• Title/Summary/Keyword: ${\delta}$-component

Search Result 226, Processing Time 0.031 seconds

Food web structure in a $Salix$ $subfragilis$ dominated wetland in Hangang estuary using stable isotopes and fatty acid biomarkers

  • Han, Dong-Uk;Yang, Dong-Woo;Lee, Eun-Joo;Park, Sang-Kyu
    • Animal cells and systems
    • /
    • v.16 no.2
    • /
    • pp.162-171
    • /
    • 2012
  • We investigated food webs of a $Salix$ $subfragilis$-dominated wetland in the Janghang wetland in the Hangang estuary, which is very close to the Demilitarized Zone, along the west coast of Korea. Our study focused on understanding sesarmine crab ($Sesarma$ $dehaani$)-related food webs in a $S.$ $subfragilis$ forest. For our study, we used carbon and nitrogen stable isotopes and fatty acid biomarkers. We collected samples of plants, animals, and detrital sediment from four quadrats ($5{\times}5m^2$) set in the $S.$ $subfragilis$ community. Samples were collected from September 2006 to June 2009, except during the winter hibernation period of $S.$ $dehaani$. In the wet season, the sediment showed relatively high ${\delta}^{13}C$ and low ${\delta}^{15}N$ signatures compared with relatively low ${\delta}13C$ and high ${\delta}15N$ signatures in the dry season. Mature $S.$ $dehaani$ appeared to feed on fresh leaves and other carbon sources, such as immature individuals or fish, in addition to detrital sediment, which appeared to be the main carbon source for immature crabs. Principal component analysis of fatty acid biomarkers of $S.$ $dehaani$ showed a clear difference between immature individuals (10-30 mm) and mature ones (larger than 30 mm), indicating that the main food source for immature crabs was detrital sediment, whereas mature crabs foraged plants in addition to consuming detrital sediment. On the basis of our results from stable isotope and fatty acid analyses, mature $S.$ $dehaani$ appeared to feed on detrital sediment and fresh leaves of $S.$ $subfragilis$ in summer in addition to engaging in cannibalism of immature individuals.

Near-IR Spectroscopic Studies of the Hydrogen Bonding between Thioacetamide and N,N-Dimethylacetamide in $CCl_4$ ($CCl_4$중에서 Thioacetamide와 N,N-Dimethylacetamide사이의 수소 결합에 관한 분광학적인 연구)

  • Kang Bong Lee;Byung-Chul Kim;Chang-ju Yun;O. D. Bonner;Young-Sang Choi
    • Journal of the Korean Chemical Society
    • /
    • v.30 no.6
    • /
    • pp.510-515
    • /
    • 1986
  • Spectra for the $v_3$+ Amide II combination band of thioacetamide(TA) were obtained in carbon tetrachloride solutions and in very dilute solutions of TA-N,N-dimethlylacetamide (DMA) in carbon tetrachloride in the range of 5~55$^{\circ}$C. The combination band in the three component system can be resolved into components due to monomeric TA, 1 : 1 TA-DMA complex and 1 : 2 TA-DMA complex. In the dilute solutions the experimental spectrum was resolved by using the computer into its two Lorentzian-Gaussian product components which have been identified with the monomeric TA and the 1 : 1 complex. The equilibrium constants and thermodynamic parameters of 1 : 1 complex were determined by analysis of concentration and temperature dependent spectra. The ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ for the 1 : 1 complex were -14.4 KJ mol$^{-1}$ and -15.6 J mol$^{-1}deg^{-1}$, respectively.

  • PDF

A Comparison of Volatile Flavor Characteristics of Chwi-namuls by Terpenoid Analysis (Terpenoid 분석을 통한 취나물류의 향기지표물질 비교)

  • Choi, Hyang-Sook
    • The Korean Journal of Food And Nutrition
    • /
    • v.25 no.4
    • /
    • pp.930-940
    • /
    • 2012
  • A comparison of essential oils composition of Aster tataricus L. (gaemichwi), Ligularia fischeri (gomchwi), Solidago virga-aurea var. asiatica Nakai (miyeokchwi), and Aster scaber (chamchwi) was performed by gas chromatography and mass spectrometry for the identification of volatile flavor characteristics in chwi-namuls. The essential oils were extracted by the hydro distillation extraction method. One hundred volatile flavor components were identified from gaemichwi essential oil. ${\alpha}$-Pinene (11.5%) was the most abundant compound, followed by myrcene (8.9%) and ${\beta}$-pinene (7.5%). Ninety-one volatile flavor components were identified from the essential oil of gomchwi. Aromadendrene (14.8%) was the most abundant component, followed by ${\beta}$-caryophyllene (7.6%) and 1-methyl-4-(1-methylethylidene)-cyclohexene (7.3%). Ninety-five volatile flavor constituents were detected in the essential oil of miyeokchwi, moreover, spathulenol (15.7%) was the most abundant component. Ninety-six volatile flavor constituents were detected in the essential oil of chamchwi. Epi-bicyclosesquiphellandrene (21.9%) was the most abundant component, followed by ${\beta}$-caryophyllene (9.5%) and ${\delta}$-terpinene (8.9%). The essential oil composition of gaemichwi was characterized by a higher contents of pinenes. The essential oil composition of gomchwi can be easily distinguished by the percentage of aromadendrene. Spathulenol and epi-bicyclosesquiphellandrene were regarded as the characteristic odorants of miyeokchwi and chamchwi, respectively.

Multi-component $ZnO-In_2O_3-SnO_2$ thin films deposited by RF magnetron co-sputtering

  • Lee, Byoung-Hoon;Hur, Jae-Sung;Back, Sang-Yul;Lee, Jeong-Seop;Song, Jung-Bin;Son, Chang-Sik;Choi, In-Hoon
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
    • /
    • 2006.10a
    • /
    • pp.68-71
    • /
    • 2006
  • Multi-component $ZnO-In_2O_3-SnO_2$ thin films have been prepared by RF magnetron co-sputtering using targets composed of $In_3Sn_4O_{12}$(99.99%) [1] and ZnO(99.99%) at room temperature. $In_3Sn_4O_{12}$ contains less In than commercial ITO, so that it lowers cost. Working pressure was held at 3 mtorr flowing Ar gas 20 sccm and sputtering time was 30 min. RF power ratio [RF1 / (RFI + RF2)] of two guns in sputtering system was varied from 0 to 1. Each RF power was varied $0{\sim}100W$ respectively. The thickness of the films was $350{\sim}650nm$. The composit ion concentrations of the each film were measured with EPMA, AES and XPS. The low resistivity of $1-2\;{\times}\;10^3$ and an average transmittance above 80% in the visible range were attained for the films over a range of ${\delta}\;(0.3\;{\leq}\;{\delta}\;{\leq}\;0.5)$. The films also showed a high chemical stability with time and a good uniformity.

  • PDF

KIC 6220497: A New Algol-type Eclipsing Binary with δ Sct Pulsations

  • Lee, Jae Woo
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.41 no.1
    • /
    • pp.41.1-41.1
    • /
    • 2016
  • We present the physical properties of KIC 6220497 exhibiting multiperiodic pulsations from the Kepler photometry. The light curve synthesis represents that the eclipsing system is a semi-detached Algol with a mass ratio of q=0.243, an orbital inclination of i=77.3 deg, and a temperature difference of ${\Delta}T=3,372K$, in which the detached primary component fills its Roche lobe by ~87% and is about 1.6 times larger than the lobe-filling secondary. To detect reliable pulsation frequencies, we analyzed separately the Kepler light curve at the interval of an orbital period. Multiple frequency analyses of the eclipse-subtracted light residuals reveal 32 frequencies in the range of $0.75-20.22d^{-1}$ with semi-amplitudes between 0.27 and 4.55 mmag. Among these, four frequencies ($f_1$, $f_2$, $f_5$, $f_7$) may be attributed to pulsation modes, while the other frequencies can be harmonic and combination terms. The pulsation constants of 0.16-0.33 d and the period ratios of $P_{pul}/P_{orb}=0.042-0.089$ indicate that the primary component is a ${\delta}$ Sct pulsating star in p modes and, thus, KIC 6220497 is an oscillating eclipsing Algol (oEA) star. The dominant pulsation period of about 0.1174 d is considerably longer than the values given by the empirical relations between the pulsational and orbital periods. The surface gravity of log $g_1=3.78$ is significantly smaller than those of the other oEA stars with similar orbital periods. The pulsation period and the surface gravity of the pulsating primary demonstrate that KIC 6220497 would be the more evolved EB, compared with normal oEA stars.

  • PDF

Molecular Theory of Superplastic Deformation (초소성변형의 분자론)

  • Chang Hong Kim;Taikyue Lee
    • Journal of the Korean Chemical Society
    • /
    • v.23 no.4
    • /
    • pp.217-236
    • /
    • 1979
  • The author's theory for plastic deformation was applied to superplastic alloys (Zn-Al eutectoid, Al-Cu, Pb-Sn, Sn-Bi, Mg-Al eutectics). The plastic deformation of the superplastic alloys could be described by two Maxwell models connected in parallel which represent two grain boundary flow units. The flow units are characterized by the two parameters $X_{gj}/{\alpha}_{gj}\;and\;{\beta}_{gj}$ (j=l or 2, g signifies the grain boundary) the values of which were obtained by applying our flow equation [Eq. (5)] to experiment. We confirmed that our flow equation describes the superplasticity very well. The curve of strain rate sensitivity m (=${\partial}\;In\;f/{\partial}\;In\;\dot{s})\;vs.\;-In\dot{s}$, where f and s are stress and strain rate, respectively, showed two peaks corresponding to flow unit gl and g2, the separation of the two peaks is determined by the difference between ${\beta}_{g1}\;and\;{\beta}_{g2}$. The condition of superplasticity is also determined by ${\beta}_{gj}$, which satisfies $\dot{s}_{mj}{\leqslant}1.53}{\beta}_{gj}$ [Eq.(13)], where $\dot{s}_{mj}$ is the s of the jth unit at the peak. The grain size dependence of ${\beta}_{gj}$ is described by $ln({\beta}_{gj})^{-1}$=alnx+b [Eq. (16)], where x is the grain size, and a and b are constants. The activation enthalpy for each flow unit, ${\Delta}H_{gj}^{\neq}$ was also determined from the temperature dependence of ${\beta}_{gj}$ which is proportional to the relaxation time of the j th unit. Since the superplasticity is determined by Eq. (13), and since ${\beta}_{gj}$ and ${\Delta}H_{gj}^{\neq}$ are related, we obtained the conclusion that superplasticity occurs in the system having small ${\Delta}H_{gj}^{\neq}$ values. The Aej values were equal to the activation enthalpies of grain boundary self-diffusion of the component atoms of the alloys, this accords with our proposed flow mechanism. The ${\Delta}H_{gj}^{\neq}$ value increases with grain size as expected from Eq. (16).

  • PDF

Effects of Paf1 complex components on H3K4 methylation in budding yeast (출아효모에서 Paf1 복합체의 구성원들이 H3의 네번째 라이신의 메틸화에 미치는 영향)

  • Oh, Jun-Soo;Lee, Jung-Shin
    • Korean Journal of Microbiology
    • /
    • v.52 no.4
    • /
    • pp.487-494
    • /
    • 2016
  • In Saccharomyces cerevisiae, Paf1 complex consists of five proteins, and they are structurally and functionally well conserved in yeast, fruit fly, plants, and human. With binding to RNA polymerase II from transcription start site to termination site, Paf1 complex functions as a platform for recruiting many types of transcription factors to RNA polymerase II. Paf1 complex contributes to H2B ubiquitination and indirectly influences on H3K4 di- and tri-methylation by histone crosstalk. But the individual effects of five components in Paf1 complex on these two histone modifications including H2B ubiquitination and H3K4 methylation largely remained to be identified. In this study, we constructed the single-gene knockout mutants of each Paf1 complex component and observed H3K4 mono-, di-, and trimethylation as well as H2B ubiquitination in these mutants. Interestingly, in each ${\Delta}paf1$, ${\Delta}rtf1$, and ${\Delta}ctr9$ strain, we observed the dramatic defect in H3K4 monomethylation, which is independent of H2B ubiquitination, as well as H3K4 di- and trimethylation. However, the protein level of Set1, which is methyltransferase for H3K4, was not changed in these mutants. This suggests that Paf1 complex may directly influence on H3K4 methylation by directly regulating the activity of Set1 or the stability of Set1 complex in an H2B ubiquitination independent manner.

A Study on the Ion-exchange Characteristics of Zeolites(A, 13X, Y, Mordenite, Chabazite) (제올라이트(A, 13X, Y, Mordenite, Chabazite)의 이온교환특성 연구)

  • An, Jin-Soo;Seo, Chung-Seok;Lee, Yong-Rae;Chun, Kwan-Sik;Park, Hyun-Soo
    • Applied Chemistry for Engineering
    • /
    • v.5 no.6
    • /
    • pp.949-956
    • /
    • 1994
  • The objective of this study is to experimentally investigate the ion exchange characteristics of five types of Zeolite(Zeolite-A, 13X, Y, Mordenite, Chabazite) for effective removal of Cs, Sr and Co ions in water solution at low concentration(0.01 N and 0.005 N). Total ion exchange capacity and equilibrium isotherm are measured, and free-energy change(${\Delta}G^0$) and enthalpy change(${\Delta}H^0$) in ion exchange reaction are calculated from experimental results. In addition the ion exchange equilibrium in the three-component system for three types of zeolite showing better efficiency is measured and plotted in triangle coordinates. It is shown from experimental results that the magnitude of free-energy change increases with the increasing ion selectivity, and the difference of free energy change between ions correlates closely with that of ion selectivity. The results also shows that Chabazite is effective for the adsorption of Cs ion, and Zeolite-A and Zeolite-13X for that of Sr and Co ions.

  • PDF

Food Sources of the Ascidian Styela clava Cultured in Suspension in Jindong Bay of Korea as Determined by C and N Stable Isotopes (탄소 및 질소안정동위원소 조성에 의한 남해안 진동만 양식 미더덕의 먹이원 평가)

  • Moon, Changho;Park, Hyun Je;Yun, Sung Gyu;Kwak, Jung Hyun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
    • /
    • v.19 no.4
    • /
    • pp.302-307
    • /
    • 2014
  • To examine the trophic ecology of the ascidian Styela clava in an aquaculture system of Korea, stable carbon and nitrogen isotopes were analyzed monthly in S. clava, coarse ($>20{\mu}m$, CPOM) and fine particulate organic matters ($0.7<<20{\mu}m$, FPOM). CPOM (means: $-18.5{\pm}1.2$‰, $9.3{\pm}0.7$‰) were significantly higher ${\delta}^{13}C$ and ${\delta}^{15}N$ values than those ($-20.5{\pm}1.5$‰, $8.4{\pm}0.5$‰) of FPOM. S. clava had mean ${\delta}^{13}C$ and ${\delta}^{15}N$ values of $-18.9({\pm}1.7)$‰ and $11.6({\pm}0.7)$‰, respectively. S. clava were more similar to seasonal variations in ${\delta}^{13}C$ and ${\delta}^{15}N$ values of FPOM than those of CPOM, suggesting that they rely largely on the FPOM as a dietary source. In addition, our results displayed that the relative importance between CPOM and FPOM as dietary source for the ascidians can be changed according to the availability of each component in ambient environment, probably reflecting their feeding plasticity due to non-selective feeding irrespective of particle size. Finally, our results suggest that dynamics of pico- and nano-size plankton (i.e., FPOM) as an available nutritional source to S. clava should be effectively assessed to maintain and manage their sustainable aquaculture production.

모세관 전기이동을 이용한 ${\delta}$-Aminolevulinc acid와 Porphobilinogen의 분리

  • Kim, Jin-Nam;Yun, Jong-Seon;Ryu, Hwa-Won
    • 한국생물공학회:학술대회논문집
    • /
    • 2000.04a
    • /
    • pp.512-515
    • /
    • 2000
  • In this study, ${\delta}-aminolevulinic$ acid, porphobilinogen, glycine and levulinic acid were succesfully separated by capillary electrophoresis(CE). We established the separative conditions of the mixture containing four components by CE. The borate buffered solution was used for CE electrolyte, and its pH was adjusted to $9.25{\sim}9.42$. Under constant current or constant voltage, higher concentraion of borate produced better resolution of four components, but adversely affected migration rates , resulting in longer analysis time. While migration time was faster with increase in applied voltage, but adversely affected resolution. Each component was separated well in borate buffer of 30mM at the applied voltage of 20kV.

  • PDF