• 제목/요약/키워드: ${\phi}_r$

검색결과 323건 처리시간 0.026초

STRUCTURE JACOBI OPERATORS AND REAL HYPERSURFACES OF TYPE(A) IN COMPLEX SPACE FORMS

  • Ki, U-Hang
    • East Asian mathematical journal
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    • 제37권1호
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    • pp.97-107
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    • 2021
  • Let M be a real hypersurface with almost contact metric structure (��, ξ, ��, g) in a nonflat complex space form Mn(c). We denote S and Rξ by the Ricci tensor of M and by the structure Jacobi operator with respect to the vector field ξ respectively. In this paper, we prove that M is a Hopf hypersurface of type (A) in Mn(c) if it satisfies Rξ�� = ��Rξ and at the same time satisfies $({\nabla}_{{\phi}{\nabla}_{\xi}{\xi}}R_{\xi}){\xi}=0$ or Rξ��S = S��Rξ.

정밀토양도와 GIS를 이용한 토석류 발생지역 예측 분석 (Numerical Modeling for the Detection of Debris Flow Using Detailed Soil Map and GIS)

  • 김판구;한건연
    • 대한토목학회논문집
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    • 제37권1호
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    • pp.43-59
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    • 2017
  • 본 연구에서는 SINMAP 모형을 이용한 토석류 발생지역에 대한 예측기법을 보여준다. 기존의 연구들은 토석류 발생을 예측하기 위해서 일부 토질시험 결과를 적용한 단일보정영역을 사용하였으나 이는 대상유역의 토질 특성을 세분화할 수 없는 문제점이 있다. 반면, 본 연구에서는 기존 연구의 문제점을 보완하기 위해서 정밀토양도와 토양통별 토질강도정수(c, ${\phi}$)를 이용하여 다중보정영역을 적용하는 방법을 제안하였다. 이 과정에서 토질은 토양침식성 인자(K)를 이용하여 1) 자갈 및 자갈질 흙, 2) 모래 및 모래질 흙, 그리고 3) 실트 및 점토질의 세가지로 분류하였다. 또한, 본 연구에서는 토석류 발생시점을 알고 있는 경우에만 T/R의 추정이 가능한 기존의 방법 대신 고도평균값을 이용하는 T/R 산정 방법을 제안하였다. 기존방법과 제안방법을 실제 토석류가 발생한 봉화군 서벽 1리에 적용하여 산정된 T/R 값들은 거의 일치하였다. 따라서 본 연구에서 제안한 토석류 발생지역 예측을 위한 방법론은 전국적인 토석류 발생위험 대비에 기여할 수 있을 것으로 기대된다.

The Effect of Different Inflows on the Unsteady Hydrodynamic Characteristics of a Mixed Flow Pump

  • Yun, Long;Dezhong, Wang;Junlian, Yin;Youlin, Cai;Chao, Feng
    • International Journal of Fluid Machinery and Systems
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    • 제10권2호
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    • pp.138-145
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    • 2017
  • The problem of non-uniform inflow exists in many practical engineering applications, such as the elbow suction pipe of waterjet pump and, the channel head of steam generator which is directly connect with reactor coolant pump. Generally, pumps are identical designs and are selected based on performance under uniform inflow with the straight pipe, but actually non-uniform suction flow is induced by upstream equipment. In this paper, CFD approach was employed to analyze unsteady hydrodynamic characteristics of reactor coolant pumps with different inflows. The Reynolds-averaged Naiver-Stokes equations with the $k-{\varepsilon}$ turbulence model were solved by the computational fluid dynamics software CFX to conduct the steady and unsteady numerical simulation. The numerical results of the straight pipe and channel head were validated with experimental data for the heads at different flow coefficients. In the nominal flow rate, the head of the pump with the channel head decreases by 1.19% when compared to the straight pipe. The complicated structure of channel head induces the inlet flow non-uniform. The non-uniformity of the inflow induces the difference of vorticity distribution at the outlet of the pump. The variation law of blade to blade velocity at different flow rate and the difference of blade to blade velocity with different inflow are researched. The effects of non-uniform inflow on radial forces are absolutely different from the uniform inflow. For the radial forces at the frequency $f_R$, the corresponding amplitude of channel head are higher than the straight pipe at $1.0{\Phi}_d$ and $1.2{\Phi}_d$ flow rates, and the corresponding amplitude of channel head are lower than the straight pipe at $0.8{\Phi}_d$ flow rates.

Kinetics and Mechanism of Nucleophilic Displacement Reactions of Y-Substituted Phenyl Benzoates with Z-Substituted Phenoxides

  • Min, Se-Won;Seo, Jin-A;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제30권10호
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    • pp.2403-2407
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    • 2009
  • Second-order rate constants have been measured for two series of nucleophilic displacement reactions, i.e., reactions of 4-nitrophenyl benzoate with Z-substituted phenoxides and those of Y-substituted phenyl benzoates (1a-h) with 4-chlorophenoxide (4-ClPhO–) in 80 mol% $H_2O$/20 mol% DMSO at 25.0 ${\pm}\;0.1\;{^{\circ}C}$. The Br$\phi$nsted-type plot for reactions of 4-nitrophenyl benzoate with Z-substituted phenoxides exhibits an excellent linear correlation with ${\beta}_{nuc}$ = 0.72. Reactions of 1a-h with 4-chlorophenoxide result in also a linear Br$\phi$nsted-type plot with ${\beta}_{lg}$ = –0.62, a typical ${\beta}_{lg}$ value for a concerted mechanism. The Hammett plots correlated with ${\sigma}^o\;and\;{\sigma}^-$ constants show many scattered points for reactions of 1a-h with 4-chlorophenoxide. In contrast, the corresponding Yukawa-Tsuno plot exhibits an excellent linear correlation with $\rho_Y$ = 2.26 and r = 0.53, indicating that expulsion of the leaving group occurs at the rate-determining step (RDS) either in a concerted mechanism or in a stepwise pathway. However, a stepwise mechanism with leaving group departure being the RDS is excluded since the leaving Y-substituted phenoxide is less basic and a better nucleofuge than the incoming 4-ClPh$O^-$. Thus, the reactions have been concluded to proceed through a concerted mechanism, in which bond formation between the nucleophile and electrophilic center is more advanced than expulsion of the leaving group in the transition state on the basis of the magnitude of ${\beta}_{nuc}\;and\;{\beta}_{lg}$ values.

Kinetic Study on Aminolysis of 4-Chloro-2-Nitrophenyl X-Substituted-Benzoates in Acetonitrile and in 80 mol % H2O/20 mol % DMSO: Effect of Medium on Reactivity and Reaction Mechanism

  • Kim, Ha-Ram;Um, Tae-Il;Kim, Min-Young;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1128-1132
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    • 2014
  • A kinetic study on aminolysis of 4-chloro-2-nitrophenyl X-substituted-benzoates (6a-i) in MeCN is reported. The Hammett plot for the reactions of 6a-i with piperidine consists of two intersecting straight lines, while the Yukawa-Tsuno plot exhibits an excellent linear correlation with ${\rho}_X$ = 1.03 and r = 0.78. The nonlinear Hammett plot is not due to a change in rate-determining step (RDS) but is caused by the resonance stabilization of substrates possessing an electron-donating group in the benzoyl moiety. The Br${\phi}$nsted-type plot for the reactions of 4-chloro-2-nitrophenyl benzoate (6e) with a series of cyclic secondary amines is linear with ${\beta}_{nuc}$ = 0.69, an upper limit for reactions reported to proceed through a concerted mechanism. The aminolysis of 6e in aqueous medium has previously been reported to proceed through a stepwise mechanism with a change in RDS on the basis of a curved Br${\phi}$nsted-type plot. It has been concluded that instability of the zwitterionic tetrahedral intermediate ($T^{\pm}$) in MeCN forces the reaction to proceed through a concerted mechanism. This is further supported by the kinetic result that the amines used in this study are less reactive in MeCN than in $H_2O$, although they are more basic in MeCN over 7 $pK_a$ units.

Atomic structure and crystallography of joints in SnO2 nanowire networks

  • Hrkac, Viktor;Wolff, Niklas;Duppel, Viola;Paulowicz, Ingo;Adelung, Rainer;Mishra, Yogendra Kumar;Kienle, Lorenz
    • Applied Microscopy
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    • 제49권
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    • pp.1.1-1.10
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    • 2019
  • Joints of three-dimensional (3D) rutile-type (r) tin dioxide ($SnO_2$) nanowire networks, produced by the flame transport synthesis (FTS), are formed by coherent twin boundaries at $(101)^r$ serving for the interpenetration of the nanowires. Transmission electron microscopy (TEM) methods, i.e. high resolution and (precession) electron diffraction (PED), were utilized to collect information of the atomic interface structure along the edge-on zone axes $[010]^r$, $[111]^r$ and superposition directions $[001]^r$, $[101]^r$. A model of the twin boundary is generated by a supercell approach, serving as base for simulations of all given real and reciprocal space data as for the elaboration of three-dimensional, i.e. relrod and higher order Laue zones (HOLZ), contributions to the intensity distribution of PED patterns. Confirmed by the comparison of simulated and experimental findings, details of the structural distortion at the twin boundary can be demonstrated.

SOME REMARKS ON PRIMAL IDEALS

  • Kim, Joong-Ho
    • 대한수학회보
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    • 제30권1호
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    • pp.71-77
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    • 1993
  • Every ring considered in the paper will be assumed to be commutative and have a unit element. An ideal A of a ring R will be called primal if the elements of R which are zero divisors modulo A, form an ideal of R, say pp. If A is a primal ideal of R, P is called the adjoint ideal of A. The adjoint ideal of a primal ideal is prime [2]. The definition of primal ideals may also be formulated as follows: An ideal A of a ring R is primal if in the residue class ring R/A the zero divisors form an ideal of R/A. If Q is a primary idel of a ring R then every zero divisor of R/Q is nilpotent; therefore, Q is a primal ideal of R. That a primal ideal need not be primary, is shown by an example in [2]. Let R[X], and R[[X]] denote the polynomial ring and formal power series ring in an indeterminate X over a ring R, respectively. Let S be a multiplicative system in a ring R and S$^{-1}$ R the quotient ring of R. Let Q be a P-primary ideal of a ring R. Then Q[X] is a P[X]-primary ideal of R[X], and S$^{-1}$ Q is a S$^{-1}$ P-primary ideal of a ring S$^{-1}$ R if S.cap.P=.phi., and Q[[X]] is a P[[X]]-primary ideal of R[[X]] if R is Noetherian [1]. We search for analogous results when primary ideals are replaced with primal ideals. To show an ideal A of a ring R to be primal, it sufficies to show that a-b is a zero divisor modulo A whenever a and b are zero divisors modulo A.

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Regulation of Nek6 Functions by Its SUMOylation on the $K^{252}$ Residue

  • Lee, Eun-Jeoung;Hyun, Sung-Hee;Chun, Jae-Sun;Shin, Sung-Hwa;Lee, Kyung-Eun;Park, In-Suk;Kang, Sang-Sun
    • Animal cells and systems
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    • 제11권2호
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    • pp.205-213
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    • 2007
  • Nek6 belongs to NIMA1 (never in mitosis, gene A) related kinase, which was originally identified in Aspergillus nidulans as a serine/threonine kinase critical for cell cycle progression. We noticed that the putative SUMOylation site is localized on the $K^{252}$ residue in $^{251}FKsD^{254}$ of Nek6, based on the consensus sequence ${\Phi}KxE$; where ${\Phi}$ represents L, I, V or F and x is any amino acid. We observed that the Nek6 SUMO mutant (K252R) has decreased protein kinase activity, nuclear speckle localization and protein stability, compared with that of the Nek6 wild type. However, the Nek6 SUMO mutant increased the cell survival rate of COS-1 cells as determined by FACS analysis. Therefore, our data suggest that SUMOylation on the $K^{252}$ residue of Nek6 is required for its normal functions, such as proper nuclear localization, kinase activity and protein stability, to control cell cycle.

내열강 마찰용접재의 ISM에 의한 크리프 수명예측에 관한 연구 (Study on Creep Life Prediction by Initial Strain Method for Friction Welded Joints of Heat Resisting Steels)

  • 김헌경;김일석;이연탁;공유식;오세규
    • 한국해양공학회지
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    • 제15권2호
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    • pp.46-52
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    • 2001
  • In this paper, the real-time prediction of high temperature creep life was carried out for the friction welded joints of dissimilar heat resisting steels (SUH3-SUH35). various life prediction method such as LMP (Larson_miller Parameter) and ISM (initial strain method) were applied. The creep behaviors of those steels and the welds under static load were examined by ISM combined with LMP at 500, 600 and $700^{\circ}C$, and the relationship between these two methods was investigated. A real-time creep lie (tr, hr) prediction equation by initial strain (${\varepsilon}_0$, %) under any creep stress ($\sigma$, MPa) at any high temperature (T, K) was developed as follows: $t_r={\alpha}{\varepsilon}_0^{\beta}{\sigma}^{-1}$ where, ${\phi}=16: {\alpha}=10^{51.412-0.104T+5.375{\times}10^5T^2}$, $ {\beta}=-83.989+0.180T-9.957{\times}10^{-5}T^2,{\phi}=20:$ ${\alpha}=10^{69.910-0.146T+7.744{\times}10^{-5}T^2$, ${\beta}=-51.442+0.105T-5.595{\times}10^{-5}T^2$ for SUH3-SUH35 friction weld of =16mm and 20mm, respectively.

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