• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.10
• /
• pp.1777-1787
• /
• 2000

The purpose of this study was to select an effective and economical alkali source for sulfur-utilizing autotrophic denitrification. Tests on acid neutralization and denitrification at various alkali/sulfur mixing ratios were performed for charcoal, briquette ashes, sea shell, and limestone. The results of the experiments showed that sea shell was the most effective alkali source because it could provide more surface area than limestone, and the optimal alkali/sulfur mixing ratio was 1/1(V/V). In a sulfur/sea shell packed bed reactor, the denitrification efficiency was above 90% up to a loading rate of 116 g $NO_3{^-}-N/m^3-day$. but the denitrification efficiency deteriorated to 48% at the loading rate of 145 g $NO_3{^-}-N/m^3-day$. The average $SO_4{^{2-}}$ generation per g of $NO_3{^-}-N$ removed was 7.02 g, which is lower than the theoretical value of 7.54 g. Denitrification and sulfate generation appeared to be a first-order and a zero-order reaction with a reaction rate constant of 0.146 /hr and -53.1 mg/L-hr, respectively. According to nitrogen mass balance, 71~109%, with an average of 90%, of the removed nitrogen was recovered as $N_2$ gas.

• Korean Journal of Soil Science and Fertilizer
• /
• v.19 no.2
• /
• pp.139-145
• /
• 1986

In order to study the influence of nitrate reduction to ionic balance in tissue of tobacco plant, differneces in amounts of those cations and anions were determined and these balances were compared with contents of organic acids and activities of nitrate reductase, while they were fertilized with different nitrogen sources ($NO_3-N$, $NH_4-N$, $NO_3+NH_4-N$) in water culture. The results of studies are summerized as follows; 1. Total uptake of inorganic cations was the highest in nitrate-fed plants, whereas that of inorganic anions showed the highest level in the plants grown with the mixture ($NO_3+NH_4$). The amounts of inorganic cations and anions were comparable in two treatments containing $NH_4-N$, but in plants treated with nitrate only had much higher level of inorganic cations than others. 2. Deficiency in the amount of inorganic anions in nitrate-fed plants was balanced with organic acids, dominantly with malic acid among them. But another two $NH_4-N$ fed plant sustained equilibrium between inorganic cations and anions. 3. Reduction of nitrate was raised in tissues of nitrate-fed plants. By the results of nitrate reduction, cations maintained equilibrium with nitrate ion were let loose. The replacement of inorganic anions with organic anions could be a compensation process for the loss of uptaken nitrate ions which must be reduced to be incorporated into organic N compounds.

• Journal of Ecology and Environment
• /
• v.43 no.4
• /
• pp.461-468
• /
• 2019

Background: This study aimed to identify NO₃^--N sources using the stable isotope δ¹⁵N in Chydorus sphaericus (OF Müller), to investigate hydrological characteristics and nutrient states in artificial wetlands near the Nakdong River. Chydorus sphaericus is dominant in wetlands where aquatic plants are abundant, occurring in high density, and is sensitive to wetland water pollution, making it suitable for identification of NO₃^--N sources. Results: NO₃^--N sources for each wetland were strongly dependent on hydrological characteristics. Wetlands with sewage or rainfall/groundwater as their main sources had high levels of NO₃^--N, whereas wetlands with surface water as their main input had comparatively lower levels. Since wetlands with sewage and rainfall/groundwater as their main water sources were mostly detention ponds, their inputs from tributaries or the main river stream were limited and nutrients such as NO₃^--N easily become concentrated. Changes in NO₃^--N levels at each wetland were closely associated with δ¹⁵N of C. sphaericus. Interestingly, regression analysis also showed positive correlation between δ¹⁵N of C. sphaericus and NO₃^--N level. Conclusions: We conclude that the nitrate stable isotope (δ¹⁵N) of C. sphaericus can be used to elucidate the hydrological characteristics of riverine wetlands. This information is important for maintenance and conservation of artificial wetlands at the Nakdong River.

• Applied Biological Chemistry
• /
• v.37 no.4
• /
• pp.277-286
• /
• 1994

The pot experiment using $^{15}N$ isotope dilution technique was carried out to calculate the balance of nitrogen of surface applied urea in the rice-soil system. The $^{15}N$ concentration was determined by stable isotope ratio mass spcetrometer (model: VG ISO-GAS MM622). In the pots with $^{15}N$ labeled urea application at the rates of 15 and 30 kg N/10a, the percentage of nitrogen derived from fertilizer (NDFF) in rice was higher at the rate of 30 kg N/10a (average 89%) than at the rate of 15 kg N/10a (average 64%). However, the recovery as percentage of fertilizer N by rice was higher at the rate of 15 kg N/10a (65.5%) than at the rate of 30 kg N/10a (54.2%). The percentage of the fertilizer N remained in extractable inorganic N form at the rates of 15 and 30 kg N/10a were $13.5%\;(NH_4-N\;5.53%,\;NO_3-N\;7.99%)$ and $16.5%\;(NH_4-N\;7.49%,\;NO_3-N\;8.98%)$ in unplanted soil, and $2.0%\;(NH_4-N\;0.63%,\;NO_3-N\;1.32%)$ and$2.3%\;(NH_4-N\;0.87%,\;NO_3-N\;1.40%)$ in soil planted to rice, respectively. The dominant form of inorganic-N in soil after harvest was $NO_3-N$ form rather than $NH_4-N$ form regardless of urea application rate or rice cultivation. The percentage of the fertilizer N remained in organic N form at the rates of 15 and 30 kg N/10a were 65.0 and 41.8% in unplanted soil, and 23.7 and 26.9% in soil planted to rice, respectively. In conclusion, the efficiency of surface-applied urea was greater at the rate 15 kg N/10a than at the rate of 30 kg N/10a.

• Korean Journal of Soil Science and Fertilizer
• /
• v.21 no.1
• /
• pp.31-40
• /
• 1988

This study was focussed to compare the concentrations of the volatile oil components of flue-cured tobacco grown by two types of nitrogen-ammonium and nitrate-under vinyl mulching. The results were summarized as follows; 1. The content of nicotine was lower and reducing sugars degraded from starch was higher content in $NO_3-N$ application than $NH_4-N$. 2. The concentrations of furfural, benzyl alcohol, and phenethyl alcohol in the cured leaf were not different between $NH_4-N$ and $NO_3-N$ treatments. 3. Some of the important flavour components-linalool, solanone, damascenone, neophytadiene, and oxyolanone + megastigmatriene-one - had much higher concentrations in $NO_3-N$ than $NH_4-N$ application. 4. In conclusion, nitrate nitrogen was more favorable to decrease nicotine and to increase some important flavour components of cured leaf than ammonium nitrogen.

• Journal of the Korean Chemical Society
• /
• v.39 no.5
• /
• pp.393-398
• /
• 1995

The oxo-nitrosyl complexes (n-Bu4N)2[M4O12Mo(NO)2{RC(NH2)NHO}2{RC(NH)NO}2] (M=Mo, W; R=(CH3)2CH, n-CH3CH2CH2) have been prepared by the reactions of monomeric complex containing {Mo(NO)2}2+ and polyoxometalates with isobutyl- and n-butylamidoxime. The prepared complexes were characterized by elemental analysis, infrared, 1H NMR, 13C NMR and UV-visible spectroscopy. These complexes contain two {M2O5}2+ [M=Mo, W] cores and a central {Mo(NO)2}2+ core. The {Mo(NO)2}2+ unit was the formally cis type and C2v symmetry in geometric structure. The two {M2O5}2+ cores and a central {Mo(NO)2}2+ core were not nearly interacted with electronic localization, which were identified by spectroscopy.

• Korean Journal of Ecology and Environment
• /
• v.48 no.3
• /
• pp.147-152
• /
• 2015

Nitrogen (N) loading from domestic, agricultural and industrial sources can lead to excessive growth of macrophytes or phytoplankton in aquatic environment. Many studies have used nitrogen stable isotope ratios to identify anthropogenic nitrogen in aquatic systems as a useful method for studying nitrogen cycle. In this study to evaluate the precision and accuracy of Kjeldahl processes, two reference materials (IAEA-NO-3, N-1) were analyzed repeatedly. Measured the ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values of IAEA-NO-3 and IAEA-N-1 were $4.7{\pm}0.2$‰ and $0.4{\pm}0.3$‰, respectively, which are within recommended values of analytical uncertainties. Also, we investigated spatial patterns of ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ in effluent plumes from a waste water treatment plant in Han River, Korea. ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values are enriched at downstream areas of water treatment plant suggesting that dissolved nitrogen in effluent plumes should be one of the main N sources in those areas. The current study clarifies the reliability of Kjeldahl analytical method and the usefulness of stable isotopic techniques to trace the contamination source of dissolved nitrogen such as nitrate and ammonia.

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.5
• /
• pp.698-703
• /
• 2012

This survey was conducted to obtain basic data of the quality of groundwater for agriculture in Gyeongnam province. Groundwater samples from paddy 15, upland 15, and plastic film house 30 sites were collected on April, July, and October in every two years from 2002 to 2008. According to the result of water quality analysis, groundwater quality was suitable for irrigation purpose averagely. The $NO_3$-N contents by land use were in the order of plastic film house > upland > paddy field and its contents were 6.53, 4.80, and $3.68mg\;L^{-1}$, respectively. In annual changes of water quality, pH was no significant change in paddy, upland, and plastic film house by 6.6~6.9. EC was increased in upland and plastic film house in 2008 and majors factors were $NO_3$-N and $Cl^-$. In upland and plastic film house, $NO_3$-N contents were 4.72 and $6.52mg\;L^{-1}$ in 2002, respectively, whereas they were 5.63 and $8.70mg\;L^{-1}$ in 2008, respectively. Of the investigated sites, $NO_3$-N was exceeded water quality standards for agriculture by 3.3~15.0% in plastic film house and $Cl^-$ was exceeded water quality standards for agriculture by 2.2% in upland of 2004. The $NO_3$-N contents were decreased with well depth and their contents were $5.38mg\;L^{-1}$ from 3~10 m, $4.87mg\;L^{-1}$ from 10~20 m, and $2.58mg\;L^{-1}$ from above 30 m. The $NO_3$-N contents by soil texture were highest in sandy loam by $5.73mg\;L^{-1}$ and lowest in clay loam by $4.13mg\;L^{-1}$. The $NO_3$-N contents by crops category were in order of fruit vegetables > leaf vegetables > rice > fruits > beans, contents of fruit vegetables and leaf vegetables were 5.81 and $5.30mg\;L^{-1}$, respectively.

• Fire Science and Engineering
• /
• v.27 no.3
• /
• pp.66-71
• /
• 2013

The purpose of this study is to assess the criteria on a floor hinge and door closer for the optimum design of the access door of a smoke control room. The door opening force due to differential pressure is 60.75 N, 40.5 N, 32.91 N and 12.66 N when the differential pressure is 60 Pa, 40 Pa, 32.5 Pa and 12.5 Pa, respectively. The door opening force of the floor hinge and door closer to which the criteria of KS F 2806 are applied is 27.5 N, 40 N, 75 N, 100 N and 125 N for the Nos. 1, 2, 3, 4 and 5 class floor hinges and door closers, respectively. This study compared the differential pressure and opening force limits of floor hinges and door closers with the values specified in NFSC 501A and found that they exceeded the criteria specified in NFSC 501A. Therefore, it is necessary to reflect the differential pressure and smoke control wind speeds as well as the opening forces specified in NFSC 501A on the design of floor hinges and door closers. The installation conditions of floor hinges and door closers of access doors differ depending on the type and name of a smoke control damper. This study found that Nos. 1, 2 and 3 floor hinges and door closers could be installed for access doors with low differential pressure and that Nos. 1 and 2 floor hinges and door closers could be installed for access doors with normal differential pressure.

• Proceedings of the Korean Society of Crop Science Conference
• /
• 2017.06a
• /
• pp.4-4
• /
• 2017

Atmospheric carbon dioxide enrichment ($eCO_2$) often increases soil nitrous oxide ($N_2O$) emissions, but the underlying mechanisms are not fully understood. Emerging evidence suggests that $eCO_2$ alters plant N preference in favor of ammonium ($NH_4{^+}-N$) over nitrate ($NO_3{^-}-N$). Yet, whether and how this attributes to the enhancement of $N_2O$ emissions has not been investigated. We examined the effects of $eCO_2$ on soil $N_2O$ emissions in the presence of two N forms ($NH_4{^+}-N$ or $NO_3{^-}-N$), using wheat (Triticum aestivum L.) as a model plant. Our results showed that N forms dominated $eCO_2$ effects on plant and microbial N utilization, and thus soil $N_2O$ emissions. Elevated $CO_2$ significantly increased the rate and the sum of $N_2O$ emissions by three to four folds when $NO_3{^-}-N$, but not $NH_4{^+}-N$, was supplied. Enhanced $N_2O$ emission was related to the reduced plant $NO_3{^-}-N$ uptake in wheat. We propose a new conceptual model in which $eCO_2$-inhibition of plant $NO_3{^-}-N$ uptake and/or $CO_2$-enhancement of soil labile C enhances the N and/or C availability for denitrifiers and increases the intensity and/or the duration of $N_2O$ emissions. Together, these findings suggest that to enhance plant N use efficiency and reduce $N_2O$ emission, crop breeding and management need to consider altered plant preference of N sources under future $CO_2$ scenarios.