo;Park, Yong-Pil
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.327-330
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    • 2001
  • Phase intergrowth in BSCCO thin films have been investigated. It turned out from XRD analyses of these phases that molar fraction of each constituent phase in the intergrowth thin film can be exhibited as a function of substrate temperature and ozone pressure. Superconducting behavior of the intergrowth thin film is also discussed.

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Enhanced Densification in Tl-1223/Ag Tapes Prepared Using Pretreated Precursors

  • 정대영;백상민;김봉준;김영철;박기곤
    • Progress in Superconductivity
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    • 제3권2호
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    • pp.198-212
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    • 2002
  • The effects of reacted precursors on phase evolution, microstructure, $J_{c}$ and junctional characteristic of the inter-granular contacts were investigated in Ag-sheathed T1-1223 tapes prepared using three kinds of reacted precursors, and compared to those in the tape prepared using an unreacted precursor The precursors were prepared by heat-treating a mixture of Sr-Ba-Ca-Cu-O, $Tl_2$$O_3$, PbO and $Bi_2$$O_3$ powders at $805^{\circ}C$ (precursor I ), $840^{\circ}C$ (precursor II ) and $905^{\circ}C$(precursor III) for 20 min. Tl-1223 phase content, grain size and J\ulcorner in the tapes appeared to increase in an order of precursors I, II and III Compared to tapes prepared using an unreacted precursor, the tapes prewar ed using precursors II and III revealed reduced pore and impurity densities and an enhanced texture. Also characteristic of inter -granular contacts and fraction of strong-links were improved. The improved properties are attributed to enhanced densification resulting from using the reacted precursors.s.

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(Na,K,Li)(Nb,Sb,Ta)O3계 세라믹스의 소성시간이 압전특성에 미치는 영향 (Effect of Sintering Time on the Piezoelectric Properties of (Na,K,Li)(Nb,Sb,Ta)O3 Ceramics)

  • 김승원;류주현
    • 한국전기전자재료학회논문지
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    • 제30권4호
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    • pp.218-222
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    • 2017
  • In this paper, in order to develop excellent composition ceramics for a piezoelectric energy- harvesting device, we synthesized $0.99(Na_{0.52}\;K_{0.443}\;Li_{0.037})(Nb_{0.883}\;Sb_{0.08}\;Ta_{0.037})O_3$ + $0.01(Sr_{0.95}Ca_{0.05})TiO_3$ + $0.3\;wt%\;Bi_2O_3\;+\;0.3\;wt%\;Fe_2O_3\;+\;0.3\;wt%\;CuO$ (abbreviated as NKN-SCT) ceramics with different sintering times, using the ordinary solid-state reaction method. The effect of sintering time on the microstructure and piezoelectric properties was investigated. The ceramics with the sintering time of 7 h have the optimum values of the piezoelectric constant ($d_{33}$), piezoelectric voltage constant ($g_{33}$), planar piezoelectric coupling coefficient (kp), mechanical quality factor (Qm), and dielectric constant (${\varepsilon}r$): $d_{33}=314[pC/N]$, $g_{33}=20.07[10^{-3}mV/N]$, kp = 0.442, Qm = 93, ${\varepsilon}r=1,768$, all being suitable for a piezoelectric energy-harvesting device.

Search for the preformed-pair state in the pseudogap regime above T$_c$ using c-axis tunneling in Bi$_2$Sr$_2$CaCu$_2$O$_{8+d}$ single crystals

  • Chang, Hyun-Sik;Lee, Hu-Jong;Oda, MigaKu;Jang, Eue-Soon;Ido, Masayuki;Choy, Jin-Ho
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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    • pp.85-85
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    • 2000
  • The normal state of high-Tc superconducting materials has been believed to contain important clues to finding the correct mechanism of the high-Tc superconductivity. One example is the existence of pseudogap in the normal state even above Tc, as observed in various measurements such as photoemission spectroscopy and tunneling conductance. In this pseudogap regime the existence of preformed pairs only with local phase coherence has been debated. Recently Choi, Bang, and Campbell[1] have proposed the occurrence of the zero-bias conductance enhancement due to Andreev quasiparticle reflection from the preformed pairs even with the local phase coherence. In this study we examine the zero-bias enhancement of the differential conductance near or slightly above Tc, using c-axis tunneling in mesa structure of Bi2Sr20a0u208+d single crystals. In slightly overdoped samples zero-bias conductance enhancement (ZBCE) has been observed over a range of 2 K above Tc. In contrast, in underdoped samples with Tc${\sim}$72K the ZBCE appears over a range of 5-6 K above Tc, a much wider temperature range than in overdoped samples. This result may pose as positive signs of the existence of prefurmed pairs in the normal state of high- Tc superconducting materials.

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BSCCO(2223) 초전도 선재의 접합공정 연구 (A Study of Joining Method of BSCCO(2223) Tape)

  • 김정호;김중석;김태우;지붕기;주진호;나완수
    • 한국초전도ㆍ저온공학회논문지
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    • 제1권2호
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    • pp.1-7
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    • 1999
  • we evaluated the effects of joining process such as contact method. shape of joined area and pressure on the electrical and mechanical properties of Bi-2223 superconducting tape, Specifically. the current capacity of the jointed tape was measured as a function of uniaxial pressure. and the thermal shock, bonding strength and the thermal of the tape were evaluated and correlated to the microstructural evolution. It was observed that the current capacity was significanrly dependent on the uniaxial pressure The jointed tape, fabricated with a pressure of 1,000-1,600 Mpa. showed the highest value of current capacity results from improvements in core density, contacting area and grain alignment, ect. In addition, the strength of jointed tape was measured to be 86 Mpa, which is about 88% of the unjoined ape's strength. The irreversible strain($\varepsilon$irrev) for the jointed tape was measured to be 0.1%, smaller than that of unjoined tape ($\varepsilon$irrev= 0.3%). The decrease in the strength and irreversible strain for jointed tape is believed to be due to the irregular geometry/morphology of the transition area of the tape.

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고온 초전도 선재의 장선화를 위한 접속에 관한 연구 (STUDY ABOUT A CONNECTIVE METHOD OF HIGH Tc SUPERCONDUCTING WIRE FOR LONG WIRE)

  • 임성훈;강형곤;이재윤;임성우;한병성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.222-224
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    • 1997
  • This study is about a connective method of High Tc wire for long wire. We prepared silver-sheathed BiPbSrCaCuO wires by the powder-in-tube method. Since the superconducting wires are ceramic, it is very hard to connect each other. In this study, we used a silver sleeve to contract wires and pressed them by various preasures. Then optimum preasure was 9,000 Kgf/$\textrm{cm}^2$ to get the high critical current. The higest critical current was 10A.

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