• 제목/요약/키워드: $BF_3$

검색결과 521건 처리시간 0.028초

기체 촉진수송을 위한 polyvinylpyrrolidone/AgBF4/Al(NO3)3 전해질 분리막 제조 (Preparation of Polyvinylpyrrolidone/AgBF4/Al(NO3)3 Electrolyte Membranes for Facilitated Gas Transport)

  • 윤기완;강상욱
    • 멤브레인
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    • 제26권1호
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    • pp.38-42
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    • 2016
  • 올레핀/파라핀 혼합 기체의 분리를 위한 올레핀 촉진 수송 분리막의 제조를 위해 amide 작용기를 가지며 glassy한 특성을 보이는 polyvinylpyrrolidone (PVP) 고분자를 분리막의 matrix로서 사용하였다. 분리막의 기체 투과 실험은 propylene과 propane 50 : 50의 부피비로 혼합된 기체를 사용하였고, bubble meter와 gas chromatography를 사용해 투과도와 선택도를 측정하였다. 또한 SEM image와 FT-IR을 통해 막의 특성을 조사하였다. 100시간의 장시간 성능 측정 결과 선택도는 약 15, 투과도는 약 1.3 GPU 이상을 각각 유지하였다. 기존의 poly(2-ethyl-2-oxazoline) $(POZ)/AgBF_4/Al(NO_3)_3$ 분리막과 비교함으로써, 고분자 matrix로서의 PVP 특성을 확인하였다.

이산화탄소 분리를 위한 이온성 액체 1-butyl-3-methylimidazolium tetrafluoroborate/Al2O3 복합체 분리막 (1-Butyl-3-methylimidazolium tetrafluoroborate/Al2O3 Composite Membrane for CO2 Separation)

  • 윤기완;강상욱
    • 멤브레인
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    • 제27권3호
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    • pp.226-231
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    • 2017
  • 이산화탄소 분리를 위해 이온성 액체/금속 산화물 복합막이 제조되었으며, 이온성 액체로서 1-butyl-3-methylimidazolium tetrafluoroborate ($BMIM^+BF_4{^-}$)와 금속산화물로서 $Al_2O_3$가 사용되었다. 13 nm의 $Al_2O_3$가 이온성 액체 $BMIM^+BF_4{^-}$에 도입되었을 때, 복합체 분리막의 성능은 $CO_2/N_2$ 선택도 30.5과 $CO_2$ 투과도 45.7 GPU로 관찰되었다. neat $BMIM^+BF_4{^-}$ 분리막의 성능($CO_2/N_2$ 선택도 5와 $CO_2$ 투과도 17 GPU)에 비해서 성능이 증가한 이유는 $Al_2O_3$의 옥사이드 층과 이온성 액체 내 자유로운 이온농도의 상승으로 인해 $CO_2$ 용해도가 상승한 것으로 확인되었다. 특히 $Al_2O_3$ 나노입자는 질소 기체에 대해서 장애물로서 작용함으로써 질소기체의 투과도가 감소하여 결과적으로 이산화탄소 분리 성능은 급격히 증가하였다.

Deletion of adipose triglyceride lipase abolishes blood flow increase after β3-adrenergic stimulation in visceral adipose tissue of mice

  • Lee, Hye-Jin;Jin, Bo-Yeong;Park, Mi-Rae;Seo, Kwan Sik;Jeong, Yong Taek;Choi, Sang-Hyun;Kim, Dong-Hoon
    • The Korean Journal of Physiology and Pharmacology
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    • 제25권4호
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    • pp.355-363
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    • 2021
  • Dynamic changes in adipose tissue blood flow (ATBF) with nutritional status play a role in the regulation of metabolic and endocrine functions. Activation of the sympathetic nervous system via β-adrenergic receptors (β-AR) contributes to the control of postprandial enhancement of ATBF. Herein, we sought to identify the role of each β-AR subtype in the regulation of ATBF in mice. We monitored the changes in visceral epididymal ATBF (VAT BF), induced by local infusion of dobutamine, salbutamol, and CL316,243 (a selective β1-, β2-, and β3-AR agonist, respectively) into VAT of lean CD-1 mice and global adipose triglyceride lipase (ATGL) knockout (KO) mice, using laser Doppler flowmetry. Administration of CL316,243, known to promote lipolysis in adipocytes, significantly increased VAT BF of CD-1 mice to a greater extent compared to that of the vehicle, whereas administration of dobutamine or salbutamol did not produce significant differences in VAT BF. The increase in VAT BF induced by β3-AR stimulation disappeared in ATGL KO mice as opposed to their wild-type (WT) littermates, implying a role of ATGL-mediated lipolysis in the regulation of VAT BF. Different vascular reactivities occurred despite no significant differences in vessel density and adiposity between the groups. Additionally, the expression levels of the angiogenesis-related genes were significantly higher in VAT of ATGL KO mice than in that of WT, implicating an association of ATBF responsiveness with angiogenic activity in VAT. Our findings suggest a potential role of β3-AR signaling in the regulation of VAT BF via ATGL-mediated lipolysis in mice.

탄소-수소 결합 활성을 이용한 1,5-헥사디엔의 하이드로아실화반응 연구 (Hydroacylation of 1,5-Hexadiene through C-H Bond Activation)

  • 전철호;한종수;김선일
    • 대한화학회지
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    • 제38권11호
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    • pp.833-840
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    • 1994
  • 8-Quinolinecarboxaldehyde (1)와 1,5-hexadiene (2)을 월킨슨 촉매(3)와 $AgBF_4(8)$의 혼합 촉매에서 반응시키면 8-quinolinyl 5-hexenyl ketone(4)와 8-quinolinyl 5-hexen-2-yl ketone (9)이 높은 수율로 반응초기에 생성된다. 가지달린 alkenyl 케톤인 9가 생성되는 이유는 월킨슨 촉매와 $AgBF_4(8)$의 반응에서 촉매에 빈 배위공간이 만들어져 1,5-hexadiene의 하이드로메탈레이션반응에서 $AgBF_4(8)$를 넣지 않았을 때보다는 입체장애가 적은 5.5각형의 중간체를 만들 수 있기 때문으로 설명된다. $AgBF_4(8)$의 사용량이 많으면 많을수록 9가 4보다 많은 비율로 생성되며, 장시간과 고온에서는 생성된 9와 4의 혼합물이 10과 5의 내부올레핀을 함유한 alkenyl 케톤으로 이성질화반응이 진행됨을 관찰할 수 있었다. 특히 고온으로 반응을 진행시킬수록 8-quinolinyl cyclopentylmethyl ketone (11)의 생성이 눈에 띄게 높아짐을 알 수 있었다.

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Effects of by-product feed-based silage on feeding, rumination, and excretion in growing Hanwoo heifers

  • Kim, Young-Il;Lee, Sang Moo;Lee, Youn Hee;Lee, Myeon;Choi, Do Young;Kwak, Wan Sup
    • Journal of Animal Science and Technology
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    • 제57권1호
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    • pp.3.1-3.6
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    • 2015
  • This study investigated the effects of feeding by-product feed (BF)-based silage on the behavior of growing Hanwoo heifers. Twelve Hanwoo heifers (13.2 months-old, 315 kg body weight; four heifers per pen) were assigned to three diets: a rice straw (RS) diet (concentrate mix and free access to RS), a RS and BF-based silage (RSBFS) diet (concentrate mix and free access to RS and BF-based silage), and a BF-based silage (BFS) diet (concentrate mix and free access to BF-based silage). Behavior was recorded for 5 days using camcorders. Compared to the RS group, the BFS group showed 21.7% higher dry matter intake, shorter feeding, rumination, and chewing times, as well as longer resting time (p < 0.05). Although all groups exhibited similar drinking, urination, and defecation frequencies, the BFS group exhibited higher feeding rates, rumination efficiency, and chewing efficiency than the RS group (p < 0.05). Compared to the BFS group, the RSBFS group showed higher $peNDF_{8.0}$ intake (15.2% vs. 25.0% dry matter intake), longer feeding and sitting times, lower defecation frequency (p < 0.05), and similar rumination efficiency. In conclusion, complete replacement of conventional RS with BF-based silage reduced rumination and chewing activity in growing Hanwoo heifers, and BF-based silage feeding with large-particle straw is an effective approach in improving heifer behavior.

들기름, 옥수수기름의 섭취와 2-Acetylaminofluorene 투여가 지질과산화물 및 PG $E_2$ TX $B_2$ 생성에 미치는 영향 (Effect of Intake of Perilla oil or Corn oil and 2-Acetylaminofluorene Treatment on Lipid Peroxidation PG $E_2$ and TX $B_2$ Productions in Rats)

  • 곽충실
    • Journal of Nutrition and Health
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    • 제25권5호
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    • pp.351-359
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    • 1992
  • This study was conducted to compare the effects of perilla oil or corn oil on lipid peroxidation and eicosanoid productions which are associated with the promotion of carcinogenesis. in liver or blood in rats. Male Sprague-Dawley8 weaning rats were fed on semisynthetic diets containing 15%(w/w) beef fat(BF). corn oil(CO) or perilla oil(PO) Three weeks after the half of rats in each diet group were injected with a single dose of 50mg 2-acetylaminofluorene (AAF)/Kg BW hepatocarcinogen intraperitoneally 3 times at 2-day interval and all of the rats were sacrificed after 8 weeks from the first injection. The rats fed on different dietary fats without 2-AAF treatment had not different MDA produc-tion and conjugated diene content in liver microsome. CO+AAf group had significantly higher conjugated diene content than BF+AAF and PO+AAF groups. and lower glucose-6-phospha-tase activity than BF+AAF group But PO+AAF had similar conjugated diene content to BF+AAF group and significantly lower MDA production than BF+AAF and CO+AAF groups. The hepatic mocrosomal lipid peroxidation was slightly greater in CO group than in PO group though perilla oil(P/S=9.67) has much more polyunsaturated fatty acids than corn oil(P/S=2.92) PG E2 level in liver and TX B2 level in plasma were significantly higher in CO group than in BF and PO groups. TX B2 level was lowered in CO and BF groups by 2-AAF treatment. These results reach to the contclousion than the type of dietary fatty acid as well as the P/S ratio has effect on hepatic microsomal lipid peroxidation and eicosanoid production and perilla oil or linolenic acid(n3) might be less effective on lipid peroxidation or PG E2 and TX B2 mediated tumor promotion than corn oil or linoleic acid(n6).

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한국인 분변에서 분리한 Bifidobacteria의 탈지유에서의 배양특성

  • 진효상
    • 한국미생물·생명공학회지
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    • 제25권3호
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    • pp.248-252
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    • 1997
  • Wild strains of bifidobacteria isolated from Korean feces were tested for their growth and acid production abilities in 10% skim milk. Growth of bifidobacteria was markedly decreased from the second transfer in the skim milk culture. When two strains, BF5 and BF33, were grown in skim milk with various supplements, the growth was enhanced by supplementation of 0.5% yeast extract, and 0.05% cysteine but not by short chain fatty acids. There was no enhancing effect of CO$_{2}$, substitution in the fermentor on growth. The viable cell counts of bifidobacteria, BF5 and BF33, were 9.76 and 9.98 logCFU/ml, respectively, after 30 hr cultivation and were diminished by 3 and 6 logs during storage at 5$\circ$C for 12 days.

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Effect of By-product Feed-based Silage Feeding on the Performance, Blood Metabolites, and Carcass Characteristics of Hanwoo Steers (a Field Study)

  • Kim, Y.I.;Park, J.M.;Lee, Y.H.;Lee, M.;Choi, D.Y.;Kwak, Wan-Sup
    • Asian-Australasian Journal of Animal Sciences
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    • 제28권2호
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    • pp.180-187
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    • 2015
  • This study was conducted to determine the effects of feeding by-product feed (BF)-based silage on the performance, blood metabolite parameters, and carcass characteristics of Hanwoo steers. The BF-based silage was composed of 50% spent mushroom substrate, 21% recycled poultry bedding, 15% cut ryegrass straw, 10.8% rice bran, 2% molasses, 0.6% bentonite, and 0.6% microbial additive (on a wet basis), and ensiled for over 5 d. Fifteen steers were allocated to three diets during the growing and fattening periods (3.1 and 9.8 months, respectively): a control diet (concentrate mix and free access to rice straw), a 50% BF-based silage diet (control diet+50% of maximum BF-based silage intake), and a 100% BF-based silage diet (the same amount of concentrate mix and ad libitum BF-based silage). The BF-based silage was fed during the growing and fattening periods, and was replaced with larger particles of rice straw during the finishing period. After 19.6 months of the whole period all the steers were slaughtered. Compared with feeding rice straw, feeding BF-based silage tended (p = 0.10) to increase the average daily gain (27%) and feed efficiency (18%) of the growing steers, caused by increased voluntary feed intake. Feeding BF-based silage had little effect on serum constituents, electrolytes, enzymes, or the blood cell profiles of fattening steers, except for low serum Ca and high blood urea concentrations (p<0.05). Feeding BF-based silage did not affect cold carcass weight, yield traits such as back fat thickness, longissimus muscle area, yield index or yield grade, or quality traits such as meat color, fat color, texture, maturity, marbling score, or quality grade. However, it improved good quality grade (1+ and 1++) appearance rates (60% for the control group vs 100% for the BF-based silage-fed groups). In conclusion, cheap BF-based silage could be successfully used as a good quality roughage source for beef cattle.

야채 및 과일추출물의 항산화작용 (Antioxidant Activity of Vegetables or Fruits Extract in Mice)

  • 허찬;김남이;김현표;허문영
    • 약학회지
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    • 제49권3호
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    • pp.249-254
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    • 2005
  • The ethanol extracts of the mixed vegetables (Bioactive Vegetables, BV) and the mixed fruits (Bioactive Fruits, BF) were evaluated for their in vivo antioxidant activities. Four weeks treatment of oral administration was performed to mice. A $KBrO_3$ as a potent oxidant was used to induce the oxidative stress for in vivo experiment. BV and BF were shown to possess the significant inhibitory effect of lipid peroxidation as measured by the level of malondialdehyde (MDA) formation although the potencies were not higher than those of well-known antioxidants such as vitamin C, trolox and quercetin. Furthermore, BV and BF inhibited DNA damage assessed by single cell gel electrophoresis (comet assay) and reduced the micronucleated reticulocyte (MNRET) formation of peripheral blood. Antioxidants tested also revealed potent inhibitory activities higher than BV and BF. These antigenotoxic activity profiles were similar to that of abovementioned inhibition of lipid peroxidation. Therefore, BV and BF having mild antioxidant activity as functional food candidates may be useful natural antioxidants by the inhibiting of lipid peroxidation and the protecting oxidative DNA and chromosomal damage.

학교시설의 장애물 없는 생활환경(Barrier Free) 인증 사례를 통한 정성평가 텍스트마이닝 기법 적용에 관한 기초연구 (A Basic Study on the Application of Text-Maining Method for Qualitative Evaluation through Barrier Free Certification in School Facilities)

  • 윤평세;이종국
    • 교육녹색환경연구
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    • 제19권1호
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    • pp.25-35
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    • 2020
  • BF인증을 도입하여 운영한 이래 2020년 2월까지 총 6,432건의 인증서 발급이 있었고, 그 중 교육연구시설은 건축물 6,237건 중 1,091건(예비인증 754건, 본인증 337건)으로 약 20%의 BF인증을 취득하였다. BF인증 건축물 평가지표 3개 항목 매개시설, 내부시설, 위생시설 중점적으로 정성평가를 실시하고, 그 도출 결과를 Text Mining 분석 통해 주요 키워드를 도출한다. 도출된 결과 매개시설의 경우 접근로에 대한 문제점이 발생되었으며, 내부시설의 계단에 대한 평가사항 중 사용자에 대한 평가지표 마련이 필요하다는 결과를 알 수 있었다. 마지막으로 위생시설의 경우 주민 개발시설에 설치되는 화장실에 대한 개선이 필요한 것을 알 수 있었다. 도출된 결과를 바탕으로 학교시설 BF인증에 필요한 평가지표가 별로도 마련되어야할 것이다.