• Journal of Photoscience
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• v.8 no.3_4
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• pp.113-117
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• 2001

Several styrylquinolium salts were synthesized to investigate their absorption and thermal properties, which had five different p-aminobenzene units and three different counter ions (iodide, perchlorate, and hexafluorophosphorate anion), respectively. Hydroxy, methoxy, and methyl group in the meta position to the amino group led to bathochromic shift, while Ν-ethyl-Ν-chloroethylamino unit instead of Ν,Ν-diethylamino unit resulted in hypsochromic shift. A dye having a methoxy group in the meta position to the amino group had the highest molar extinction coefficient ($\xi$), while a dye carrying chloro group in Ν-alkyl chains had the lowest $\xi$. The type of counter ions had no effect on spectral properties like the maximum absorption wavelength and $\xi$. All styryl dyes had exothermic peaks at decomposition in DSC curves. Among these styryl dyes, S2 series with perchlorate anions showed the strongest exothermic decomposition. From TGA spectra, S3 series with hexafluorophosphorate anions had the best thermal stability and the sharpest threshold at thermal decomposition.

• Steel and Composite Structures
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• v.36 no.3
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• pp.339-353
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• 2020

This study investigates the seismic performance of steel reinforced concrete (SRC) T-shaped columns under low cyclic loading tests. Based on test results of ten half-scale column specimens, failure patterns, hysteretic behavior, skeleton curves, ultimate strength, ductility, stiffness degradation and energy dissipation capacity were analyzed. The main variables included loading angles, axial compression ratios and steel ratios. The test results show that the average values of the ductility factor and the equivalent viscous damping coefficient with respect to the failure of the columns were 5.23 and 0.373, respectively, reflecting good seismic performance. The ductility decreased and the initial stiffness increased as the axial compression ratio of the columns increased. The strength increased with increasing steel ratio, as expected. The columns displaced along the web had higher strength and initial stiffness, while the columns displaced along the flange had better ductility and energy dissipation capacity. Based on the test and analysis results, a formula is proposed to calculate the effective stiffness of SRC T-shaped columns.

• Journal of the Korean Chemical Society
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• v.21 no.6
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• pp.413-421
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• 1977

The orbital mixing analysis was applied to the acid-catalyzed nucleophilic substitution reaction of N-acetylpyrrolidone. It was found that the reactivity of protonated carbonyl carbon is greatly enhanced due to increase in positive charge (for charge controlled reaction) and also increase in LUMO AO coefficient (for orbital controlled reaction) of the carbonyl carbon atom.

• Nuclear Engineering and Technology
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• v.52 no.6
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• pp.1172-1179
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• 2020

As a Lagrangian particle method, Moving Particle Semi-implicit (MPS) method has great capability to capture interface/surface. In recent years, the multiphase flow simulation using MPS method has become one of the important directions of its developments. In this study, some key methods for multiphase flow have been introduced. The interface tension model in multiphase flow is modified to maintain the smooth of the interface and suitable for the three-phase flow. The mass transfer at immiscible liquid interface entrained by single bubble which could occur in Molten Core-Concrete Interaction (MCCI) has been investigated using this particle method. With the increase of bubble size, the height of entrainment column also increases, but the time of film rupture is slightly different. With the increase of density ratio between the two liquids, the height of entrained column decreases significantly due to the decreasing buoyancy of the denser liquid in the lighter liquid. In addition, the larger the interface tension coefficient is, the more rapidly the entrained denser liquid falls. This study validates that the MPS method has shown great performance for multiphase flow simulation. Besides, the influence of physical parameters on the mass transfer at immiscible interface has also been investigated in this study.

• Nuclear Engineering and Technology
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• v.54 no.8
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• pp.3117-3129
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• 2022

Deeply understanding the phase change of thin liquid sodium film inside wick pore is very important for further studying high-temperature sodium heat pipe's heat transfer. For the first time, the evaporation and condensation of thin liquid sodium film are investigated by the Lennard-Jones potential of molecular dynamics. Based on the startup and normal operation of the sodium heat pipe, three different cases are simulated. First, the equilibrium is achieved and the Mass Accommodation Coefficients of the three cases are 0.3886, 0.2119, 0.2615 respectively. Secondly, the non-equilibrium is built. The change of liquid film thickness, the number of gas atoms, the net evaporation flux (J_net), the heat transfer coefficient (h) at the liquid-gas interface are acquired. Results indicate that the magnitude of the J_net and the h increase with the basic equilibrium temperature. In 520-600 K (the startup of the heat pipe), the h has approached 5-6 W m^-2 K^-1 while liquid film thickness is in 11-13 nm. The fact shows that during the initial startup of the sodium heat pipe, the thermal resistance at the liquid-gas interface can't be negligible. This work is the complement and extension for macroscopic investigation of heat transfer inside sodium heat pipe. It can provide a reference for further numerical simulation and optimal design of the sodium heat pipe in the future.

• Steel and Composite Structures
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• v.46 no.2
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• pp.221-236
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• 2023

In order to study the seismic response of the main plant of steel reinforced concrete (SRC) structure of the CAP1400 nuclear power plant under the influence of different high-mode vibration, the 1/7 model structure was manufactured and its dynamic characteristics was tested. Secondly, the finite element model of SRC frame-bent structure was established, the seismic response was analyzed by mode-superposition response spectrum method. Taking the combination result of the 500 vibration modes as the standard, the error of the base reactions, inter-story drift, bending moment and shear of different modes were calculated. Then, based on the results, the influence of high-mode vibration on the seismic response of the SRC frame-bent structure of the main plant was analyzed. The results show that when the 34 vibration modes were intercepted, the mass participation coefficient of the vertical and horizontal vibration mode was above 90%, which can meet the requirements of design code. There is a large error between the seismic response calculated by the 34 and 500 vibration modes, and the error decreases as the number of modes increases. When 60 modes were selected, the error can be reduced to about 1%. The error of the maximum bottom moment of the bottom column appeared in the position of the bent column. Finally, according to the characteristics of the seismic influence coefficient αj of each mode, the mode contribution coefficient γj•Xji was defined to reflect the contribution of each mode to the seismic action.

• Steel and Composite Structures
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• v.31 no.1
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• pp.13-25
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• 2019

Reactive powder concrete (RPC) is a type of ultra-high strength concrete that has a relatively high brittleness. However, its ductility can be improved by confinement, and the use of RPC in composite RPC filled steel tube columns has become an important subject of research in recent years. This paper aims to present an experimental study of axial capacity calculation of RPC filled circular steel tube columns. Twenty short columns under axial compression were tested and information on their failure patterns, deformation performance, confinement mechanism and load capacity were presented. The effects of load conditions, diameter-thickness ratio and compressive strength of RPC on the axial behavior were further discussed. The experimental results show that: (1) specimens display drum-shaped failure or shear failure respectively with different confinement coefficients, and the load capacity of most specimens increases after the peak load; (2) the steel tube only provides lateral confinement in the elastic-plastic stage for fully loaded specimens, while the confinement effect from steel tube initials at the set of loading for partially loaded specimens; (3) confinement increases the load capacity of specimens by 3% to 38%, and this increase is more pronounced as the confinement coefficient becomes larger; (4) the residual capacity-to-ultimate capacity ratio is larger than 0.75 for test specimens, thus identifying the composite columns have good ductility. The working mechanism and force model of the composite columns were analyzed, and based on the twin-shear unified strength theory, calculation methods of axial capacity for columns with two load conditions were established.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.10 no.4
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• pp.1790-1806
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• 2016

Digital image encryption is widely used for image data security. JPEG standard compresses image with great performance on reducing file size. Thus, to encrypt an image in JPEG format we should keep the quality of original image and reduced size. This paper proposes a JPEG image encryption scheme based on quantized DC and non-zero AC coefficients inner category scrambling. Instead of coefficient value encryption, the address of coefficient is encrypted to get the address of cipher text. Then 8*8 blocks are shuffled. Chaotic iteration is employed to generate chaotic sequences for address scrambling and block shuffling. Analysis of simulation shows the proposed scheme is resistant to common attacks. Moreover, the proposed method keeps the file size of the encrypted image in an acceptable range compared with the plain text. To enlarge the cipher text possible space and improve the resistance to sophisticated attacks, several additional procedures are further developed. Contrast experiments verify these procedures can refine the proposed scheme and achieve significant improvements.

• Nuclear Engineering and Technology
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• v.54 no.4
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• pp.1321-1335
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• 2022

This study was conducted to investigate the effect of absorption coefficient models on the P1 radiation model for a premixed hydrogen flame containing the water vapor. A CFD combustion simulation analysis was performed using XiFoam, one of the open-source CFD solvers in OpenFOAM. The solver using the flamelet combustion model has been modified to implement radiative heat transfer. The absorption coefficient models used in this study the grey-mean model and constant model, and for comparison, case without radiation was added. This CFD simulation study consisted of benchmarking the THAI HD-15 and HD-22 experiments. The difference between the two tests is the inclusion of water vapor in the condition before ignition. In the case of the HD-22 experiment containing water vapor in the initial condition, the simulation results show that the grey-mean absorption coefficient model has a strong influence on the temperature decrease of the flame and on the change in pressure inside the vessel.

• Journal of applied mathematics & informatics
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• v.28 no.3_4
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• pp.663-677
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• 2010

In this paper, the generalized SOR-like methods are presented for solving the saddle point problems. Based on the SOR-like methods, we introduce the uncertain parameters and the preconditioned matrixes in the splitting form of the coefficient matrix. The necessary and sufficient conditions for guaranteeing its convergence are derived by giving the restrictions imposed on the parameters. Finally, numerical experiments show that this methods are more effective by choosing the proper values of parameters.