• Title/Summary/Keyword: $^{63}Ni$

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Radionuclide Transport Mediated by Pseudo-Colloid in the fractured Rock Media : Model Development

  • Baik, Min-Hoon;Hahn, Phil-Soo
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.769-774
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    • 1995
  • In this study, a transport model was developed in order to analyze and predict the transport behaviors of radionuclides mediated by pseudo-colloid in the fractured rock media. It was resulted that the transport of Pu-239 was faster than Ni-63 because pseudo-colloid formation constant of Pu-239 was greater than that of Ni-63. Also, the effect of pseudo-colloid formation on the transport of a radionuclide was shown to be very significant when the apparent pseudo colloid formation constant, $K_{ap}(m^{3}/kg)$, was greater than 100. Thus, it can be concluded that acceleration of radionuclide migration may be occurred because the pseudo-colloid formation of radionuclides increases the amount of mobile components in the solution and consequently decreases the amount of radionuclides adsorbed on the stationary solid medium.

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Effects of Electrodeposition Conditions on Properties of Ni Thin Films Electrodeposited from Baths Fabricated by Dissolving Metal Ni Powders (금속 Ni 분말을 용해한 도금용액으로부터 전기도금 된 Ni 박막 특성에 미치는 도금조건의 영향)

  • Yoon, Pilgeun;Park, Keun-Yong;Uhm, Young Rang;Choi, Sun Ju;Park, Deok-Yong
    • Journal of the Korean institute of surface engineering
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    • v.48 no.3
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    • pp.73-81
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    • 2015
  • Chloride plating solution was fabricated by dissolving metal Ni powders in solution with HCl and deionized water. Effects of deposition conditions on the properties of Ni films electrodeposited from chloride baths were studied. Current efficiency of Ni films electrodeposited from the baths containing saccharin was decreased with increasing the current density. Residual stress of Ni thin films ware measured to be about 230 ~ 435 MPa in the range of current density of $10{\sim}25mA/cm^2$. Cathode current efficiency in baths without saccharin was initially increased with increasing pH, while it was decreased with increasing pH further. Cathode current efficiency in baths with saccharin (except at pH 2) exhibited less 10 ~ 20% than that in baths without saccharin. Residual stress of Ni films electrodeposited from baths without saccharin was measured to be 388 ~ 473 MPa in the range of pH 2 ~ pH 5 and then was increased to 551 MPa at pH 6. On the other hand, residual stress of Ni films electrodeposited from baths with saccharin was increased with increasing pH. Surface morphology was strongly affected by the change of current density, but slightly by solution pH and addition of saccharin.

A Study on Distribution Behavior of Ni and Sb in Reduction products of Cu Matte Converting (동 매트제련의 반응생성물중 Ni와 Sb의 분배거동에 관한 연구)

  • 김영진;이광막;김영홍
    • Resources Recycling
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    • v.8 no.5
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    • pp.44-50
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    • 1999
  • The sbdy iwestlgaled ihc propa-ties of Lhe dust\ulcorner rrom fe~~oallomya ~~ufacturTeh. e chemical composition, cornpasitlon material, p d c l e sire md shapes of the bulk dust, sired dust and magnetically separated durl were mvesligaled. As the re\ulcornerulL, we suppose that the dust from &gh Carbon Fenama~~gunesMc anuiact~vingP rocess is not sufiicient as solulce material of Mn because of ale low Mn canlenl (13.5%) and complicaled composition mate~ial. The dust from Bug F!lter or AOD Proccss is mi~inlym ade up of 0.2-2 pm Mn30, (Hausmam~iu)p iutlde in spherical shape and thc Mn content is 63.190.The dust from Cooler of AOD Process is inninly made up of coarse Ca(O1-Or)zM. n,FeyO,, SiO, and fine Mn30d.

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Mechanical Properties of Intermetallic/Metal Laminated Composite by SHS Reaction (자전고온반응에 의한 금속간화합물/금속 적층복합재료의 기계적 특성)

  • ;;Manabu Enoki
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.60-63
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    • 2002
  • Metal/intermetallic laminated composites have been manufactured by SHS reactions between Ni and Al elemental metal foils. Microstructure showed that the intermetallic volume fraction was 55%, 45%, 35% in the 1:1, 2:1, 4:1 thickness ratio(Ni:Al) specimen and the main phases of the intermetallic were transformed from $Ni_2Al_3$ to NiAl when the thickness ratio was increased. Tensile strength and elongation were increased when the volume fraction of Ni metallic phase was increased. Under assumptions of isostrain condition, the tensile strength of metal/intermetallic laminated composites didn't obey the ROM due to the thermal residual stress and this was confirmed by X-ray residual stress analysis. Fracture toughness results by the SENB test showed R-curves with upward curvature based on LSB condition. Bridging stress based on LSB condition was determined by the curve fitting analysis, In-situ observed microstructure during fracture test showed that the various bridging mechanism such as crack bridging, crack branching and ductile failure of metallic layer were occurred

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Sintering Characteristics of Nickel Silicide Alloy (니켈 실리사이드 화합물의 소결특성)

  • Byun, Chang-Sop;Lee, Sang-Hou
    • Korean Journal of Materials Research
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    • v.16 no.6
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    • pp.341-345
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    • 2006
  • [ $Ni_2Si$ ] mixed powders were mechanically alloyed by a ball mill and then processed by hot isostatic pressing (HIP) and spark plasma sintering (SPS). In the powder that was mechanically alloyed for 15minutes(MA 15 min), only Ni and Si were observed but in the powder that was mechanically alloyed for 30minutes(MA 30 min), $Ni_2Si$, Ni and Si were mixed together. Some of the MA 15 min powder and MA 30 min powder were processed by HIP under pressure of 150MPa at the temperature of $1000^{\circ}C$ for two hours and some of them were processed by SPS under pressure of 60 MPa at the temperature of $1000^{\circ}C$ for 60 seconds. Both methods completely compounded the powders to $Ni_2Si$. The maximum density of sintered lumps by HIP method was 99.5% and the maximum density of the sintered lump by SPS method was 99.3%. with the hardness of HRc 66 with the hardness of HRc 63. Therefore, the SPS method that can sinter in short time at low cost is considered to be more economical that the HIP method that requires complicated sintering conditions and high cost and the sintering can produce target materials in desired sizes and shapes to be used for thin film.

63Ni in beta voltaic battery

  • Kim, Jin Joo;Uhm, Young Rang;Son, Kwang Jae
    • Proceedings of the Korean Magnestics Society Conference
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    • 2014.11a
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    • pp.176-176
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    • 2014
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A Conservative Safety Study on Low-Level Radioactive Waste Repository Using Radionuclide Release Source Term Model (선원항 모델을 사용한 저준위 방사성폐기물 처분장의 보수적인 안전성고찰)

  • Kim, Chang-Lak;Lee, Myung-Chan;Cho, Chan-Hee
    • Nuclear Engineering and Technology
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    • v.25 no.1
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    • pp.63-70
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    • 1993
  • A simplified safety assessment is carried out on rock-cavern type disposal of LLW using the analytical repository source term (REPS) model. For reliable prediction of the leach rates for various radionuclides, degradation of concrete structures, corrosion rate of waste container, degree of corrosion on the container surface, and the characteristics of radionuclides are considered in the REPS model. The results of preliminary assessment show that Cs-137, Ni-63, and Sr-90 are dominant. For the parametric uncertainty and sensitivity analysis, Latin hypercube sampling technique and rank correlation technique are applied. The results of the potential public health impacts show that radiological dose to intruder in the worst case scenario will be negligible and that more attention should be given to near-field performance.

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Some Meteorological Anomalies and their Relationships with Rice Yield for El Niño Years in South Korea (엘니뇨 발생연도의 우리나라의 이상기상 특징과 쌀 수량과의 관계)

  • Shim, Kyo-Moon;Jung, Myung-Pyo;Kim, Yong-Seok;Choi, In-Tae;Kim, Ho-Jung;Kang, Kee-Kyung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.18 no.3
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    • pp.143-150
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    • 2016
  • In this study, we analyzed the relationship between rice yield and abnormal meteorological features for El $Ni{\tilde{n}}o$ years (with more than 1.0 Oceanic $Ni{\tilde{n}}o$ Index) since 1980 in South Korea. The national averaged rice yield of El $Ni{\tilde{n}}o$ years (n=14) was $4,663kg\;ha^{-1}$, which was less than that of non El $Ni{\tilde{n}}o$ years (n=16) by $102kg\;ha^{-1}$, but the difference was not significant statistically (t=1.215, p=0.234). The averaged rice yield of El $Ni{\tilde{n}}o$ end years ($4,558kg\;ha^{-1}$) was analyzed to be less than those of El $Ni{\tilde{n}}o$ start years and non El $Ni{\tilde{n}}o$ years by 209 and $206kg\;ha^{-1}$, respectively. But, the trend was not significant statistically (df=2, f=2.355, p=0.114). When meteorological anomalies were analyzed based on seasonal meteorological values, 18 meteorological events in total were observed for the past 30 years (1981-2010). In detail, abnormally much precipitation occurred 6 times, most often, followed by 5 times of abnormally low temperature during the past 30 years. Occurrence of meteorological anormalies of El $Ni{\tilde{n}}o$ end years was 0.71 events per year on average, which was higher than those of El $Ni{\tilde{n}}o$ start years ($0.43yr^{-1}$) and non El $Ni{\tilde{n}}o$ years ($0.63yr^{-1}$), even if the differences were not significant statistically (df=2, f=0.321, p=0.727).