• Journal of the Korean Vacuum Society
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• v.5 no.1
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• pp.14-24
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• 1996

We have investigated atomic and electronic structures of a clean Pd(111) surface using low energy electron diffraction (LEED) and angle-resolved photoemission spectroscopy (ARPES). A typical clean LEED pattern with a 3-fold symmetry has been observed, corresponding to that for an fcc (111) surface. ARPES measurements have been performed along the $\Gamma-M,\Gamma-K,\Gamma-M$TEX> symmetry lines, from which the experimental band structure of Pd(111) has been determined. The experimental band structure and work function of Pd(111) surface are found to agree well with the calculated band structure of bulk Pd and the calculated work function of Pd(111), respectively. However, the peak positions in the experimental band structure are located closer to the Fermi level than in the theoretical band structure by 0.1~0.8 eV, depending on the $\kappa$-points in the Brillouin zone. In additin, the experimental band widths are narrower than the theoretical band widths by about 0.5eV. The effects of the localized surface Pd 4d states and the Coulomb interaction between Pd 4d bulk electrons have been discussed as possible origins of such discrepancies between experiment and theory.

• Journal of the Korean Vacuum Society
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• v.15 no.2
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• pp.139-144
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• 2006

Using scanning tunneling microscopy (STM) measurements, we studied the adsorption of hydrogen on the Si(111)$4{\times}1$-In surface at room temperature. The H atom features are found to be located between the two protrusions in one side of the $4{\times}1$ chain. The adsorbed H preferentially occupies one of the two zigzag In subchains, suggesting that the adsorption of H is influenced by the subsurface structure. The adsorbed H atom induces not only a localized distortion but also perturbs the distant region and results in a period-doubling modulations in the STM images. This H-induced perturbation differs from the Na-Induced perturbation on the same surface.

• Journal of the Korean Vacuum Society
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• v.5 no.3
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• pp.199-205
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• 1996

InGaAs eqitaxial layers have been selectively grown on patterned GaAs(100) substrates by chemical beam epitaxy (CBE) using triethylgallium (TEGa), trimethylindium (TMIn), and unprecracked monoethylarsine (MEAs). Facet growth of InGaAs epilayers has also been investigated at the various growth temperatures and Si4N4 dielectric pattern directions. In [011] jirection of mask, the change from (311), (377) and (111) facets to (311) facet with increasing growth temperature was observed. In [011] direction, however, the change from (011) and (111) facets to (111) facet with increasing growth temperature was observed. These results are attributed to the sidewall growth caused by different surface migration lengths of reactants. The formation of U-shaped (100) top surface is also discussed in terms of dangling bond model.

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.438-444
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• 2008

A self-assembled monolayer of 2,2'-bipyridine (22BPY) molecules on Au(111) underwent a structural phase transition when the polarity of a bias voltage was switched in scanning tunneling microscopy (STM) experiments. The nature of two bright spots representing each 22BPY molecule on Au(111) in the high-resolution STM images was identified by calculating the partial density plots for a monolayer of 22BPY molecules adsorbed on Au(111) using tight-binding electronic structure calculations. The stacking pattern of the chains of 22BPY molecules on Au(111) was explained by examining the intermolecular interactions between the 22BPY molecules based on first principles electronic structure calculations for a 22BPY dimer, (22BPY)2. The structural instability of the 22BPY molecule arrangement caused by a change in the bias voltage switch was investigated by estimating the adsorbate-surface interaction energy using a point-charge approximation for Au(111).

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.142-142
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• 2012

다양한 In/Si (111) 표면에 PTCDA분자를 흡착하여 일어나는 현상에 대해 STM을 이용하여 실험하였다. PTCDA분자가 $\sqrt{31}{\times}\sqrt{31}$ 표면에서는 강한 표면-분자 상호작용 때문에 배열되지 않고 고립된 분자로 흡착되며 $\sqrt{7}{\times}\sqrt{3}$-hex표면에서는 표면-분자 상호작용이 약하여 분자와 분자 사이의 상호작용으로 수소결합을 통한 2차원 herringbone 구조를 형성한다. 하지만 $4{\times}1$ 표면에서는 수소결합 없이 준 1차원 배열을 형성하며 지금까지 연구된 다른 모든 표면에서 수소결합에 의하여 분자배열을 이루는 것과 대조된다. 이는 $4{\times}1$ 표면에서 표면-분자 사이의 상호작용에 의해 분자배열이 결정되기 때문이다. 또한, Si (111)$-7{\times}7$면 위에 서로 다른 덮힘양의 In 원자를 포함하는$\sqrt{3}{\times}\sqrt{3}$, $2{\times}2$, 그리고 $\sqrt{7}{\times}\sqrt{3}$-hex상이 같이 있는 표면에 PTCDA분자를 흡착할 경우, PTCDA분자의 흡착이 In층 안에서 In 원자를 이동시키면서 국소적으로 in의 덮힘양이 많은 상으로 변화시키는 것을 관찰하였다. PTCDA분자가 In원자를 이동시키는 이유는 상대적으로 약한 In층과의 결합보다는 더 강한 Si (111)표면과의 결합을 위한 것으로 해석된다.

• Journal of The Korean Society of Agricultural Engineers
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• v.55 no.6
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• pp.87-99
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• 2013

For analysis of climate change effects on agriculture, precise agricultural meteorological data are needed to target period and site. In this study, agricultural meteorological data under new climate change scenario (RCP 8.5) are constructed from 2011 to 2099 in 111 agriculture major station suggested by Rural Development Administration (RDA). For verifying constructed data, comparison with field survey data in Suwon shows same trend in maximum temperature, minimum temperature, average temperature, and precipitation in 2011. Also comparison with normals of daily data in 2025, 2055, and 2085 shows reliability of constructed data. In analysis of constructed data, we can calculate sum of days over temperature and under temperature. Results effectively show the change of average temperature in each region and odd days of precipitation which means flood and dry days in target region.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.181-181
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• 1999

Self-assembled monolayers(SAMs) of alkanethiol have been formed on the Cu(111) surfaces in vacuum. The thermal behavior of octanethiol-based SAMs on the Cu(111) surface have been examined in ultrahigh vacuum. Using X-ray photoelectron spectroscopy (XPS), it is found that the monolayers are stable up to about 500K in vacuum. Decomposition is signaled by a decrease in the intensity of C ls peak, accompanied by an increase of the intensity of the Cu 2p peak. However, the intensity of the S 2p peak doesn't change much as a function of annealing temperature. Thermal the decomposition mass spectra show that n-alkene is the predominant species desorbing from the surface in the 500-600K temperature range. The totality of these data leads to the conclusion that the monolayers decompose through the S-C bond cleavage by hydrogen elimination reaction, resulting in the desorption of hydrocarbon moiety as n-alkene. Following this initial decomposition step, Cu2S layers are observed on the surface. For comparison, attempts were also made to examine the thermal behavior of octanethiol-based SAMs on the Cu(111) surface in air. It has been shown that the SAMs on the Cu(111) surfaces begin to desorb with the oxidation of the thiolate to sulfonate at 400K. Upon annealing to 450K, the monolayer has almost completely desorbed as indicated by the virtual disappearance of the S 2p peak.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1995.10a
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• pp.167-171
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• 1995

The formation of preferred orientations in cold rolled and recrystallized Inconel 690 sheets was studied by the x-ray texture measurements and TEM observations. The increasing{220} pole intensity in the plane normal at the higher reductions was related to the{110}<112> texture component. The rolling texture of the Inconel 690 was the pure metal type. THe dislocation cells were found in the near{110}<112> oriented grains. The onset of deformation twins in the {112}<111>oriented grains. The onset of deformation twins in the {112}<111> oriented grains. The onset of deformation twins in the {112}<111> oriented grains caused the weakening of {112}<111> and the development of {552}<115> in the rolling texture. The annealing texture of the Inconel 690 sheets was dependent on the annealing temperature. The annealing texture of 750$^{\circ}C$ annealed sheets was similar to the cold rolling texture. The major preferred orientations of the 950$^{\circ}C$ annealed specimens were {112}<110> and {001}<110>. The formation of fine and closely spaced annealing twins in the specimen annealed at 1150$^{\circ}C$ led to the randomization of the annealing texture.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.1358-1362
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• 2005

The Ni-base superalloy GTD-111DS was designed in the 1970s and is widely used as the material of the first stage blade under a severe combination of temperature and pressure in gas turbines. But because GTD-111DS is distributed in the shape of blade and blade has a unique figure and many cooling channels, it is hard to manufacture the test specimen. In this reason, there are little data on the microstructure and mechanical properties of the alloy. Therefore through the microstructure analysis, present paper observed that the shape of $\gamma{'}$ did not change even if aging time was increased but the amount and volume of the deposition of secondary $\gamma{'}\;rose\;and\;secondary\;\gamma{'}\;grew\;among\;primary\;\gamma{'}$. Also, by tensile test for different temperature, there was difference between yield strength and tensile strength in room temperature on heat treatment and extracting region but the more increasing temperature, the more decreasing difference between yield strength and tensile strength.

• Proceedings of the Korean Nuclear Society Conference
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• 1977.06a
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• pp.111.1-111
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• 1977