• Title/Summary/Keyword: ${\alpha}_i$-properties

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$\alpha$-D-Glucosidase Inhibitor from Streptomyces sp. (I) - Identification of the Strain - (Streptomyces속 균주가 생성하는 $\alpha$-D-Glucosidase Inhibitor( I ) -균주의 동정 -)

  • 도재호;주현규
    • Microbiology and Biotechnology Letters
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    • v.17 no.3
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    • pp.202-206
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    • 1989
  • A microorganism, YS-221-B strain which powerfully produced $\alpha$-D-Glucosidase Inhibitor was isolated from soil. The morphological, cultural characteristics and physiological properties of the strain were investigated. As the results of various examinations, the strain YS-221-B was identified to be similar to Streptomyces flavouirens except the utilization of raffinose, i-inositol among the various carbon sources.

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Rheological Properties of the Solutions of Incompatible Polymer Blends

  • Sohn, Jeong-In;Ree, Taik-Yue
    • Bulletin of the Korean Chemical Society
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    • v.2 no.4
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    • pp.142-147
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    • 1981
  • A blend polymeric system composed of poly(methyl methacrylate) (PMMA or PM) and polystyrene (PS) dissolved in chloroform was rheologically studied. The viscosities ${\eta}_{bl}$ of the blend system with various blending ratios ${\chi}$ changing from zero (pure PS solution) to unity (pure PMMA solution) were measured at $25{\circ}C$ as a function of shear rates ${\dot{s}}$ by using a Couette type viscometer. ${\eta}_{bl}$ at a given ${\dot{s}}$ decreased exponentially with ${\chi}$ reaching asymptotic constant value of ${\eta}_{bl}$ ; ${\eta}_{bl}$ at a given ${\chi}$ is greater at a smaller ${\dot{s}}$. These results are explained by using Ree-Erying's theory of viscosity, ${\eta}_{bl}=(x_1{\beta}_1/{\alpha}_1)_{b}_1+ (x_2{\beta}_2/{\alpha}_2)_{bl}[sinh^{-1}{\beta}_2(bl) {\dot{s}}]/{\beta}_2(bl){\dot{s}}$. The Gibbs activation energy ${\Delta}G_i^\neq$(i = 2 for non-Newtonian units) entering into the intrinsic relaxation time ${\beta}$ is represented by a linear combination ${\Delta}G_i^\neq(bl) ={\chi}{\Delta}G_i^{\neq}_{iPM}+(1-{\chi}){\Delta}G_i^{\neq}_{iPS}$;the intrinsic shear modulus$[[\alpha}_i]^{-1}$ is also represented by $[{\alpha}_i(bl)]^{-1}={\chi}[{\alpha}_{iPM}]^{-1}+(1-{\chi})[{\alpha}_{iPS}]^{-1}$ and the fraction of area on a shear surface occupied by the ith flow units $x_i(bl)$ is similarly represented, i.e., $x_i(bl) = {\chi}x_{iPM}+(1-{\chi})x_{iPS}$. By using these ideas the Ree-Eyring equation was rewritten which explained the experimental results satisfactorily.

Materials Development in α-Sialon Ceramics

  • Mitomo Mamoru;Xie Rong-Jun;Hirosaki Naoto
    • Journal of the Korean Ceramic Society
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    • v.43 no.8 s.291
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    • pp.451-457
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    • 2006
  • The solid solutions of ${\alpha}-Si_3N_4$, i.e. ${\alpha}$-sialons, are represented by a general formula of $M_x(Si,Al)_{12}(O,N)_{16}$, in which metal ions (M) dissolve into interstitial sites to stabilize the structure. Processing methods for the fabrication of ${\alpha}/{\beta}$-sialon composites, ${\alpha}-sialon/{\beta}Si_3N_4$ composites, refractory or tough ${\alpha}$-sialon ceramics have been developed to tailor the mechanical properties. Translucent and photoluminescent properties have been investigated recently. A number of applications of ${\alpha}$-sialon ceramics as engineering and optical ceramics are also presented.

Physical ppropperties in Rare-earth Compounds

  • Takashi, Suzuki
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.18-18
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    • 1998
  • F First I will introduce our works how to improve the crystal growth t technique for Rare earth pnictides and chalcogenides. All these substances h have hi양1 vapor pressure and high melting print up to 3$\alpha$)()C. 까len we employ m the tungsten or molybden crucibles and enclose the sample by 빼e welding of m the lid with high current electron beam. We cannot elevate the temperature up t to 3$\alpha$)()C without suitable radiation shield because rate of radiation loss r rapidly increase in such a high temperature regions. There were no good r radiation shield but we discovered that the p-BN could work as an excellent r radiation shield after checking of the many substances. S Secondly I will show several interesting and unusual 뻐ysical properties of obtained crystals under high magnetic field, hi양1 pressure and also i including angle resolve photoemission spectroscopy. I will stress the p properties of the low carrier concentration with strong correlation on C댐, U USb and Yb4As3

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${\alpha},{\omega}$-Bis[4-(4'(S)-(+)-2-methylbutylbiphenyl-4-carboxy)phenoxy]alkanes-Synthesis and Liquid Crystalline Properties of New Dimesogenic Compounds (${\alpha},{\omega}$-비스[4-(4'-(S)-(+)-2-메틸부틸비페닐-4-카르복시)페녹시]알칸 -새로운 디메소겐 화합물의 합성 및 액정성)

  • Kim, Jae Hoon;Lee, Soo Min;Jin, Jung Il
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.679-695
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    • 1998
  • A series of ${\alpha}{\omega}-bis[4-(4'-(S)-(+)-2-methylbutylbiphenyl-4-carboxy)phenoxy]alkanes$, were synthesized, and their thermal and liquid crystalline properties were studied. The chain length of the central polymethylene spacers, x, of the chiral twin compounds was varied from 3 to 12. These compounds were characterized by elemental analysis, IR and NMR spectroscopy, differential thermal analysis (DSC), and crosspolarized microscopy. All compounds were found to be enantiotropic liquid crystalline, and the values of melting $(T_m)$ and isotropization temperature $(T_i)$ as well as ${\delta}H_I$ and ${\delta}S_I$ decreased in a zig-zag fashion, revealing the so called odd-even effect as x increased. Their mesomorphic properties fell into four categories depending upon x; (a) compounds with x=3, 4 and 5 formed only a cholesteric phase on heating, while on cooling they went through two transitions of isotropic (I)-to-cholesteric (Ch) and Ch-to-smectic $A\;(S_A)$ phases before crystallization. (b) compounds with x=6, 8 and 10 exhibited only a cholesteric phase both on heating and on cooling. (c) compounds with x=7 and 9 went through three transitions of crystal $(C)-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases on heating while on cooling they went through four transitions of I-to-Ch, $Ch-to-S_A,\;S_A-to-Smectic\;C\;(S_C),\;and\;S_c-to-C$ phases in that order, and (d) compounds with x=11 and 12 went reversibly through four transitions of $C-to-S_C,\;S_C-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases.

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A CLASS OF ARITHMETIC FUNCTIONS ON PSL2(ℤ), II

  • Spiegelhalter, Paul;Zaharescu, Alexandru
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.2
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    • pp.443-455
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    • 2014
  • Atanassov introduced the irrational factor function and the strong restrictive factor function, which he defined as $I(n)=\displaystyle\prod_{p^{\alpha}||n}^{}p^{1/{\alpha}}$ and $R(n)=\displaystyle\prod_{p^{\alpha}||n}^{}p^{{\alpha}-1}$ in [2] and [3]. Various properties of these functions have been investigated by Alkan, Ledoan, Panaitopol, and the authors. In the prequel, we expanded these functions to a class of elements of $PSL_2(\mathbb{Z})$, and studied some of the properties of these maps. In the present paper we generalize the previous work by introducing real moments and considering a larger class of maps. This allows us to explore new properties of these arithmetic functions.

Polymeric Acetate-Selective Electrodes Based on meso-(α,α,α,α)-Tetrakis-[(2-arylphenylurea)phenyl]porphyrins: Electormic and pH Effects

  • Lee, Hyo-Kyoung;Song, Ki-ju;Seo, Hyung-Ran;Jeon, Seung-won
    • Bulletin of the Korean Chemical Society
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    • v.23 no.10
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    • pp.1409-1412
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    • 2002
  • Polymeric membrane electrodes for acetate anion based on meso-(${\alpha}$,${\alpha}$,${\alpha}$,${\alpha}$)-5,10,15,20-tetrakis[2-(penta-fluorophenylurea) phenyl]porphyrin I and similar urea-functionalized porphyrins Ⅱ-Ⅳ as neutral ionophores were prepared. The membrane based on porphyrin I exhibits the best potentiometric properties in pH 6.0 rather than pH 7.0: linear stable response over a wide concentration range (6.0 ${\times}$$10^{-5}$-1.0 ${\times}$$10^{-2}$) with a slope of -59.6 mV/decade and a detection limit of log[CH3CO$O^-$] = -5.32. Selectivity coefficients obtained from the matched potential method (MPM) in pH 6.0 indicate that interferences of hydrophobic anions are very small for the membranes of porphyrins I and II having the strong withdrawing group. The electronic effect of urea-functionalized porphyrins and pH effect of buffer solutions are discussed on the potentiometric response.

EXCITED-STATE TWISTED INTRAMOLECLILAR CHARGE TRANSFER OF p-N,N-DIMETHYLAMINOBENZOIC ACID IN AQUEOUS CYCLODEXTRIN SOLUTIONS: TIME-RESOLVED FLUORESCENCE STUDY

  • Kim, Yong-Hee;Cho, Dae-Won;Yoon, Min-Joong
    • Journal of Photoscience
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    • v.3 no.3
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    • pp.153-158
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    • 1996
  • The effects of $\alpha$- and $\beta$-cyclodextrins (CD) on the twisted intramolecular charge transfer (TICT) behavior of p-N,N'-dimethylaminobenzoic acid (DMABA) in buffered aqueous solution have been investigated by examining formation and decay behaviors of the TICT-typical dual fluorescence. The ratio of the TICT emission to the normal emission (I$_a$/I$_b$) increases linearly $\alpha$-CD concentration increases, while in the presence of $\beta$-CD it shows nonlinear dependences on the CD concentration. The analysis of the CD-dependent changes of the I$_a$/I$_b$ and absorption spectra demonstrates formation of 1:1 inclusion complexes between DMABA and CDs. The decay time of the normal emission (ca. 700 ps) is little affected by the formation of $\alpha$-CD inclusion complex, whereas it increases upto ca. 1.6 ns upon formation of $\beta$-CD inclusion complex. The TICT emission for the $\beta$-CD inclusion complex exhibits two decay components while it shows a single component for the $\alpha$-CD inclusion complex, indicating formation of one or two types of inclusion complex in the presence of $\alpha$-CD or $\beta$-CD, respectively. These results are attributed to the CD cavity size dependence on patterns of complexation between CDs and DMABA. The CD size dependences of the TICT fluorescence properties with the orientation of the guest molecule demonstrate that the specific hydrogen bonding between the carboxylic acid group and water plays an important role in the excited-state TICT.

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${\pi}G{\alpha}$-LOCALLY CLOSED SETS AND ${\pi}G{\alpha}$-LOCALLY CONTINUOUS FUNCTIONS

  • Rani, I. Arockia;Balachandran, K.;Janaki, C.
    • East Asian mathematical journal
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    • v.24 no.4
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    • pp.317-328
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    • 2008
  • In this paper we introduce ${\pi}G{\alpha}$-LC sets, ${\pi}G{\alpha}-LC^*$ sets and ${\pi}G{\alpha}-LC^{**}$ sets and different notions of generalizations of continuous functions in topological space and discuss some of their properties. Further we prove pasting lemma for ${\pi}G{\alpha}-LC^{**}$ continuous functions and ${\pi}G{\alpha}-LC^{**}$ irresolute functions.

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Adsorption Characteristic of Endo I and Exo II Purified from Cellulase by Trichoderma viride on Celluloses with Different Crystallinity (결정성이 다른 셀룰로오스에 대한 Trichoderma viride속 Cellulase로부터 분리한 Endo I 및 II의 흡착특성)

  • 김동원;홍영관;장영훈;이재국
    • KSBB Journal
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    • v.13 no.2
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    • pp.162-167
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    • 1998
  • The adsorption behaviors of two major cellulase components, endo I and exo II, from Trichoderma viride were investigated using $\alpha$-celluloses with different correlation crystallinity index(Cc) as substrates. The adsorption of cellulase enzyme components was significantly affected by the reaction condition and the physicochemical properties of the cellulose. The $\alpha$-cellulose was hydrolyzed in the presence of cellulase for various periods. The correlation crystallinity index of $\alpha$-cellulose increased with increasing the hydrolysis time. The adsorption was apparently found to obey the first-order kinetics, and the adsorption activation energy(Ea) was calculated from the adsorption rate constant(ka). The value of adsorption rate constant for endo I was larger than that of exo II. This means that endo I are adsorbed more rapidly than exo II. With the increase in correlation crystallinity index, the values of the adsorption rate constants for endo I and exo II decreased, respectively. The activation energy for the adsorption of exo II on the cellulose also was larger than that of endo I. Also adsorption activation energy of endo I and exo II increased with an increase in the crystallinity of sample cellulose.

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