• Title/Summary/Keyword: ${\alpha}$/${\beta}$ratio

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Studies on the Constituents of Ulmus parvifolia (참느릅나무의 성분에 관한 연구)

  • Moon, Young-Hee;Rim, Gi-Ryong
    • Korean Journal of Pharmacognosy
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    • v.26 no.1
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    • pp.1-7
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    • 1995
  • The bark of Ulmus parvifolia Jacq. (Ulmaceae) has been used for the treatment of gonorhea, edema, scabies and eczema marginatum. Previous investigations conducted with the heartwood and leaves have demonstrated it to contain sesquiterpenes as well as fat acids from the heartwood and flavonol glycosides from leaves. However, no phytochemical work has been done on the bark parts of this plant. Investigation of the phytochemical constituents in the barks of U. parvifolia has resulted in the isolation of sterols, sterol glucoside and a catechin glycoside, $(+)-catechin\;7-O-{\alpha}-{_L}-rhamnopyranoside$, all of which were isolated for the first time from this plant. Sterols were consisted of the three components, ${\beta}-sitosterol$, stigmasterol and campesterol in a ratio of 92.1:4.1:3.8, and sterol glucoside was identified as ${\beta}-sitosterol\;3-O-{\beta}-{_D}-glucoside$. The structure of the catechin $7-O-{\alpha}-{_L}-rhamnoside$ was established primarily by analysis of $^1H-and$ COSY-45 NMR, HMQC and HMBC and EI mass spectra of the heptaacetate. Especially, HMBC spectrum provides effective way for the determination of the point of attachment of the rhamnosyl group to catechin moiety.

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Principal Milk Components in Buffalo, Holstein Cross, Indigenous Cattle and Red Chittagong Cattle from Bangladesh

  • Islam, M.A.;Alam, M.K.;Islam, M.N.;Khan, M.A.S.;Ekeberg, D.;Rukke, E.O.;Vegarud, G.E.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.6
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    • pp.886-897
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    • 2014
  • The aim of the present study was to get a total physical and chemical characterization and comparison of the principal components in Bangladeshi buffalo (B), Holstein cross (HX), Indigenous cattle (IC) and Red Chittagong Cattle (RCC) milk. Protein and casein (CN) composition and type, casein micellar size (CMS), naturally occurring peptides, free amino acids, fat, milk fat globule size (MFGS), fatty acid composition, carbohydrates, total and individual minerals were analyzed. These components are related to technological and nutritional properties of milk. Consequently, they are important for the dairy industry and in the animal feeding and breeding strategies. Considerable variation in most of the principal components of milk were observed among the animals. The milk of RCC and IC contained higher protein, CN, ${\beta}$-CN, whey protein, lactose, total mineral and P. They were more or less similar in most of the all other components. The B milk was found higher in CN number, in the content of ${\alpha}_{s2}-$, ${\kappa}$-CN and ${\beta}$-lactalbumin, free amino acids, unsaturated fatty acids, Ca and Ca:P. The B milk was also lower in ${\beta}$-lactoglobulin content and had the largest CMS and MFGS. Proportion of CN to whey protein was lower in HX milk and this milk was found higher in ${\beta}$-lactoglobulin and naturally occuring peptides. Considering the results obtained including the ratio of ${\alpha}_{s1}-$, ${\alpha}_{s2}-$, ${\beta}$- and ${\kappa}$-CN, B and RCC milk showed best data both from nutritional and technological aspects.

A Study On the Structure and Mechanical Properties of Polypropylene filament treated with Dry heat treatment at Different draw ratio (연신비를 달리한 Polypropylene filament의 건열처리에 따른 구조와 물성에 관한 연구)

  • Lee, Eun-Woo;Cho, In-Sul
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.61-68
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    • 1999
  • The variety of crystalline structure and mechanical properties of PP filament treated with dry heat treatment at different draw ratio has been studied. Crystalline structure and mechanical properties of annealed PP filament at different draw ratio has been examined by XRD, UTM, and density method. Heat treatment has been carried out $100^{\circ}C$, $120^{\circ}C$ $140^{\circ}C$ for 30min. in dry oven. From the results of this study, it found the following facts. It was found that the crystallinity and crystallite size of (110) plane of sample were increased with increasing of annealed temperature and draw ratio. The crystalline form of annealed sample which was undrawn showed ${\alpha}$, ${\beta}$ mixing form below $120^{\circ}C$ and showed ${\alpha}$ form at $140^{\circ}C$. But the crystalline form of annealed sample which was drawn showed ${\alpha}$ form at $120^{\circ}C$. Initial modulus and tensile strength were increased with increasing of annealing temperature, and the degree of orientation was decreased with decreasing of annealing temperature.

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A Study on Sugars in Korean Sweet Rice Drink "Sikhye" -4. Glutinous Rice Sikhye- (식혜의 이소말토올리고당에 관한 연구 -4보 찹쌀식혜-)

  • 안용근
    • The Korean Journal of Food And Nutrition
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    • v.10 no.2
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    • pp.180-185
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    • 1997
  • Sikye was produced from glutinous rice. The glutinous rice Sikhye was found to contain 7.3% of limit dextrin, 10.1% of maltose, 1.3% of maltotriose and 1.75% of rice residue. Limit dextrin in glutinous rice Sikhye was purified by ethanol fractionation followed by gel chromatography on Biogel P-2. The purified limit dextrin showed both signal of $\alpha$-1,4- and $\alpha$-1,6-glucosidic linkage with its estimation ratio of 5:1 by 1H-NMR analysis. Limit dextrin was digested with enzymes(30units/ml) of $\alpha$-amylase, $\alpha$-glucosidase and glucoamylase from Aspergillus awamori, sweet potato $\beta$-amylase and human salivary $\alpha$-amylase at 37$^{\circ}C$ for 1 hour, respectively. Hydrolysis rates of these amylases on it were similar that of rice Sikhye. $\alpha$-Glucosidase plus human salivary $\alpha$-amylase hydrolyzed it to 18%. The results suggest that glutinous rice is more effective to produce high level of branched maltooligosaccharide compared with rice as raw material for Sikye making.

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CT Based 3-Dimensional Treatment Planning of Intracavitary Brachytherapy for Cancer of the Cervix : Comparison between Dose-Volume Histograms and ICRU Point Doses to the Rectum and Bladder

  • Hashim, Natasha;Jamalludin, Zulaikha;Ung, Ngie Min;Ho, Gwo Fuang;Malik, Rozita Abdul;Ee Phua, Vincent Chee
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.13
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    • pp.5259-5264
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    • 2014
  • Background: CT based brachytherapy allows 3-dimensional (3D) assessment of organs at risk (OAR) doses with dose volume histograms (DVHs). The purpose of this study was to compare computed tomography (CT) based volumetric calculations and International Commission on Radiation Units and Measurements (ICRU) reference-point estimates of radiation doses to the bladder and rectum in patients with carcinoma of the cervix treated with high-dose-rate (HDR) intracavitary brachytherapy (ICBT). Materials and Methods: Between March 2011 and May 2012, 20 patients were treated with 55 fractions of brachytherapy using tandem and ovoids and underwent post-implant CT scans. The external beam radiotherapy (EBRT) dose was 48.6Gy in 27 fractions. HDR brachytherapy was delivered to a dose of 21 Gy in three fractions. The ICRU bladder and rectum point doses along with 4 additional rectal points were recorded. The maximum dose ($D_{Max}$) to rectum was the highest recorded dose at one of these five points. Using the HDRplus 2.6 brachyhtherapy treatment planning system, the bladder and rectum were retrospectively contoured on the 55 CT datasets. The DVHs for rectum and bladder were calculated and the minimum doses to the highest irradiated 2cc area of rectum and bladder were recorded ($D_{2cc}$) for all individual fractions. The mean $D_{2cc}$ of rectum was compared to the means of ICRU rectal point and rectal $D_{Max}$ using the Student's t-test. The mean $D_{2cc}$ of bladder was compared with the mean ICRU bladder point using the same statistical test. The total dose, combining EBRT and HDR brachytherapy, were biologically normalized to the conventional 2 Gy/fraction using the linear-quadratic model. (${\alpha}/{\beta}$ value of 10 Gy for target, 3 Gy for organs at risk). Results: The total prescribed dose was $77.5Gy{\alpha}/{\beta}10$. The mean dose to the rectum was $4.58{\pm}1.22Gy$ for $D_{2cc}$, $3.76{\pm}0.65Gy$ at $D_{ICRU}$ and $4.75{\pm}1.01Gy$ at $D_{Max}$. The mean rectal $D_{2cc}$ dose differed significantly from the mean dose calculated at the ICRU reference point (p<0.005); the mean difference was 0.82 Gy (0.48-1.19Gy). The mean EQD2 was $68.52{\pm}7.24Gy_{{\alpha}/{\beta}3}$ for $D_{2cc}$, $61.71{\pm}2.77Gy_{{\alpha}/{\beta}3}$ at $D_{ICRU}$ and $69.24{\pm}6.02Gy_{{\alpha}/{\beta}3}$ at $D_{Max}$. The mean ratio of $D_{2cc}$ rectum to $D_{ICRU}$ rectum was 1.25 and the mean ratio of $D_{2cc}$ rectum to $D_{Max}$ rectum was 0.98 for all individual fractions. The mean dose to the bladder was $6.00{\pm}1.90Gy$ for $D_{2cc}$ and $5.10{\pm}2.03Gy$ at $D_{ICRU}$. However, the mean $D_{2cc}$ dose did not differ significantly from the mean dose calculated at the ICRU reference point (p=0.307); the mean difference was 0.90 Gy (0.49-1.25Gy). The mean EQD2 was $81.85{\pm}13.03Gy_{{\alpha}/{\beta}3}$ for $D_{2cc}$ and $74.11{\pm}19.39Gy_{{\alpha}/{\beta}3}$ at $D_{ICRU}$. The mean ratio of $D_{2cc}$ bladder to $D_{ICRU}$ bladder was 1.24. In the majority of applications, the maximum dose point was not the ICRU point. On average, the rectum received 77% and bladder received 92% of the prescribed dose. Conclusions: OARs doses assessed by DVH criteria were higher than ICRU point doses. Our data suggest that the estimated dose to the ICRU bladder point may be a reasonable surrogate for the $D_{2cc}$ and rectal $D_{Max}$ for $D_{2cc}$. However, the dose to the ICRU rectal point does not appear to be a reasonable surrogate for the $D_{2cc}$.

Study on Seasonal Variation Characteristics of Forest Phytoncide in Ulsan Metropolitan Trails (계절에 따른 울산지역 산책로의 피톤치드 특성연구)

  • Park, Heung Jai;Yu, Bong Gwan;Park, Sun Ho;Lee, Jin Yeol;Hahm, Yoo Sik;Jeong, Seong Wook;Byeon, Ki Yeong;Kim, So Hee;Jung, Im Su;Lee, Mi Lim
    • Journal of Environmental Science International
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    • v.22 no.11
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    • pp.1415-1419
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    • 2013
  • This study was conducted to investigate the seasonal variation characteristics of phytoncide in trail of Ulsan Metropolitan. Air samples were collected from May to December 2011. They were collected using Tenax Ta tube and phytoncides were detected and quantified using a Gas Chromatograph Mass Spectrometer (GC/MSD). This study are summarized as follows; The seasonal concentrations of phytoncide are Munsu Mt. 272.3 ${\mu}g/m^3$, Samho Mt. 192.4 ${\mu}g/m^3$, Shinbul Mt. 50.9 ${\mu}g/m^3$, Sibli Bamboo forest 22.4 ${\mu}g/m^3$ and Joongbu Fire Station 24.4 ${\mu}g/m^3$. In Munsu Mt., Samho Mt. and Shinbul Mt. major component ratio is ${\alpha}$-Pinene > ${\beta}$-Pinene+Myrcene >Limonene >Camphene > ${\gamma}$-Terpinene > ${\alpha}$-Terpinene. Bamboo forest and Joongbu fire station major component ratio is ${\alpha}$-Pinene >Limonene > ${\beta}$-Pinene+Myrcene >Camphene > ${\alpha}$-Terpinene. The variation of seasonal concentration is summer >spring >fall >winter. The phytoncide concentration of coniferous forest(Munsu Mt., Samho Mt.) is higher than broadleaf forest(Shinbul Mt.).

A Facile Synthesis of p-Nitrophenyl Glycosides

  • Yoon, Shin-Sook;Kim, Dong-Sung;Nam Shin, Jeong E.
    • Bulletin of the Korean Chemical Society
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    • v.15 no.7
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    • pp.559-563
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    • 1994
  • Glycosylation of benzoylated glycosyl halides of glucose, galactose and mannose with potassium p-nitrophenoxide and 18-crown-6 complex in chloroform resulted in the stereospecific formation of 1,2-trans p-nitrophenyl glycopyranosides in good yields. The same reaction with benzylated mannopyranosyl chloride gave the ${\alpha}-and\;{\beta}-p-nitrophenyl$ mannopyranosides in 3 : 1 ratio. However, acetylated 2-azido-altropyranosyl chloride gave ${\beta}-p-nitrophenyl$ altropyranoside only.

Effect of Sea Tangel Intake on Cytokine Production in Macrophage from Normal and Diabetic Mice (다시마섭취가 정상과 당뇨 생쥐 대식세포의 Cytokine 분비에 미치는 영향)

  • 조성희;양경미;배복선;임선아;유리나
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.5
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    • pp.952-959
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    • 1998
  • To investigate the effect of sea tangle on macrophage activity in normal and diabetic states, 10week old ICR mice were fed control(C) and sea tangle(S) diet containing 5%(w/w) cellulose and 13.6%(w/w) dry sea tangle for four weeks, after which two thirds of mice(CD and SD) were made diabetic by intramuscular injection of streptozotocin(150mg/kg bw). At 4th day after diabetes was apparent by urinary glucose, one half of diabetic mice(CDM and SDM) were treated with metformin(500mg/kg bw) orally. Peritoneal macrophages obtained from 3%-thioglycollate treated mice were cultured in the presence of lipopolysaccaride from Salmonella abortus equi(10$\mu\textrm{g}$/ml) for 24 hrs and tumor necrosis factor-$\alpha$(TNF$\alpha$), interleukin-1$\beta$(1L-1$\beta$)and prostaglandin E2(PGE2) were measured in culture media. Release of IL-1$\beta$and PGE2 from macrophage were increased in normal mice by sea tangle diet and had the same tedency in diabetic mice with or without metformin treatment although not statistically significant. Release of TNF$\alpha$ tended to be reduced by diabetes but were not changed significantly by sea tangle diet. Fatty acid compositions of macrophage and liver phospholipids showed that diabetes reduced arachidonic acid/linoleic acid ratio and sea tangle diet appeared to increase contentsof polyunsaturated fatty acids.

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The Eigenvalues and Their Relationships for the Rectangular Frame (4각형 골조의 고유치와 고유치 간의 관계)

  • Lee, Soo-Gon;Kim, Soon-Cheol;Song, Chang-Young;Song, Sang-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.3
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    • pp.139-150
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    • 2005
  • Finite element method is applied to the determinations of the two eigenvalues(the elastic critical load and the natural frequence of lateral vibrations) of single story-3 equal bay rectangular frame. The analysis parameters are taper parameter ${\alpha}$ for column, and beam span to column height ratio, ${\beta}$ and second moment area ratio of beam to column, ${\Upsilon}$. Support condition at the column base and sway condition at the column top are also considered in the stability analysis of frame. The changes in the coefficient of eigenvalue are represented by algebraic function of analysis parameter. The coefficients estimated by the proposed algebraic function show good agreement with those determined by finite element method, which suggest the design aid role of the proposed function. By increasing the column axial forces step by step, the corresponding frequencies are also determined, which makes one examine or confirm the relationship suggested by other studies.

Empirical Study for the Effects of Various Filler-Shapes on the Modulus of PP Composites (충전제 함량과 형태에 따른 PP복합체의 모듈러스 변화에 대한 실증적 연구)

  • Kim, Jae-Min;Jeoung, Sun-Kyoung;Shim, Je-Hyeon;Hwang, Hyo-Yeon;Lee, Kee-Yoon
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.346-351
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    • 2010
  • The mechanical properties of polypropylene (PP) composites, especially the effects of the filler shapes on the modulus were studied. The experimental results were investigated and compared with the theoretical approaches proposed by Lee and Paul and based on Eshelby's principle, which three dimensional ellipsoids were filled as filler and analyzed in terms of aspect ratio, ${\rho}_\alpha=a_1/a_3$ and ${\rho}_\beta=a_1/a_2$. The shapes of fillers were observed by SEM and aspect ratios were statistically calculated. Young's moduli in the longitudinal and transverse directions for barium sulfate whose shape was sphere ($\rho_\alpha=\rho_\beta=1$) had the same values, as predicted values. The modulus in the $x_1$ direction for a glass fibers increased as the filler content increased, while the modulus in the $x_3$ direction was increased relatively small. Furthermore, mica was also used to investigate the effects of the primary and secondary aspect ratios on the mechanical properties.