• Title/Summary/Keyword: ${\beta}-mixing$

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Enzymatic Hydrolysis of Hydrophobic Triolein by Lipase in a Mone-phase Reaction System Containing Cyclodextrin; Reaction Characteristics

  • Lee, Yong-Hyun;Kim, Tae-Kwon;Shin, Hyun-Dong;Park, Dong-Chan
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.3 no.2
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    • pp.103-108
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    • 1998
  • A hydrophobic substrate triolein was hydrolyzed by lipase in a mono-phase reaction system containing cyclodextrin(CD) as emulsifier. The triolein was transformation to an emulsion-like state in the CD containing reaction system in contrast to the oil-droplet like state without CD due to the formation of an inclusion complex between the lipids and CDs. The hydyrolysis reaction increased substantially in the CD containing reaction system, and the optimum reaction conditions including the amount of lipase, ${\beta}$-CD concentration, and mixing ratio of triolein and ${\beta}$-CD, were determined. The performance of the enzyme reaction in a mono-phase reaction system was compared with that of a two-phase reaction system which used water immiscible hexane as the organic solvent. The role of a CD in the mono-phase reaction system was elucidated by comparing the degree of the inclusion complex formation with triolein and oleic acid, Km and Vmax values, and product inhibition by oleic aicd in aqueous and CD containing reaction systems. The resulting enhanced reaction seems to be caused by two phenomena; the increased accessibility of lipase to triolein and reduced product inhibition by oleic acid through the formation of an inclusion complex.

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Synthesis of SiC Nanoparticles by a Sol-Gel Process (나노 실리카와 카본블랙이용 탄화열 반응으로 나노 SiC 합성 및 특성)

  • Jeong, Kwang-Jin;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.23 no.4
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    • pp.246-249
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    • 2013
  • Nano-sized ${\beta}$-SiC nanoparticles were synthesized combined with a sol-gel process and a carbothermal process. TEOS and carbon black were used as starting materials for the silicon source and carbon source, respectively. $SiO_2$ nanoparticles were synthesized using a sol-gel technique (Stober process) combined with hydrolysis and condensation. The size of the particles could be controlled by manipulating the relative rates of the hydrolysis and condensation reactions of tetraethyl orthosilicate (TEOS) within the micro-emulsion. The average particle size and morphology of synthesized silicon dioxide was about 100nm and spherical, respectively. The average particles size and morphology of the used carbon black powders was about 20nm and spherical, respectively. The molar ratio of silicon dioxide and carbon black was fixed to 1:3 in the preparation of each combination. $SiO_2$ and carbon black powders were mixed in ethanol and ball-milled for 12 h. After mixing, the slurries were dried at $80^{\circ}C$ in an oven. The dried powder mixtures were placed in alumina crucibles and synthesized in a tube furnace at $1400{\sim}1500^{\circ}C$ for 4 h with a heating rate of $10^{\circ}C$/min under flowing Ar gas (160 cc/min) and furnace cooling down to room temperature. SiC nanoparticles were characterized by XRD, TEM, and SAED. The XRD results showed that high purity beta silicon carbide with excellent crystallinity was synthesized. TEM revealed that the powders are spherical shape nanoparticles with diameters ranging from 15 to 30 nm with a narrow distribution.

Characteristics of Nano-Sized, α-2ZrO2·P2O5 Powder Prepared by Polyvinyl Alcohol Solution Method (Polyvinyl Alcohol 용액법에 의해 제조된 나노크기 α-2ZrO2·P2O5 분말의 특성 연구)

  • Ma, Chung-Il;Lee, Sang-Jin
    • Korean Journal of Materials Research
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    • v.27 no.4
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    • pp.179-183
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    • 2017
  • $2ZrO_2{\cdot}P_2O_5$ powder, which is not synthesized by solid reaction method, was successfully synthesized through PVA solution method. In this process, the firing temperature and the PVA content strongly affected the crystallization behavior and final particle size. A stable ${\alpha}$-phase $2ZrO_2{\cdot}P_2O_5$ was synthesized at a firing temperature of $1200^{\circ}C$ and holding time of 4 h. ${\beta}$-phase $2ZrO_2{\cdot}P_2O_5$ was observed, with un-reacted $ZrO_2$ phases, for firing temperatures lower than $1200^{\circ}C$. In terms of the PVA content effect, the powder prepared with a PVA mixing ratio of 12:1 showed stable ${\alpha}$-phase $2ZrO_2{\cdot}P_2O_5$; however, the ${\beta}$-phase was found to co-exist at relatively higher PVA content. The synthesized ${\alpha}$-phase $2ZrO_2{\cdot}P_2O_5$ powder showed an average particle size of 100~250 nm and an average thermal expansion coefficient of $-2.5{\times}10^{-6}/^{\circ}C$ in the range of room temp. ${\sim}800^{\circ}C$.

Infrared Spectroscopy and Differential Scanning Calorimetry of Silk Fibroin/Hyaluronic Acid Blend Film (견피브로인/히아론산 브렌드 필름의 적외선 분광 분석 및 시차열분석)

  • Kweon HaeYong;Lee Kwang-Gill;Yeo Joo-Hong;Woo SoonOk;Han SangMi;Lee Yong Woo;Lee Jang Hern;Park Young Hwan
    • Journal of Sericultural and Entomological Science
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    • v.46 no.1
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    • pp.28-31
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    • 2004
  • Bombyx mori silk fibroin/hyaluronic acid blend films were prepared by mixing aqueous solution of B. mori silk fibroin and hyaluronic acid. According to the FTIR spectra, no interaction between silk fibroin and hyaluronic acid was found. The conformation of silk fibroin in blend films was changed from random coil to $\beta$-sheet structure by treatment of EDC ethanol solution. Thermal degradation peak of silk fibroin and hyaluronic acid was also not altered by blending each other. The average swelling ratio of silk fibroin/hyaluronic acid blend films was 70. Therefore, silk fibroin/hyaluronic acid blend films might be one of possible wound dressing materials.

Immunomodulatory effects of β-1,3/1,6-glucan and lactic acid bacteria in LP-BM5 murine leukemia viruses-induced murine acquired immune deficiency syndrome (면역결핍 모델에서 β-1,3/1,6-glucan과 유산균을 이용한 in vivo 면역 활성 조절 효과)

  • Kim, Min-Soo;Kim, JoongSu;Ryu, Min Jung;Kim, Ki hong;Hwang, Kwontack
    • Food Science and Preservation
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    • v.24 no.8
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    • pp.1158-1167
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    • 2017
  • In this study, ${\beta}$-1,3/1,6-glucan, lactic acid bacteria, and ${\beta}$-1,3/1,6-glucan+lactic acid bacteria were tested for 10 weeks using an immunodeficient animal model infected with LP-BM5 murine AIDS virus On the immune activity. Cytokines production, plasma immunoglobulin concentration, T cell and B cell proliferation were measured. As a result, the T cell proliferative capacity which was weakened by immunization with LP-BM5 murine AIDS virus increased significantly T cell proliferative capacity compared with the red ginseng control group. B cell proliferative capacity was significantly higher than the infected control group. Increased B cell proliferation was reduced. In the cytokine production, IL-2, IL-12 and IL-15 in the Th1-type cytokine increased the secretion of IL-2, IL-12 and IL-15 compared to the infected control. The proliferative capacity of the treated group was higher than that of the mixed treatment group. TNF-${\alpha}$ was significantly decreased compared with the infected control group. The IL-4, IL-6 and IL-10 levels were significantly inhibited in the infected control group and the Th1/Th2 type cytokine expression was regulated by immunohistochemistry. IgE, IgA, and IgG levels were significantly lower in the immunoglobulin secretion assay than in the control. As a result, the immunomodulatory effect of ${\beta}$-1,3/1,6-glucan+lactic acid bacteria was confirmed by mixing with LP-BM5 murine AIDS virus-infected immunodeficient animal model.

Effect of Carrot Juice on Enzymatic Browning of Potato Juice (당근 쥬스가 감자 쥬스의 효소적 갈변 반응에 미치는 영향)

  • 김미정;이창용
    • Korean journal of food and cookery science
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    • v.9 no.3
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    • pp.181-186
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    • 1993
  • Potato and carrot are the main sourses of vitamin C and vitamin A each. As a folk ramedy, potato-carrot mixtures have been used to cure a stomach ulcer in Korea. To investigate the effects of carrot juice on the browning of potato juice, we examined the brewing in various ratio of two juices. We also investigated the role of potato juice in the carotene oxidation of carrot juice. Delta "L" values of potato juice were abruptly decreased after 5 min. reaction and they were very different from the juice mixture of potato and carrot. Those containing higher ratio of potato were decreased greatly. In blanching treatment to eliminate the effect of the enzymes in potato and carrot, delta "L" values of cooked potato were decreased a little but those of cooked carrot were decreased greatly. To investigate the fact that the inhibitory effect of carrot juice in potato browning was due to the dilution of polyphenolics of potato juices by carrot juice mixing, we added H20 equivalent to carrot water content to potato juice. The diluted sample showed less decreasing pattern than nondiluted sample. We also added appropriate amount of ${\beta}$-carotene to the same samples. Delta "L" values of with added B-carotene were more slowly decreased than those of without added B-carotene.

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Electrorheological Properties of Phosphoric Ester Cellulose ER Fluids on the Elevated Temperature (온도 변화에 따른 인산 에스테르 셀룰로오스 ER 유체의 전기유변학적 특성)

  • 안병길;오경근;최웅수;권오관
    • Tribology and Lubricants
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    • v.15 no.1
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    • pp.8-16
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    • 1999
  • The electrorheological (ER) behavior of suspensions in silicone oil of phosphoric ester cellulose powder (average particle size : 18$\pm$1 ${\mu}{\textrm}{m}$) was investigated on the elevated temperature up to 10$0^{\circ}C$. For development of anhydrous ER fluids using at wide temperature range, it should be researched to how the effect of temperature on the ER activities. As a first step, the anhydrous ER suspensions mixing with the phosphoric ester cellulose particles which were made from the phosphoric ester reaction of cellulose were measured. As increasing the temperature, not only the analysis of electrical properties such as dielectric constant current density and electrical conductivity but also the rheological properties of ER fluids were studied. From the experimental results, the temperature had a large influence to the ER properties of anhydrous ER fluids. The current density, conductivity and elecoorheological effect ($\tau$$_{A}$$\tau$$_{0}$) of phosphoric ester cellulose ER fluids were proportional to the temperature with power law. And the shear stress of them was closely related with the square of dielectric constant mismatch parameter ($\beta$$^2$) under constant shear rate and electric field.d.

Fabrication of Cu-Zn Alloy Nano Powders by Wire Explosion of Electrodeposited Wires (도금선재의 전기선폭발을 이용한 Cu-Zn 합금 나노분말 제조)

  • Kim, Won-Baek;Park, Je-Shin;Suh, Chang-Yeul;Lee, Jae-Chun;Oh, Yong-Jun;Mun, Jeong-Il
    • Journal of Powder Materials
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    • v.14 no.1 s.60
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    • pp.38-43
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    • 2007
  • Cu-Zn alloy nano powders were fabricated by the electrical explosion of Zn-electroplated Cu wire along with commercial brass wire. The powders exploded from brass wire were composed mainly of ${\alpha},{\beta},\;and\;{\gamma}$ phases while those from electroplated wires contained additional Zn-rich phases as ${\varepsilon}$, and Zn. In case of Zn-elec-troplated Cu wire, the mixing time of the two components during explosion might not be long enough to solidify as the phases of lower Zn content. This along with the high vapor pressure of Zn appears to be the reason for the observed shift of explosion products towards the high-Zn phases in electroplated wire system.

A Study On the Structure and Mechanical Properties of Polypropylene filament treated with Dry heat treatment at Different draw ratio (연신비를 달리한 Polypropylene filament의 건열처리에 따른 구조와 물성에 관한 연구)

  • Lee, Eun-Woo;Cho, In-Sul
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.61-68
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    • 1999
  • The variety of crystalline structure and mechanical properties of PP filament treated with dry heat treatment at different draw ratio has been studied. Crystalline structure and mechanical properties of annealed PP filament at different draw ratio has been examined by XRD, UTM, and density method. Heat treatment has been carried out $100^{\circ}C$, $120^{\circ}C$ $140^{\circ}C$ for 30min. in dry oven. From the results of this study, it found the following facts. It was found that the crystallinity and crystallite size of (110) plane of sample were increased with increasing of annealed temperature and draw ratio. The crystalline form of annealed sample which was undrawn showed ${\alpha}$, ${\beta}$ mixing form below $120^{\circ}C$ and showed ${\alpha}$ form at $140^{\circ}C$. But the crystalline form of annealed sample which was drawn showed ${\alpha}$ form at $120^{\circ}C$. Initial modulus and tensile strength were increased with increasing of annealing temperature, and the degree of orientation was decreased with decreasing of annealing temperature.

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Polymer Base Bored Pile in Bangkok Subsoils

  • Teparaksa, Wanchai
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.407-426
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    • 2008
  • The bentonite slurry has been used as the stabilize suspension for wet process bored pile construction in Thailand. The bentonite suspension has benefit on filtration in the sand layer, but it creates thick cake film along pile shaft and loose sedimentation at pile toe. The base grouting technique was widely used to rectify the soft base or loose sedimentation problem of bored pile. The base grouting technique was not increased only end bearing capacity, but was also more increase in skin friction capacity of the bored piles. The comprehensive researches on base grouting was carried out by installing PVC casing inside the shaft to allow the drilling through the pile base in order to collect the soil sample below the pile tip. The polymer based slurry recently was used to replace the bentonite slurry to overcome the thick cake film along pile shaft as well as loose sedimentation at pile toe. The extent research on polymer slurry by physical model was performed to verify the real behavior of polymer. The appropriate mixing ratio of polymer was proposed. The design skin friction coefficient, $\beta$ and end bearing coefficient, Nq, for sand layer base on fully instrumented tested pile were proposed. The application on remedial of the lose capacity bored pile with large displacement in Bangladesh was proposed and discussed.

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