• 제목/요약/키워드: $^{63}Ni$

검색결과 238건 처리시간 0.027초

Radionuclide Transport Mediated by Pseudo-Colloid in the fractured Rock Media : Model Development

  • Baik, Min-Hoon;Hahn, Phil-Soo
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1995년도 춘계학술발표회논문집(2)
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    • pp.769-774
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    • 1995
  • In this study, a transport model was developed in order to analyze and predict the transport behaviors of radionuclides mediated by pseudo-colloid in the fractured rock media. It was resulted that the transport of Pu-239 was faster than Ni-63 because pseudo-colloid formation constant of Pu-239 was greater than that of Ni-63. Also, the effect of pseudo-colloid formation on the transport of a radionuclide was shown to be very significant when the apparent pseudo colloid formation constant, $K_{ap}(m^{3}/kg)$, was greater than 100. Thus, it can be concluded that acceleration of radionuclide migration may be occurred because the pseudo-colloid formation of radionuclides increases the amount of mobile components in the solution and consequently decreases the amount of radionuclides adsorbed on the stationary solid medium.

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금속 Ni 분말을 용해한 도금용액으로부터 전기도금 된 Ni 박막 특성에 미치는 도금조건의 영향 (Effects of Electrodeposition Conditions on Properties of Ni Thin Films Electrodeposited from Baths Fabricated by Dissolving Metal Ni Powders)

  • 윤필근;박근용;엄영랑;최선주;박덕용
    • 한국표면공학회지
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    • 제48권3호
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    • pp.73-81
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    • 2015
  • Chloride plating solution was fabricated by dissolving metal Ni powders in solution with HCl and deionized water. Effects of deposition conditions on the properties of Ni films electrodeposited from chloride baths were studied. Current efficiency of Ni films electrodeposited from the baths containing saccharin was decreased with increasing the current density. Residual stress of Ni thin films ware measured to be about 230 ~ 435 MPa in the range of current density of $10{\sim}25mA/cm^2$. Cathode current efficiency in baths without saccharin was initially increased with increasing pH, while it was decreased with increasing pH further. Cathode current efficiency in baths with saccharin (except at pH 2) exhibited less 10 ~ 20% than that in baths without saccharin. Residual stress of Ni films electrodeposited from baths without saccharin was measured to be 388 ~ 473 MPa in the range of pH 2 ~ pH 5 and then was increased to 551 MPa at pH 6. On the other hand, residual stress of Ni films electrodeposited from baths with saccharin was increased with increasing pH. Surface morphology was strongly affected by the change of current density, but slightly by solution pH and addition of saccharin.

동 매트제련의 반응생성물중 Ni와 Sb의 분배거동에 관한 연구 (A Study on Distribution Behavior of Ni and Sb in Reduction products of Cu Matte Converting)

  • 김영진;이광막;김영홍
    • 자원리싸이클링
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    • 제8권5호
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    • pp.44-50
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    • 1999
  • 동 매트 중에 함유된 불순물 중 단순한 산화정련으로는 제거하기 어려워 제련 후 조동에 함유되어 동의 순도와 기계적 성질을 저하시키는 Ni와 Sb를 매트제련 동안에 제거하기 위한 기초 자료를 제시하고자 공기 송풍에 의한 합성 동 매트의 용련 반응을 통하여 반응 생성물인 매트와 슬래그 그리고 조동에 함유된 Ni와 Sb의 거동 및 상호 연관성을 조사하였다. 공기 송풍에 따른 합성 매트의 용련동안 생성된 반응 생성물에 대한 Ni와 Sb의 분배비로부터 Sb가 Ni과 공존 시 Ni의 슬래그화를 촉진하는 역할을 하며, 또한 Ni은 Sb와 공존시 조동 중으로의 Sb 이동을 저해하고 슬래그화를 촉진시키는 것으로 나타났다. 따라서 Ni와 Sb의 슬래그화를 유도하기 위해서는 Ni와 Sb의 공존이 필요한 것으로 생각된다.

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자전고온반응에 의한 금속간화합물/금속 적층복합재료의 기계적 특성 (Mechanical Properties of Intermetallic/Metal Laminated Composite by SHS Reaction)

  • 김희연;정동석;;홍순형
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 추계학술발표대회 논문집
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    • pp.60-63
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    • 2002
  • Metal/intermetallic laminated composites have been manufactured by SHS reactions between Ni and Al elemental metal foils. Microstructure showed that the intermetallic volume fraction was 55%, 45%, 35% in the 1:1, 2:1, 4:1 thickness ratio(Ni:Al) specimen and the main phases of the intermetallic were transformed from $Ni_2Al_3$ to NiAl when the thickness ratio was increased. Tensile strength and elongation were increased when the volume fraction of Ni metallic phase was increased. Under assumptions of isostrain condition, the tensile strength of metal/intermetallic laminated composites didn't obey the ROM due to the thermal residual stress and this was confirmed by X-ray residual stress analysis. Fracture toughness results by the SENB test showed R-curves with upward curvature based on LSB condition. Bridging stress based on LSB condition was determined by the curve fitting analysis, In-situ observed microstructure during fracture test showed that the various bridging mechanism such as crack bridging, crack branching and ductile failure of metallic layer were occurred

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니켈 실리사이드 화합물의 소결특성 (Sintering Characteristics of Nickel Silicide Alloy)

  • 변창섭;이상호
    • 한국재료학회지
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    • 제16권6호
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    • pp.341-345
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    • 2006
  • [ $Ni_2Si$ ] mixed powders were mechanically alloyed by a ball mill and then processed by hot isostatic pressing (HIP) and spark plasma sintering (SPS). In the powder that was mechanically alloyed for 15minutes(MA 15 min), only Ni and Si were observed but in the powder that was mechanically alloyed for 30minutes(MA 30 min), $Ni_2Si$, Ni and Si were mixed together. Some of the MA 15 min powder and MA 30 min powder were processed by HIP under pressure of 150MPa at the temperature of $1000^{\circ}C$ for two hours and some of them were processed by SPS under pressure of 60 MPa at the temperature of $1000^{\circ}C$ for 60 seconds. Both methods completely compounded the powders to $Ni_2Si$. The maximum density of sintered lumps by HIP method was 99.5% and the maximum density of the sintered lump by SPS method was 99.3%. with the hardness of HRc 66 with the hardness of HRc 63. Therefore, the SPS method that can sinter in short time at low cost is considered to be more economical that the HIP method that requires complicated sintering conditions and high cost and the sintering can produce target materials in desired sizes and shapes to be used for thin film.

63Ni in beta voltaic battery

  • Kim, Jin Joo;Uhm, Young Rang;Son, Kwang Jae
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2014년도 자성 및 자성재료 국제학술대회
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    • pp.176-176
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    • 2014
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선원항 모델을 사용한 저준위 방사성폐기물 처분장의 보수적인 안전성고찰 (A Conservative Safety Study on Low-Level Radioactive Waste Repository Using Radionuclide Release Source Term Model)

  • Kim, Chang-Lak;Lee, Myung-Chan;Cho, Chan-Hee
    • Nuclear Engineering and Technology
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    • 제25권1호
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    • pp.63-70
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    • 1993
  • 암반동굴 타입의 저준위방사성폐기물 처분장의 보수적인 안전성평가를 처분장 선원항 REPS 모델을 사용하여 수행하였다. 신뢰할만한 핵종별 침출율 예측을 위하여 REPS 모델에서 콘크리트 구조물의 열하시간, 부석의 형태와 부식율. 드럼표면의 부식면적 비, 그리고 핵종의 특성등이 고려되고 있다. 예비평가의 결과로 Cs-137, Ni-63, Sr-90등이 주요한 핵종임을 알 수 있다. 파라메타의 불확실성과 민감도분석을 위하여 라틴하이퍼큐브 샘플링과 Rank Correlation 기법이 사용되었다. 침입자 시나리오를 적용하였을 경우의 예상 피폭선량도 허용치 이하임과 처분장의 환경영향평가에 있어서 비교적 불확실성이 적은 Near Field의 중요성에 대한 인식이 새롭게 강조되어야 할 필요가 있음을 알 수 있었다.

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엘니뇨 발생연도의 우리나라의 이상기상 특징과 쌀 수량과의 관계 (Some Meteorological Anomalies and their Relationships with Rice Yield for El Niño Years in South Korea)

  • 심교문;정명표;김용석;최인태;김호정;강기경
    • 한국농림기상학회지
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    • 제18권3호
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    • pp.143-150
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    • 2016
  • 본 논문에서는 1980년 이후 중간 강도 이상의 엘니뇨가 발생한 해의 이상기상 특징과 쌀 수량과의 관계를 분석하였다. 엘니뇨가 발생한 해(n=14)의 전국 평균 쌀 생산량은 $466.3kg\;10a^{-1}$으로 미발생한 해(n=16)의 전국 평균 쌀 생산량 $476.5kg\;10a^{-1}$ 보다 단위면적당 10.2kg 적었지만, 통계적으로는 유의하지 않았다(t=1.215, p=0.234). 또한, 엘니뇨 종료해의 전국 평균 쌀 생산량이 엘니뇨 시작해와 엘니뇨 미발생해의 쌀 생산량보다 낮은 경향을 보였지만, 통계적으로 유의하지 않은 것으로 분석되었다(df=2, f=2.355, p=0.114). 엘니뇨 발생해의 이상기상 발생횟수는 0.57회/년으로 엘니뇨 미발생해의 이상기상 발생횟수(0.63회/년) 보다 다소 적은 것으로 분석되었다. 그러나 엘니뇨 발생해를 시작해와 종료해로 구분하여 이상기상 발생횟수를 조사하면, 엘니뇨 종료해의 이상기상 발생횟수가 0.71회/년으로 엘니뇨 시작해의 이상기상 발생횟수(0.43회/년)와, 엘니뇨 미발생해의 이상기상 발생횟수(0.63회/년) 보다 많은 것으로 조사되었다. 하지만, 이들은 통계적으로 유의한 차이를 나타내지는 않았다(df=2, f=0.321, p=0.727).