• 제목/요약/키워드: $A-S_N2Ar\

검색결과 209건 처리시간 0.029초

오비탈 용접법을 적용한 STS 316L 파이프 소재의 용접부 특성에 관한 연구 (A Study on the Welds Characteristics of Stainless Steel 316L Pipe using Orbital Welding Process)

  • 이병우;조상명
    • 동력기계공학회지
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    • 제14권2호
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    • pp.71-77
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    • 2010
  • This paper was studied on microstructure, mechanical properties and corrosion characteristics of 316L stainless steel pipe welds was fabricated by orbital welding process. S-Ar specimen was fabricated by using Ar purge gas and S-$N_2$ specimen was fabricated by using $N_2$ purge gas. Ferrite was not detected in weld metal of S-$N_2$ specimen but the order of 0.13 Ferrite number(FN) was detected in weld metal of S-Ar specimen. Oxygen and Nitrogen concentration of S-$N_2$ specimen was higher than S-Ar specimen on HAZ and inner bead. The welds microstructural characteristics of S-Ar and S-$N_2$ specimens are similar. The microvickers hardness values of S-Ar and S-$N_2$ specimens welds were similar and average values of each regions were in the range of 174~194. The microstructures of S-Ar and S-$N_2$ weld metal were full austenite by primary austenite solidification. The Solidification structures of S-Ar and S-$N_2$ weld metal were formed directional dendrite toward bead center. The potentiodynamic polarization curve of STS 316L pipe welds exhibited typical active, passive, transpassive behaviour. Corrosion current density$(I_{corr.})$ and corrosion rate values of S-Ar specimen in 0.1M HCl solution were $0.95{\mu}A/cm^2$ and $0.31{\mu}A$/year respectively. The values of S-$N_2$ specimen were $1.4{\mu}A/cm^2$ and $0.45{\mu}m$/year.

계수 영상화된 측모 두부방사선 규격사진의 계측오차 (ERRORS IN DIGITIZED LATERAL CEPHALOMETRIC RADIOGRAPHY)

  • 전선두;조봉혜;나경수
    • 치과방사선
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    • 제27권2호
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    • pp.105-116
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    • 1997
  • The purpose of this study is to evaluate the cephalometric reproducibility in digitized cephalometric radiography by comparing the measurement errors between the remeasured and retaken conventional and digitized lateral cephalometric radiography. The mean of the differences and error percentage of each cephalometric measurement were obtained using 96 lateral cephalometric radiography from 48 patients between the age of 11 and 13. The results were as follows; 1. The repeated measurement group of conventional radiography showed least amount of mean differences while those of the retaken measurement group of digitized image showed largest amount of mean differences in every measurement. 2. The measurements which showed statistically significant difference between the conventional radiography and digitized image were S-Go, Ar-Go, S-Ar-Go and S-sN-sNT in repeated measurement group. 3. The measurements which showed statistically significant difference between the repeated and retaken measurement groups were N-S-Ar, MP-Ll and S-sN-sPog in conventional radiography and S-N, Go-Me and N-A in digitized Image. 4. Large amount of error percentage was shown at A-N-B and N-A in retaken measurement group of conventional radiography and N-S-Ba and A-N-B in retaken measurement group of digitized image. 5. The amount of error percentage at Ar-Go and N-S- Ar in retaken measurement group of conventional radiography and S-N, N-A, S-N-B and N-S-Ba in retaken measurement group of digitized image was more than double than those from remeasured groups.

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Effects of Gas Flow Ratio on the Properties of Tool Steel Treated by a Direct Current Flasma Nitriding Process

  • Jang H. K.;Whang C. N.;Kim S. G.;Yu B. G.
    • 한국표면공학회지
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    • 제38권5호
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    • pp.202-206
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    • 2005
  • Nitriding treatments were conducted on tool steel (SKD 61) at a temperature of $500^{\circ}C$ for 5 hr using high vacuum direct current (DC) plasma, with ammonia and argon as source gases. The structural and compositional changes produced in the nitrided layers by applying different ratios of Ar to $NH_{3}\;(n_{Ar}/n_{NH3}) were investigated using glancing x-ray diffraction (GXRD), optical microscopy, atomic force microscopy (AFM), micro-Vickers hardness testing, and pin-on-disc type tribometer. Nitriding case depths of around of $50{\mu}m$ were produced, varying slightly with different ratios of $n_{Ar}/n_{NH3}. It was found that the specimen surface hardness was 1150 Hv with $n_{Ar}/n_{NH3}=1, increasing to a maximum value of 1500 Hv with $n_{Ar}/n_{NH3}=5. With a further increase in ratio to $n_{Ar}/n_{NH3}=10, the surface hardness of the specimen reduced slightly to a value of 1370 Hv. These phenomena were caused by changes of the crystallographic structure of the nitride layers, i.e the $\gamma'-Fe_{4}N$ phase only was observed in the sample treated with $n_{Ar}/n_{NH3}$=1, and the intensity of the $\gamma'-Fe_{4}N$ phase were reduced but new phase of $\varepsilon'-Fe_{3}N$, which was known as a high hardness, with increasing $n_{Ar}/n_{NH3}. Also, the relative weight loss of counterface of the pin-on-disc with unnitrided steel was 0.2. And that of nitrided steel at a gas mixture ($n_{Ar}/n_{NH3}) of 1, 5, 7, and 10 was 0.4, 0.7, 0.6, and 0.5 mg, respectively. This means that the wear resistance of the nitrided samples could be increased by a factor of 2 at least than that of unnitrided steel.

Study of CO2+(CO2)n Cluster in a Paul Ion Trap

  • Karimi, L.;Sadat Kiai, S.M.;babazaheh, A.R.;Elahi, M.;Shafaei, S.R.
    • Mass Spectrometry Letters
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    • 제10권1호
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    • pp.27-31
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    • 2019
  • In this article, the properties of ${CO_2}^+(CO_2)_n$ clusters in a Paul ion trap have been investigated using mass-selective instability mode which conducted by chosen precursor ions, mainly $Ar^+$ and ${CO_2}^+$ produced by a mixture of Ar and $CO_2$. Exposure of ${CO_2}^+$ ions to $CO_2$ molecules, lead to the formation of ${CO_2}^+(CO_2)_n$ clusters. Here, Ar gas react as a buffer gas and lead to form ${CO_2}^+(CO_2)_n$ cluster by collisional effect.

액체혼합물의 활동도계수의 이론적 계산 (Theoretical Calculation of Activity Coefficients of Liquid Mixtures)

  • 문대원;전무식;이태규
    • 대한화학회지
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    • 제21권6호
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    • pp.395-403
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    • 1977
  • 액체이론(Significant Structure Theory)를 단원자 분자로부터 다원자 분자에 이르는 여러 액체혼합물에 적용하여 전 농도 범위에서 액체 혼합물의 활동도 계수를 계산했다. 단원자 분자계(Ar-Kr, Kr-Xe)와 이원자 분자계$(Ar-O_2,\;N_2-CO)$와 메탄-크립톤계의 액체혼합물의 활동도 계수는 ${\delta}E_s$ 수정 변수에 의해 좋은 결과를 얻었다. 아르곤-질소, 산소-질소, 그리고 메탄-프로판계에 대해서는 이 외에 ${\delta}$V, ${\delta}$n 수정 변수가 더 필요했다.

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Ar, He 및 $N_2$ 가스의 $\alpha$-입자 저지능과 저지 단면적 측정 (The Stopping Power and Cross-section Measurement of $\alpha$-particle in Ar, He and $N_2$ gases)

  • 이정훈;황재광;황한열;정원모;주관식
    • Journal of Radiation Protection and Research
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    • 제13권2호
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    • pp.1-8
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    • 1988
  • 3MeV에 서 5.4MeV 사이의 $\alpha$-입자에 대한 저지능과 저지 단면적을 He, Ar, 및 $N_2$ 가스에 대해서 측정했다. Srivastava의 저지능 공식을 본 실험결과에 적용시켜 그 타당성을 알아보았다. 그결과 Ar의 경우는 매우 잘 일치됨을 보여주며, He의 경우는 27-28%, $N_2$의 경우는 13-26%의 불일치를 보여주고 있다.

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하악골 성장 지표로서 경추골 성숙도의 유용성 (USEFULNESS OF CERVICAL VERTEBRAE MATURATION STAGE AS A MANDIBULAR MATURATION INDICATOR)

  • 최봉선;최남기;김선미;양규호;정성수
    • 대한소아치과학회지
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    • 제34권4호
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    • pp.551-559
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    • 2007
  • 하악골 성장을 평가하는 데 경추골 성숙도가 수완부골 성숙도만큼 유용한가 규명하고자 본 연구를 시행하였다. 정상교합을 가진 만 8세$\sim$만 16세 여성 292명을 연구대상으로 하여 진단석고모형, 측모두부규격방사선사진, 그리고 수완부방사선사진을 이용하여 경추 및 수완부의 골성숙도를 비교하여 다음과 같은 결과를 얻었다. 1. 연령 증가에 따라 경추 및 수완부의 골성숙도가 일정하게 증가하였다. 2. 경추골 성숙도가 증가할수록 Ar-Go, Go-Me, N-Go, S-Gn, N-Me이 일정하게 증가하였다. 3. 수완부골 성숙도가 증가할수록 Ar-Go, Go-Me, N-Go, S-Gn이 일정하게 증가하였다. 4. 경추골 성숙도 3단계와 4단계 사이에서 Ar-Go, Go-Me, N-Go, S-Gn이 크게 증가하였고, 수완부골 성숙도 6단계와 7단계 사이에서 Go-Me, S-Gn이 크게 증가하였다. 5. Ar-Go, Go-Me, N-Go, S-Gn, N-Me은 경추 및 수완부 골성숙도와 각각 유의 한 상관성을 보였다. 이상의 결과는 하악골 성장을 평가하는 데에 경추골 성숙도가 수완부골 성숙도처럼 유용하게 사용될 수 있음을 시사한다.

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Ar/$C1_2/N_2$플라즈마를 이용한 Pt 박막 식각에서 $N_2$ Gas의 역할 ($N_2$ Gas roles on Pt thin film etching using Ar/$C1_2/N_2$ Plasma)

  • 류재홍;김남훈;이원재;유병곤;장의구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.468-470
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    • 1999
  • One of the most critical problem in etching of platinum was generally known that the etch slope was gradual. therefore, the addition of $N_2$ gas into the Ar/C1$_2$ gas mixture, which has been proposed the optimized etching gas combination for etching of platinum in our previous article, was performed. The selectivity of platinum film to oxide film as an etch mask increased with the addition of N2 gas, and the steeper etch slope over 75 $^{\circ}$ could be obtained. These phenomena were interpreted the results the results of a blocking layer such as Si-N or Si-O-N on the oxide mask. Compostional analysis was carried out by X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS). Moreover, it could be obtained the higher etch rate of Pt film and steeper profile without residues such as p.-Cl and Pt-Pt ant the addition N\ulcorner of 20 % gas in Ar(90)/Cl$_2$(10) Plasma. The Plasma characteristic was extracted from optical emissionspectroscopy (OES).

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Cation Radicals with 2-Phridylhydrazones in Nitrile Solvents s-Triazolo[4,3-a]pyridines by Thianthrene Cation Radical Perchlorate and 1-(2-Pyridyl)-1,2,4-Triazoles by Tris(2,4-Dibromophenyl)-aminium Hexachloroantimonate

  • 박균하;전건;신승림;오세화
    • Bulletin of the Korean Chemical Society
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    • 제18권6호
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    • pp.604-608
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    • 1997
  • Reactions of arenealdehyde 2-pyridylhydrazones (1) with thianthrene cation radical ($Th^{+·}$) and tris(2,4-dibromophenyl)aminium hexachloroantimonate ($Ar_3N^{+·}SbCl_6^-$) were investigated. The major product was switched depending on the cation radical being used. That is, s-triazolo[4,3-α]pyridines (2), an intramolecular cyclization product, and 1-(2-pyridyl)-1,2,4-triazoles (3), an intermolecular cycloaddition product, were obtained as a major product when reacted with $Th^{+·}$ and $Ar_3N^{+·}$, respectively in nitrile solvents. The plausible mechanisms are proposed based on both the reduction potentials of $Th^{+·}$ and $Ar_3N^{+·}$ and control experiments.

Cu 금속과 Si 기판 사이에서 확산방지막으로 사용하기 위한 Zr(Si)N 박막의 특성 (Characteristic of Zr(Si)N film as a diffusion barrier between Cu metal and Si substrate)

  • 김좌연;조병철;채상훈;김헌창;박경순
    • 한국결정성장학회지
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    • 제12권6호
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    • pp.283-287
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    • 2002
  • 초고집적 반도체 회로에서 Cu를 배선으로 쓰이기 위한 Cu 금속과 Si 기판사이의 확산방지막으로써 Zr(Si)N 박막을 연구하였다. Zr(Si)N 박막증착은 DC magnetron sputter으로 $Ar/N_2$의 혼합 gas를 사용한 reactive sputtering 방법을 이용하였다. 상온에서 ZrN 박막 증착시 Ar gas와 NE gas 비율이 48 : 2일 때 가장 낮은 비저항값을 가졌으며, 증착시 기판의 온도의 증가에 따라서 비저항값이 낮아졌다. 비저항값이 감소된 ZrN 박막일수록 (002)면의 방향성을 갖는 결정이 성장되었다. ZrN 박막의 Cu 확산방지 특성은 ZrN 박막에 Si을 첨가함으로써 개선될 수 있으며 지나치게 첨가될 경우에는 오히려 확산방지 특성이 감소되었다. 접착력 특성에서는 ZrN에 Si의 함유량이 증가함에 파라 개선되었다. 증착막의 특성은 XRD, 광학 현미경, scretch tester 그리고 $\alpha$-step 등을 사용하여 분석하였다.