• Advances in nano research
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• 제13권3호
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• pp.259-267
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• 2022

Two-dimensional (2D) transition metal carbides/nitrides or "MXenes" belong to a diverse-class of layered compounds, which offer composition- and electric-field-tunable electrical and physical properties. Although the majority of the MXenes, including Ti₃C₂T_x, are metallic, they typically show semiconductor-like behaviour in their percolated thin-film structure; this is also the most common structure used for fundamental studies and prototype device development of MXene. Magnetoconductance studies of thin-film MXenes are central to understanding their electronic transport properties and charge carrier dynamics, and also to evaluate their potential for spin-tronics and magnetoelectronics. Since MXenes are produced through solution processing, it is desirable to develop deposition strategies such as inkjet-printing to enable scale-up production with intricate structures/networks. Here, we systematically investigate the extrinsic negative magnetoconductance of inkjetprinted Ti₃C₂T_x MXene thin-films and report a crossover from weak anti-localization (WAL) to weak localization (WL) near 2.5K. The crossover from WAL to WL is consistent with strong, extrinsic, spin-orbit coupling, a key property for active control of spin currents in spin-orbitronic devices. From WAL/WL magnetoconductance analysis, we estimate that the printed MXene thin-film has a spin orbit coupling field of up to 0.84 T at 1.9 K. Our results and analyses offer a deeper understanding into microscopic charge carrier transport in Ti₃C₂T_x, revealing promising properties for printed, flexible, electronic and spinorbitronic device applications.

• 한국응용과학기술학회지
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• 제13권2호
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• pp.21-28
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• 1996

Diazotization of STA synthesized by the indirect diazotization method. The effect of catalyst and agitation (rpm) about STA and H-acid reaction were examined and the optimum conditions were investigated experimentally. The yields and characteristics of $1^{.st}$ coupling and diazotization synthesis were identified by HPLC and FT-IR analysis. $1^{.st}$ condensation of CNC and mPDSA were synthesized at $5^{\circ}C$ and pH=6.5. The conditions of alkaly coupling of H-acid were synthesized at $5^{\circ}C$ and pH=8. The condensation of products was identified by U. V. analysis. From this results, It was obtained to reactive dyestuffs of bi-functional reactivity with high fastness and high adsorption.

• Applied Biological Chemistry
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• 제47권2호
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• pp.270-273
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• 2004

꾸지뽕나무(Cudrania tricuspidata Bureau)의 클로로포름 추출물로부터 2종의 prenylated flavonoid 항균 물질을 분리하였다. 분리할 화합물에 대하여 항균활성을 실험 한 결과 화합물 1과 2는 $10\;{\mu}g/disk$의 농도에서 Gram 양성균인 Staphylococcus aureus, Bacillus subtilis 그리고 Bacillus cereus에 대하여 활성을 보였다. 이들의 구조를 $^lH\;NMR,\;^{13}C\;NMR$ 및 2D NMR을 포함한 분광학적인 방법을 통하여 분석한 결과, 화합물 1과 2는 euchrestaflavanone B와 euchrestaflavanone C로 각각 동정 되었다.

• 대한전기학회논문지
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• 제41권1호
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• pp.50-55
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• 1992

Piezoelectric Buzzer which has been generally used requires about 30kV/cm poling process and has the aging effects. In this study, 0.85 PZN - 0.10 BT - 0.05 PT system ceramics with additives of 0 - 2 wt% YS12TOS13T were fabricated and investigated on electromechanical coupling coefficient(kS1pT), electric field induced charge coefficient(dS131T), and sound level. As the results, in the 0.4 wt% YS12TOS13T added composition ceramics compared with the basic, kS1pT was increased from 0.355 to 0.39 and induced piezoelectric d constant increased from 204 to 220 x 10S0-12T (C/N) and sound level of electrostrictive Buzzer has the highest value of 71.5 dB under 8kV/cm bias electric field.

• Bulletin of the Korean Chemical Society
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• 제32권11호
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• pp.3899-3903
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• 2011

General, fast, and efficient fusion methods for the synthesis of dendrimers with 1,3-diynes at a core were developed. The synthetic strategy was employed the oxidative homo-coupling of terminal alkyne. The oxidative homo-coupling reaction of the alkyne-functionalized Frechet-type dendrons 1-Dm was allowed to provide first through fourth generation dendrimers 2-Gm with 1,3-diynes at core. The fusion of the propargylfunctionalized PAMAM dendrons 3-Dm by homo-coupling of terminal alkyne lead to the formation of symmetric PAMAM dendrimers 4-Gm. Their structure of dendrimers was confirmed by $^1H$ and $^{13}C$ NMR spectroscopy, IR spectroscopy, mass spectrometry, and GPC analysis.

• 한국자기학회지
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• 제13권5호
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• pp.211-215
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• 2003

퍼말로이/교환중간층(Ru, V)퍼말로이 구조의 인위적 페리층을 만들어 이때 교환중간층의 두께를 4-20 $\AA$으로 변화시키며 이때의 보자력( $H_{c}$), 스핀플로핑 필드( $H_{sf}$ ), 포화자계( $H_{s}$ )의 변화를 SQUID로 확인하였다. 아울러 수직단면투과전자현미경을 이용하여 Ru, V의 인위적페리층의 미세구조를 관찰하였다. 퍼말로이를 채용한 인위적 구조는 모두 보자력이 10 Oe이하로 가능하였고 교환 층의 두께를 조절함으로써 적절한 $H_{s}$ , $H_{sf}$ 의 선택이 가능하였다. 특히 바나듐을 교환매개층으로 채택한 경우도 8 $\AA$의 두께에서 교환 작용이 확인되었다. 미세구조확인결과 V의 경우 퍼말로이와 혼입에 의해 유효두께가 얇아져서 교환 작용이 작아짐을 확인하였다.

• 한국자기학회지
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• 제10권4호
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• pp.171-177
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• 2000

RF 마그네트론 스퍼터링 증착법으로 제작한 Co/NiMn 이층막에서의 교환자기결합현상을 연구하였다. 어닐링의 온도와 시간에 따른 교환자기결합력(H$_{ex}$)의 변화를 조사하여 300 $^{\circ}C$에서 13시간의 열처리후에 최대의 교환결합자장을 얻을 수 있음을 보였고, NiMn과 Co층의 적층순서를 변화시켰을 때, NiMn 상층구조의 시편이 더 높은 교환자기결합력을 나타냄을 알 수 있었다. 상층의 Ta 보호막의 사용이 교환자기결합을 나타내는데 필수적임을 알 수 있었는데 , AES 분석은 Ta 보호층을 적용하지 않은 경우에, 산소원자가 막 내부의 깊은 곳까지 침투함으로 인하여 교환자기결합력이 일어나지 않음을 보여주었다. 또한 교환자기결합에 대한 Ta 바닥층의 효과를 연구하였다. Ta 바닥층은 높은 교환자기결합력을 얻기 위해서는 사용하지 않는 것이 낫다는 것을 알아내었다. X선 회절분석의 결과는, Ta 바닥층이 다층막에 우선방위조직을 형성시키는데 기여하지만, NiFe/NiMn 이층막에서의 경우와는 달리 교환자기결합에 반드시 필요한 조건이 아님을 보여주었다. 또한 Co층과 NiMn층의 두께에 따른 교환결합력의 영향을 조사하여, 교환결합력은 200 $\AA$ 이상의 NiMn층 적용 시 최대값을 가지며, Co층의 두께에 반비례함을 알 수 있었다.다.

• 한국자기공명학회논문지
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• 제10권1호
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• pp.59-73
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• 2006

Spin-lattice relaxation pathway of $CH_2$ spin system by two dimensional NOESY sequence has been discussed. Two-dimensional spectra governed by dipolar relaxation mechanism were simulated in term of transfer mode, the generalization of conventionally used magnetization mode in one dimension. The transfer matrix directly related to the Redfield relaxation matrix can be constructed by the multiplet of transfer mode. The observable relaxation transfer modes causes to variation of the off-diagonal signal intensity of phase sensitive NOESY spectra from which variable spectral density can be extracted with simple group theoretical calculation. The variation of the J-coupling peak intensity as a function of the mixing time in 2-D spectra for $n-Undecane-5-^{13}C$ and Bromoacetic $2-^{13}C$ acid has been theoretically traced.

• 한국정보전자통신기술학회논문지
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• 제7권1호
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• pp.20-25
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• 2014

차세대 친환경 조명인 LED소자는 온도가 올라갈수록 LED의 발광효율이 떨어지고 $80^{\circ}C$이상 올라갈수록 수명이 감소하고 스펙트럼선의 파장이 본래의 파장보다 장파장 쪽으로 이동하는 Red Shift현상 및 $T_j$ 상승에 따라 광 출력이 감소되는 큰 문제점이 대두되고 있어 열을 최소화 할 수 있는 방열설계 연구가 진행 중이다. COB Type LED의 경우 보드에 LED 칩을 직접 결합시켜 열 저항을 낮췄지만 주거용 13.5W의 경우 방열판을 통해 발열 문제를 해결해야한다. 본 논문에서는 주거용 13.5W COB LED 다운라이트에 맞게 Heat Sink를 설계하고, 그 설계한 Heat Sink와 13.5W COB를 패키징하여 Solidworks flow simulation을 통해 최적의 Fin두께를 선정하여 접촉식 온도계를 사용한 열적 특성을 분석 하고 평가 하였다.

• 한국정보기술학회 영문논문지
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• 제10권1호
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• pp.37-43
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• 2020

This paper presents analysis of passive metal interconnection of the LNA block in CMOS integrated circuit. The performance of circuit is affected by the geometry of RF signal path. To investigate the effect of interconnection lines, a cascode LNA is designed, and circuit simulations with full-wave electromagnetic (EM) simulations are executed for different positions of a component. As the results, the position of an external capacitor (C_ex) changes the parasitic capacitance of electric coupling; the placement of component affects the circuit performance. This analysis of interconnection line is helpful to analyze the amount of electromagnetic coupling between the lines, and useful to choose the signal path in the layout design. The target of this work is the RF LNA enabling the seamless connection of wireless data network and the following standards have to be supported in multi-band (WCDMA: 2.11~ 2.17 GHz, CDMA200 1x : 1.84~1.87 GHz, WiBro : 2.3~2.4GHz) mobile application. This work has been simulated and verified by Cadence spectre RF tool and Ansoft HFSS. And also, this work has been implemented in a 0.13um RF CMOS technology process.