• Journal of the Korean Chemical Society
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• v.39 no.5
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• pp.384-392
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• 1995

Steady-state sublimation vapour pressures of anhydrous bismuth trichloride have been measured by the continuous gravimetric Knudsen effusion method from 370.6 to 488.8 K. Additional effusion measurements have also been made from 438.2 to 495.7 K by the torsion effusion method. Based on a correlation of ${\Delta}_H0298$.15 and ${\Delta}_H0298$.15, a recommended p(T) equation has been obtained for BiCl3(s); log(p/Pa)=－C/(T/K)－2.838log(T/K)－8.097${\times}$10-2(K/T)2＋22.588, where p is in Pa, T in Kelvin and ${\Delta}_H0298$.15 in kJmo1-1 and C=(${\Delta}_H0298$.15＋5.9988)/1.9146${\times}$10-2. Condensation coefficients and their temperature dependence have been derived from the effusion measurements.

• The Journal of Advanced Prosthodontics
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• v.6 no.6
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• pp.427-433
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• 2014

PURPOSE. Surface color is one of the main criteria to obtain an ideal esthetic. Many factors such as the type of the material, surface specifications, number of firings, firing temperature and thickness of the porcelain are all important to provide an unchanged surface color in dental ceramics. The aim of this study was to evaluate the color changes in dental ceramics according to the material type and glazing methods, during the multiple firings. MATERIALS AND METHODS. Three different types of dental ceramics (IPS Classical metal ceramic, Empress Esthetic and Empress 2 ceramics) were used in the study. Porcelains were evaluated under five main groups according to glaze and natural glaze methods. Color changes (${\Delta}E$) and changes in color parameters (${\Delta}L$, ${\Delta}a$, ${\Delta}b$) were determined using colorimeter during the control, the first, third, fifth, and seventh firings. The statistical analysis of the results was performed using ANOVA and Tukey test. RESULTS. The color changes which occurred upon material-method-firing interaction were statistically significant (P<.05). ${\Delta}E$, ${\Delta}L$, ${\Delta}a$ and ${\Delta}b$ values also demonstrated a negative trend. The MC-G group was less affected in terms of color changes compared to other groups. In all-ceramic specimens, the surface color was significantly affected by multiple firings. CONCLUSION. Firing detrimentally affected the structure of the porcelain surface and hence caused fading of the color and prominence of yellow and red characters. Compressible all-ceramics were remarkably affected by repeated firings due to their crystalline structure.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.91-94
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• 2002

The conditions of zone-melting method such as a sample travel speed in a furnace, content of Nd422, control of melting temperature, and heat-treatment with/without Ar gas for $NdBa_{2}Cu_{3}O_{7-\delta}$ superconductor was optimized, As a results, a $NdBa_{2}Cu_{3}O_{7-\delta}$ sample with a surface area of $25mm^{2}$ showed a good superconducting properties when its travel speed was 6 mm/h, The improvement of superconductivity added with 10~20 wt% of Nd422 phase increasing pinning effect was also shown. The critical current density, $J_{c}$ was remarkable affected by the condition of heat-treatment temperature of $NdBa_{2}Cu_{3}O_{7-\delta}$superconductor with/without Ar ambient gas.

• Coupled systems mechanics
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• v.6 no.1
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• pp.17-28
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• 2017

In this work, we extend the previously developed split kinetic energy (dubbed KEP) method by Mineo and Chao (2012) by modifying the mass parameter to include the negative mass. We first show how to separate the total system into the subsystems with 3 attractive delta potentials by using the KEP method. For repulsive delta potentials, we introduce "negative" mass terms. Two cases are demonstrated using the "negative" mass terms for repulsive delta potential problems in quantum mechanics. Our work shows that the KEP solution scheme can be used to obtain not only the exact energies but also the exact wavefunctions very precisely.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.19 no.4 s.74
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• pp.375-387
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• 2006

Different from the previous studies which investigated seismic P-$\Delta$ effect in slender columns though comparison of response spectra according to stability coefficients obtained from the analyses based on the assumed moment-curvature relationship, the axial force and P-$\Delta$ effect in RC columns are investigated on the basis of the layered section method which can effectively consider the changes of stiffness and yield strength due to the application of axial force in RC members. Practical ranges of slenderness and stability coefficient are assumed, and sixty sets of horizontal/vertical earthquake inputs are used in the analysis. From the parametric study, it is noted that the maximum deformation of the slender RC column is hardly affected by P-$\Delta$ effect or vortical earthquake but dominantly affected by the applied axial force. Therefore, it can be concluded that no additional consideration for the P-$\Delta$ effect and vortical earthquake is required in the seismic design of a slender RC column if the axial force effect is taken into account in the analysis and design procedures.

• Journal of the Korean Chemical Society
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• v.32 no.4
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• pp.291-296
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• 1988

Rates of the reaction for p-nitrobenzyl chloride, benzyl chloride and p-methylbenzyl chloride with pyridine in DMF solvent have been measured by an electric conductivity method at $40^{\circ}\;and\;50^{\circ}C$ under various pressures. From those rate constants, the activation parameters ${\Delta}V^{\neq},\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S^{\neq},\;{\Delta}G^{\neq}$) were evaluated. ${\Delta}V^{\neq}\;and\;{\Delta}{\beta}^{\neq}$ are both negative valued, but ${\Delta}H^{\neq}$ is positive and ${\Delta}S^{\neq}$ is large negative value. From the evaluation of the initial state and transition state which was resulted from substituents and pressure, it was found that this reaction proceeds through bimolecular reaction.

• Journal of Electrical Engineering and Technology
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• v.5 no.4
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• pp.538-544
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• 2010

This paper proposes an estimation algorithm for the separate primary and secondary leakage inductances of a three phase $Y-\Delta$ transformer using least squares method. The voltage equations from the primary and secondary windings are combined into a differential equation to estimate the separate primary and secondary leakage inductances in order to use the line current of the delta winding. Separate primary and secondary leakage inductances are obtained by applying least squares method to the differential equation. The performance of the proposed algorithm is validated under transient states, such as magnetic inrush and overexcitation, as well as in the steady state with various cut-off frequencies of low-pass filter. The proposed technique can accurately generate separate leakage inductances both in the steady and transient states.

• International Journal of Aeronautical and Space Sciences
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• v.2 no.2
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• pp.28-38
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• 2001

A numerical method for the assessment and correction of tunnel wall interference effects on forced-oscillation testing is presented. The method is based on the wall pressure signature method using computed wall pressure distributions. The wall pressure field is computed using unsteady three-dimensional full Navier-Stokes solver for a 70-degree pitching delta wing in a wind tunnel. Approximately-factorized alternate direction implicit (AF-ADI) scheme is advanced in time by solving block tri-diagonal matrices. The algebraic Baldwin-Lomax turbulence, model is included to simulate the turbulent flow effect. Also, dual time sub-iteration with, local, time stepping is implemented to improve the convergence. The computed wall pressure field is then imposed as boundary conditions for Euler re-simulation to obtain the interference flow field. The static computation shows good agreement with experiments. The dynamic computation demonstrates reasonable physical phenomena with a good convergence history. The effects of the tunnel wall in upwash and blockage are analyzed using the computed interference flow field for several reduced frequencies and amplitudes. The corrected results by pressure signature method agree well with the results of free air conditions.

• Journal of Technologic Dentistry
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• v.35 no.3
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• pp.185-192
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• 2013

Purpose: The aim of this study was to compare with color reproducibility of the coating method and dipping method using a colour liquid. Methods: Two groups of square-shaped specimens ($10mm{\times}10mm$ in diameter, 1.5mm thickness) were prepared for analysis(n=15/group). The CM(Coating Method) group was fabricated as full zirconia specimens with the coating coloring method and Group DM(Dipping Method) was prepared as specimens of 0.7 mm-thick zirconia plate using the dipping coloring method and veneered with 0.8mm-thick porcelain. Color parameters were measured with ShadeEye $NCC^{(R)}$ spectrophotometer and color differences were calculated using the equation ${\Delta}E^*= \{({\Delta}L^*)^2+({\Delta}a^*)^2+({\Delta}b^*)^2\}^{1/2}$. Non-parametric statistical methods, the Mann-Whitney test, and the Kruskal-Wallis test were used to analyze the data. Type one error rate was set at 0.05. Results: Color difference values larger than 7 were observed between specimens with the coating method and the dipping method, which were detectable difference in a clinical setting. Conclusion: Cautious application of the coating coloring method in a clinical setting and further researches to standardize the coating method are needed.

• Journal of the Korean Electrochemical Society
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• v.3 no.2
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• pp.109-114
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• 2000

The relation between the phase-shift profile fur the intermediate frequencies and the Langmuir adsorption isotherm at the poly-Ir/0.1 M $H_2SO_4$ aqueous electrolyte interface has been studied using ac impedance measurements, i.e., the phase-shift methods. The simplified interfacial equivalent circuit consists of the serial connection of the electrolyte resistance $(R_s)$, the faradaic resistance $(R_F)$, and the equivalent circuit element $(C_P)$ of the adsorption pseudoca-pacitance $(C_\phi)$. The comparison of the change rates of the $\Delta(-\phi)/{\Delta}E\;and\;\Delta{\theta}/{\Delta}E$ are represented. The delayed phase shift $(\phi)$ depends on both the cathode potential (E) and frequency (f), and is given by $\phi=tan^{-1}[1/2{\pi}f(R_s+R_F)C_P]$. The phase-shift profile $(-\phi\;vs.\;E)$ for the intermediate frequency (ca. 1 Hz) can be used as an experimental method to determine the Langmuir adsorption isotherm $(\theta\;vs.\;E)$. The equilibrium constant (K) for H adsorption and the standard free energy $({\Delta}G_{ads})$ of H adsorption at the poly-Ir/0.1 M $H_2SO_4$ electrolyte interface are $2.0\times10^{-4}$ and 21.1kJ/mol, respectively. The H adsorption is attributed to the over-potentially deposited hydrogen (OPD H).