• 보존과학연구
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• s.15
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• pp.21-32
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• 1994

Optimum conditions for benzene synthesis and liquid scintillation counting have been studied for the determination of radiocarbon age. In benzene synthesis the carbon dioxide converted to benzene with high efficiency of 91%. Yields of each step with 10L of carbon dioxide were $CO_2$ $\rightarrow$$C_2H_2$(94%), $C_2H_2$$\rightarrow$$C_6H_6$(96%) and$CO_2$$\rightarrow$$C_6H_6$(91%), respectively. Benzene synthesized from oxalate was measured with purity of 95% by GC /MS. $\delta^13$(C$^13$C/$^12$C) of oxalate was measured to $-24.7\{textperthousand}$ by massspectrometer. For liquid scintillation counting of benzene sample low background and highest FOM were measured in 0.5 ml cocktail and 3 ml standard solution with the range of 15.4∼74.9 KeV window setting. Oxalate and background samples weremeasured to $28.7\pm0.12$cpm and $3.92\pm0.04$ cpm in 15.4∼74.9 KeV

• Journal of the Korean Chemical Society
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• v.48 no.5
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• pp.473-482
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• 2004

The homobimetallic anion, $M^+({\eta}^5-MeCp)Mn(CO)_2Mn(CO)_5^-(M^+=Na^+,\;PPN^+)$was disrupted by CH2CHCH2Cl in THF at various temperatures ($20^{\circ}C~50^{\circ}C$) under the pseudo 1st order reaction conditions where excess of allyl chloride was employed under a nitrogen atmosphere. This homobimetallic anion seems to be involved in a concerted reaction mechanism in which a four-centered transition state is proposed. After undergoing the transition state, this reaction eventually leads to (MeCp)Mn$(CO)_3$ on addition of CO and $({\eta}^1-allyl)Mn(CO)_5$, respectively. However, in case of $Na^+$ analog, $Na^+$ may play a novel counter ion effect on the disruption reaction either by transferring one terminal CO from the $Mn(CO)_5$ moiety on to the $({\eta}^5-MeCp)Mn(CO)_2$of the corresponding homobimetallic complex, eventually resulting in $({\eta}^5-MeCp)Mn(CO)_3$ or through the interaction between $Na^+$ and the leaving group (Cl) of allyl chloride. This reaction is of overall second order with respect to homobimetallic complex with the activation parameters (${\Delta}H^{\neq}=17.15{\pm}0.17kcal/mol,\;{\Delta}S^{\neq}=-9.63{\pm}0.10$ e.u. for $Na^+$ analog; ${\Delta}H^{\neq}=22.13{\pm}0.21 kcal/mol,\;{\Delta}S^{\neq}=9.74{\pm}0.19$ e.u. for $PPN^+$ analog reaction).

• Journal of the East Asian Society of Dietary Life
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• v.21 no.4
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• pp.526-534
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• 2011

Cold air drying was conducted on steamed chestnut-sweet potato to improve its quality, convenience, and preference as snack. Steamed sweet potato was dried from 10 to $25^{\circ}C$ for 48 hours, and moisture contents, colors, texture, and taste were evaluated. The lowest moisture content was 4.53% at $25^{\circ}C$. Lightness decreased while other color values (a, b, and ${\Delta}$E) increased with increasing drying temperature and drying time. Reducing sugar and soluble solid contents ranged from 93.22~190.35 mg/g and 17~60 $^{\circ}Brix$, respectively. The highest hardness of chestnut-sweet potato was 25.13 kgf/$cm^2$, and springiness and cohesiveness were 88.60, and 94.87%, respectively, when dried at $25^{\circ}C$ for 48 hours. Sensory evaluation score was highest at $20^{\circ}C$ for 24 hours. The optimum drying conditions were determined to be $19^{\circ}C$ and 39.5 hours by RSM(response surface methodology).

• Korean Journal of Agricultural and Forest Meteorology
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• v.15 no.2
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• pp.102-108
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• 2013

To understand the relationship of growth and water use efficiency (WUE) between superior and inferior families from open-pollinated progenies of P. densiflora, two families (one superior and one inferior families) in two open-pollinated progeny test sites were selected using volume growth at 26 years. And we compared environmental factors and WUE which was calculated from measured ${\delta}^{13}C$ in the wood. The ${\delta}^{13}C$ change during the last 20 years showed steady decrease and same pattern as WUE in the fertile site, while there was an inverse relationship between ${\delta}^{13}C$ and WUE in poor site, indicating an interaction between gene and environment. The superior family showed higher WUE than inferior family in poor site, indicating efficient stomatal control of the former under water stress. Water use efficiency calculated by carbon isotope composition can be used as a selection criterion for drought tolerance families in open-pollinated progenies of P. densiflora.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.13 no.3
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• pp.203-215
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• 2009

In this article, we study the existence and uniqueness of mild and classical solutions for a nonlinear impulsive differential equation with nonlocal conditions u'(t) = Au(t) + f(t, u(t); Tu(t); Su(t)), $0{\leq}t{\leq}T_0$, $t{\neq}t_i$, u(0) + g(u) = $u_0$, ${\Delta}u(t_i)=I_i(u(t_i))$, i = 1,2,${\ldots}$p, 0<$t_1$<$t_2$<$\cdots$<$t_p$<$T_0$, in a Banach space X, where A is the infinitesimal generator of a $C_0$ semigroup, g constitutes a nonlocal conditions, and ${\Delta}u(t_i)=u(t_i^+)-u(t_i^-)$ represents an impulsive conditions.

• Journal of the Korean Chemical Society
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• v.13 no.1
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• pp.5-8
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• 1969

Acid dissociation constants and chelate stability constants of 8-hydroxyquinoline-5-sulfonic acid have been determined for divalent metal ions. Co (Ⅱ), Ni (Ⅱ) and Zn (Ⅱ) by means of the Calvin-Bjerrum technique at the various temperatures. The standard free energy changes for the reactions at $20^{\circ}$, $30^{\circ}$, $40^{\circ}$and $50^{\circ}C$ were calculated, and the corresponding values of ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ applying over this temperature range are reported. The results are interpreted on the basis of current theories of metal chelate formation in aqueous solution.

• Electrical & Electronic Materials
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• v.5 no.1
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• pp.28-42
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• 1992

본 논문에서는 ZnO 바리스터의 유전특성에 대해 검토하였다. 25~75[.deg.C]의 온도에서 1[kHz]~13[MHz]의 부파수 범위에서 LCR meter와 computer로 구성된 측정장치를 사용하여 정전용량-주파수, 및 손실계수-주파수의 관계를 측정하였다. 수학적 해석 방법에 의해 복소유전율의 실험결과로 부터 3-4개의 Debye 피크를 추출할 수 있었다. 각 피크를 .alpha., .betha., .gamma. 및 .delta.라 할 때 활성화에너지는 각각 0.35-0.48, 0.62-0.99, 0.48 및 0.33-0.41[eV]이었고, 각 피크 중 .gamma.는 공핍층에 형성된 도너준위, .alpha. 및 .delta.는 결정립 계면준위, .betha.피크는 도너이온에 의한 것으로 추정된다.

• Korean Journal of Pharmacognosy
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• v.31 no.4
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• pp.401-406
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• 2000

Marine sponges are known to be a source of diverse sterols. In our study on the cytotoxic components of the marine sponge Spirastrella abata, $5{\alpha},8{\alpha}-epidioxy\;{\Delta}^6$ sterols (1-5) and $5{\alpha},8{\alpha}-epidioxy\;{\Delta}^{6,9(11)}$ sterols (6-7) were isolated. The structures were identified based on the analyses of $^1H-NMR,\;^{13)C-NMR$, and MS data. These compounds were assayed for cytotoxicity against 5 human solid tumor cell lines including A549, SK-OV- 3, SK-MEL-2, XF498, and HCT15.

• Journal of Powder Materials
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• v.13 no.3 s.56
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• pp.178-186
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• 2006

The effect of use of $H_2O$ as PCA(process control agent) to prevent the carbon contamination during mechanical alloying process and the precipitation behavior in Ni-20Cr-20Fe-5Nb bulk alloy after aging were investigated. NbC and $Cr_2O_3$ were formed during mechanical alloying and consolidation processes in the Ni-20Cr-20Fe-5Nb alloy in which methanol($CH_3OH$) was added as PCA. Formation of NbC in this alloy decreased the amount of Nb dissolved in the Ni matrix. The use of $H_2O$ as PCA in Ni-20Cr-20Fe-5Nb alloy prevented the formation of NbC and increased the hardness. The increase of hardness in this alloy was attributed to the increased amount of Nb dissolved in the Ni matrix. After aging treatment for 20 hours at $600^{\circ}C\;and\;720^{\circ}C$ of Ni-20Cr-20Fe-5Nb bulk alloy in which $H_2O$ added as PCA, ${\gamma}"$$(Ni_3Nb,\;tetragonal)\;and\;{\delta}\;(Ni_3Nb,\;orthorhombic)$ precipitates were formed, respectively. The precipitation temperatures of ${\gamma}"$ and ${\delta}$ in this bulk alloy were lower than those in commercial IN 718 alloy. It seemed that the lower precipitation temperatures for ${\gamma}"$ and ${\delta}$ in this bulk alloy than in commercial IN 718 alloy were due to severe plastic deformation during mechanical alloying.

• Journal of the Mineralogical Society of Korea
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• v.17 no.1
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• pp.61-73
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• 2004

The purposes of this study are to investigate the occurrence, the hydrochemical characteristics and the origin of the $CO_2$-rich springs from the Kangwon Province, and to reanalyze the previous studied results of other researchers. The $CO_2$-rich water samples were collected at 13 locations in the Kangwon Province. The $CO_2$-rich water shows a high $CO_2$ concentration ($P_{CO2}$ 0.787 to 4.78 atm), weak acidic pHs, electrical conductivity values ranging from 422 to 2,280 $\mu$S/cm, and high Fe and F contents. The chemical compositions of $CO_2$-rich water from this study area are classified into three types; $Ca-HCO_3$, Ca(Na)-$HCO_3$, $Na-HCO_3$ types. The chemical data of $CO_2$-rich waters and their host rocks indicate that $Na-HCO_3$ type water are mainly influenced by biotite, K-feldspar granite, and Ca(Na)-HC $O_3$, type water is chiefly influenced by gneiss and carbonate minerals in granite. F and Fe contents of $CO_2$-rich waters are abundant in $Na-HCO_3$, and $Ca-HCO_3$ types, respectively. The results of this study suggest that the chemical composition $CO_2$-rich water is mainly controlled by the mineralogical composition of aquifer host rocks. Oxygen and deuterium isotope data indicate that $CO_2$-rich water is meteoric origin. The $\delta^{13}$C values (-0.3$\textperthousand$ to -6.2$\textperthousand$ PDB) suggest that dissolved carbonates are mainly derived from a deep-seated $CO_2$ and partly from carbonate minerals.