• Title/Summary/Keyword: $\pi$Configuration

Search Result 76, Processing Time 0.027 seconds

A case on the Evaluation of the Effectiveness of Model based Configuration Management System for Small/ Medium-Sized Plant (모델 기반 중소형 플랜트 형상관리 시스템의 효과성 평가 사례)

  • Ha, Ga Yeon;Kim, Jinil;Shin, Junguk;Yeom, Choong Sub
    • Journal of the Korean Society of Systems Engineering
    • /
    • v.17 no.1
    • /
    • pp.107-113
    • /
    • 2021
  • Plant Configuration Management(CM) is an activity to maintain consistency of design requirements, physical configuration, facility configuration information throughout the life cycle of the plant by systematically managing changes that occur during the plant design and operation process. Conformity between information must be ensured not only in the design stage, but also in the case of design changes in the operation and maintenance stages, and thus a computer system capable of efficiently managing them is required. In particular, in consideration of an application to small and medium-sized domestic plants, a computer system that can support configuration management at a low cost is needed. Accordingly, in this study, a configuration management system has been developed to support the management of plant design information and change procedures in the operation stage of small and medium-sized plants. Here, a case for quantitatively evaluating the effectiveness of the developed system is described.

Study of the Valence and Rydberg States of a Lithium Dimer by the Multi-reference Configuration-interaction Method

  • Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.5
    • /
    • pp.1422-1432
    • /
    • 2014
  • Convergent all-electron multi-reference configuration-interaction (MRCI) calculations are performed for a lithium dimer with Kaufmann's Rydberg basis functions. A comparison of the results of these calculations with those of the effective core potential/core polarization potential (ECP/CPP) method and experimental data reveals the deficiency of the all-electron ab initio method. The deficiency is related to the mere 51.9% attainment of electron correlation for the ground state. The percent attainment of electron correlation for the first excited state is slightly better than that for the ground state, preventing us from obtaining better agreements with experimental data by means of increasing the size of basis sets. The Kaufmann basis functions are then used with the ECP/CPP method to obtain the accurate convergent potential energy curves for the $^1\prod_u$ states correlated to Li(2p) + Li(2p) and Li(2s) + Li(n = 2, 3, 4). Quantum defect curves (QDCs) calculated for both the $X^2\sum_g$ and 1 $^2\prod_u$ states of the $Li{_2}^+$ ion and the Lu-Fano plot reveal a strong series-series interaction between the two $2snp{\pi}$ and $2pnp{\pi}$ Rydberg series. The QDCs are then used to resolve assignment problems in the literature. The reassignments, performed by Jedrzejewski-Szemek et al., of the dissociation product of the D $^1\prod$ state from (2s+3d) to (2s+3p) and that of the 6 $^1\prod_u$ from (2s+4d) to (2s+4p) are found to be incorrect. It may be more natural to assign their $2snp{\pi}$ Rydberg series as a $2snd{\pi}$ series. The state, assigned as 5p $^1\prod_u$ by Ross et al. and 4d $^1\prod$ by Jedrzejewski-Szemek et al., is assigned as the 7 $^1\prod_u$ state, correlated to the Li(2s) + Li(4f) limit.

Dual Regulation of R-Type CaV2.3 Channels by M1 Muscarinic Receptors

  • Jeong, Jin-Young;Kweon, Hae-Jin;Suh, Byung-Chang
    • Molecules and Cells
    • /
    • v.39 no.4
    • /
    • pp.322-329
    • /
    • 2016
  • Voltage-gated $Ca^{2+}$ ($Ca_V$) channels are dynamically modulated by Gprotein-coupled receptors (GPCR). The $M_1$ muscarinic receptor stimulation is known to enhance $Ca_V2.3$ channel gating through the activation of protein kinase C (PKC). Here, we found that $M_1$ receptors also inhibit $Ca_V2.3$ currents when the channels are fully activated by PKC. In whole-cell configuration, the application of phorbol 12-myristate 13-acetate (PMA), a PKC activator, potentiated $Ca_V2.3$ currents by ~two-fold. After the PMA-induced potentiation, stimulation of $M_1$ receptors decreased the $Ca_V2.3$ currents by $52{\pm}8%$. We examined whether the depletion of phosphatidylinositol 4,5-bisphosphate ($PI(4,5)P_2$) is responsible for the muscarinic suppression of $Ca_V2.3$ currents by using two methods: the Danio rerio voltage-sensing phosphatase (Dr-VSP) system and the rapamycin-induced translocatable pseudojanin (PJ) system. First, dephosphorylation of $PI(4,5)P_2$ to phosphatidylinositol 4-phosphate (PI(4)P) by Dr-VSP significantly suppressed $Ca_V2.3$ currents, by $53{\pm}3%$. Next, dephosphorylation of both PI(4)P and $PI(4,5)P_2$ to PI by PJ translocation further decreased the current by up to $66{\pm}3%$. The results suggest that $Ca_V2.3$ currents are modulated by the $M_1$ receptor in a dual mode-that is, potentiation through the activation of PKC and suppression by the depletion of membrane $PI(4,5)P_2$. Our results also suggest that there is rapid turnover between PI(4)P and $PI(4,5)P_2$ in the plasma membrane.

A Educational Study on Detection of Fluoride by Borane Compounds (보레인 화합물을 이용한 불소 이온 검출에 관한 교육 연구)

  • Lee, Kang Mun
    • Korean Educational Research Journal
    • /
    • v.37 no.1
    • /
    • pp.33-45
    • /
    • 2016
  • We propose a research for detection of the fluoride ion using borane compounds. Based on the Lewis acid-base reaction, we discussed the fundamental of sensing for fluoride ion. One of the important aspects in the chemistry of organoboranes is their behaviors as Lewis acids, which is a result of the vacant $2p_{\pi}$ orbital on the tricoordinate boron center. The electronic interaction between boron atoms and ${\pi}$-orbitals of donor molecules, constructed from the carbon 2p orbitals, is generally strong. Boron atoms can reach the desired octet configuration either through ${\pi}$-overlap with a suitable X or through formation of Lewis acid-Lewis base complexes.

  • PDF

Ultra-Low Powered CNT Synaptic Transistor Utilizing Double PI:PCBM Dielectric Layers (더블 PI:PCBM 유전체 층 기반의 초 저전력 CNT 시냅틱 트랜지스터)

  • Kim, Yonghun;Cho, Byungjin
    • Korean Journal of Materials Research
    • /
    • v.27 no.11
    • /
    • pp.590-596
    • /
    • 2017
  • We demonstrated a CNT synaptic transistor by integrating 6,6-phenyl-C61 butyric acid methyl ester(PCBM) molecules as charge storage molecules in a polyimide(PI) dielectric layer with carbon nanotubes(CNTs) for the transistor channel. Specifically, we fabricated and compared three different kinds of CNT-based synaptic transistors: a control device with $Al_2O_3/PI$, a single PCBM device with $Al_2O_3/PI:PCBM$(0.1 wt%), and a double PCBM device with $Al_2O_3/PI:PCBM$(0.1 wt%)/PI:PCBM(0.05 wt%). Statistically, essential device parameters such as Off and On currents, On/Off ratio, device yield, and long-term retention stability for the three kinds of transistor devices were extracted and compared. Notably, the double PCBM device exhibited the most excellent memory transistor behavior. Pulse response properties with postsynaptic dynamic current were also evaluated. Among all of the testing devices, double PCBM device consumed such low power for stand-by and its peak current ratio was so large that the postsynaptic current was also reliably and repeatedly generated. Postsynaptic hole currents through the CNT channel can be generated by electrons trapped in the PCBM molecules and last for a relatively short time(~ hundreds of msec). Under one certain testing configuration, the electrons trapped in the PCBM can also be preserved in a nonvolatile manner for a long-term period. Its integrated platform with extremely low stand-by power should pave a promising road toward next-generation neuromorphic systems, which would emulate the brain power of 20 W.

MO Studies of Configuration and Conformation (XV). Through-Space and Through-Bond Interactions In Ethylene Diamine (배치와 형태에 관한 분자궤도론적 연구 (제15보). 에틸렌 디아민의 Through-Space 및 Through-Bond 상호작용)

  • Ikchoon Lee;Chang Kook Sohn;Chang Hyun Song
    • Journal of the Korean Chemical Society
    • /
    • v.26 no.2
    • /
    • pp.65-72
    • /
    • 1982
  • STO-3G level computations were performed on n-propylamine, n-propylamine radical and cis-and trans-ethylene diamines in order to investigate structural contributions of (n${\pi}$/m) and (n-${\sigma}^*$) structures to the energy variations accompanying the conformational changes. It was found that (5${\pi}$/5) and (4${\pi}$/4) structures had attractive and repulsive nonbonded interactions, respectively, which were approximately additive. anti(n-${\sigma}^*$) structures had more stabilzing hyperconjugative interactions than syn(n-${\sigma}^*$) structures, but due to the large internuclear repulsion the net effect was destabilizing inthe former in contrast with the net stabilizing contribution in the latter. Moreover it was found that the stabilizing ${\pi}$-nonbond structure, (5${\pi}$/5) was always cooperatively reinforced by the more stabilizing anti(n-${\sigma}^*$) interaction, whereas the destabilizing (4${\pi}$/4) structure was accompanied by the less stabilizing syn(n-${\sigma}^*$) interaction. This type of cooperativity was found general through-bond interaction of the terminal lone pair lobes split the energy levels into two, $n_+ = \frac{1}{\sqrt{2}}(n_1 + n_2)$ and $n_- = \frac{1}{\sqrt{2}}(n_1 - n_2)$, the latter being the lower level, which can be shown using simple overlap patterns of the two lobes with a common vicinal ${\sigma}^*$ orbital.

  • PDF

Design and Test of Lateral/Directional Control Law of a Tailless UAV Using Spoilers (스포일러를 이용한 무미익 항공기의 횡방향축 제어기설계 및 시험)

  • Hong, Jin-sung;Hwang, Sun-yu;Lee, Kwang-hyun;Hur, Gi-bong
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.47 no.6
    • /
    • pp.422-428
    • /
    • 2019
  • A tailless or Blended-Wing-Body(BWB) shaped configuration is highlighted for UCAV with low RCS characteristics. The BWB configuration is characterized by its directional static instability and low controllability. To control the directional movement of the BWB configured vehicle, directional thrust vectoring equipment or drag rudder typed control surfaces which utilize the drag differences of the wing can be considered. This paper deals with a BWB shaped configuration using a spoiler and describes the lateral-directional aerodynamic characteristics of the vehicle. In addition, it is shwon that the lateral-directional motion can be controlled effectively by using the classical PI control structure. This control law is verified by flight test and showed adequate for the tailless BWB shaped UAV.

A Modular Disturbance Observer-based Cascade Controller for Robust Speed Regulation of PMSM

  • Kim, In Hyuk;Son, Young Ik
    • Journal of Electrical Engineering and Technology
    • /
    • v.12 no.4
    • /
    • pp.1663-1674
    • /
    • 2017
  • This paper deals with the robust speed regulation of a surface-mounted permanent magnet synchronous motor (SPMSM) that is subject to parametric uncertainties and external disturbances. The proposed approach retains a conventional cascade control configuration composed of an outer-loop speed control module and inner-loop current control modules. Baseline proportional-integral (PI) controllers are designed for nominal modular systems without accounting for the uncertainties to set a desired control performance of the closed-loop system. After studied in both frequency and time domains, a reduced-order proportional-integral observer (PIO), as a modular disturbance observer, is incorporated with each control module to maintain the ideal performance of the modules. Theoretical analysis confirms the desired performance recovery of the augmented system with modular PIOs to the nominal system. Comparative computer simulations and experimental results validate the proposed cascade control method for SPMSM speed regulation.

Designing Cost Effective Open Source System for Bigdata Analysis (빅데이터 분석을 위한 비용효과적 오픈 소스 시스템 설계)

  • Lee, Jong-Hwa;Lee, Hyun-Kyu
    • Knowledge Management Research
    • /
    • v.19 no.1
    • /
    • pp.119-132
    • /
    • 2018
  • Many advanced products and services are emerging in the market thanks to data-based technologies such as Internet (IoT), Big Data, and AI. The construction of a system for data processing under the IoT network environment is not simple in configuration, and has a lot of restrictions due to a high cost for constructing a high performance server environment. Therefore, in this paper, we will design a development environment for large data analysis computing platform using open source with low cost and practicality. Therefore, this study intends to implement a big data processing system using Raspberry Pi, an ultra-small PC environment, and open source API. This big data processing system includes building a portable server system, building a web server for web mining, developing Python IDE classes for crawling, and developing R Libraries for NLP and visualization. Through this research, we will develop a web environment that can control real-time data collection and analysis of web media in a mobile environment and present it as a curriculum for non-IT specialists.

MO Studies on Nicotine (I) (니코틴의 배치와 형태에 관한 분자궤도론적 연구 (제1보))

  • Ikchoon Lee;Dong Hwan Park
    • Journal of the Korean Chemical Society
    • /
    • v.22 no.4
    • /
    • pp.195-201
    • /
    • 1978
  • Configuration and conformation of nicotine and its protonated form have been studied by MO theoretically using EHT and CNDO/2 methods. The form with angle of rotation ${\theta}\;=\;280^{\circ}$ of pyrrolidine ring was shown to be most stable and this was interpreted in terms of conjugative, electrostatic and seric effects. It was predicted that protonation occurs on the nitrogen atom of pyridine ring and forms a ${\pi}$-complex.

  • PDF