• Title/Summary/Keyword: "S" modifier

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From An Imitator to a Pioneer in Design Strategy -A Study on Progresses of the Design Promotion on Strategy in Korea since 1950s- (디자인 전략의 모방자에서 선구자로 -한국 디자인 진흥 전략의 발전 과정에 관한 고찰-)

  • Chung, Kyung-Won
    • Archives of design research
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    • v.17 no.4
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    • pp.385-396
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    • 2004
  • The progresses in the Korean design promotion strategy since the 1950s have been studied. Korean design strategy was somewhat limited in the imitator who copied advanced nations strategies at the beginning. Their strategies changed to adopter and/or modifier in conjunction with the Korean economic development. It has pursued pioneer strategies since 2000. This study has identified the changing environment of design, the nature of design promotion strategy, the historical background and current states of world design promotion. Finally, it has suggested four challenges for transforming Korea into the world class design nation: Formulation of law for cultivating the design industry; enhancing the self-survival power of Korea Institute of Design Promotion(KIDP), the establishment of the Korea Design Promotion Foundation, upgrading the Korea Federation of Design Associations(KFDA).

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Effect of Alumina Nanooxide Application on Nitrendipine Manufacturing Process (알루미나 나노산화물이 Nitrendipine 제조 공정에 미치는 영향)

  • Chae, E.J.;Uhm, Y.R.;Han, B.S.;Rhee, C.K.;Park, S.E.
    • Journal of Powder Materials
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    • v.14 no.2 s.61
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    • pp.127-131
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    • 2007
  • The alumina nano powders synthesized by levitational gas condensation (LGC) method were applied to catalyst in manufacturing process of Hanzsch reaction for Nitrendipine. The L-tartaric acid on the surface is carried out with participation of carbonyl fragments, O-H, C-H bonds which affects stereo selectivity, yield on the reagents positively. From the analysis of the IR-spectroscopy, the carbonyl fragments, O-H, and C-H bond were created by the catalytic reaction. From the analysis of the rR-spectroscopy, the carbonyl fragments, O-H, and C-H bond were created by the catalytic reaction. The newly created bonds made a chiral center on the final product.

Preparation and analysis of lyophilized whole blood as external quality control materials for Pb and Cd determination by graphite furnace atomic absorption spectrometry (흑연료 원자흡수 분광법에 의한 혈중의 납, 카드뮴 정량을 위한 외부정도관리 시료제조 및 분석)

  • Lee, Kong-Joo;Lim, H.B.
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.273-279
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    • 1995
  • Lyophilized whole blood samples containing various concentrations of Pb and Cd have been prepared as external quality control materials. These materials have been characterized with graphite furnace atomic absorption spectrometry(GFAAS), The optimized conditions for the quantitative determination of Ph and Cd in whole blood using GFAAS were obtained at the ashing temperature of $600{\sim}650^{\circ}C$ with 0.1% ammonium dihydrogen phosphate and 0.1% Triton X-100 as matrix modifier. Homogeniety and stability of the prepared whole blood have been studied at the optimized analytical condition.

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In vitro and In vivo Effects of Gelidium amansii on Intestinal Immune System

  • Jun, Woo-Jin;Kim, Se-Han;Lee, Dae-Hee;Chun, Jin-Woong;Sim, Sang-In;Lee, Kwang-Won;Cho, Hong-Yon;Hong, Bum-Shik
    • Food Science and Biotechnology
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    • v.14 no.1
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    • pp.147-151
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    • 2005
  • Purified compound with intestinal immune system-modulating properties, GWE-2c, was isolated from methanol extract of Gelidium amansii by sequential procedures with silica gel column, LH-20 Sephadex gel column, and thin-layer chromatographies. In the presence of GWE-2c, strong immunoactivity in Peyers patch cell-mediated bone marrow cells was observed in vitro. In vivo intestinal immune-modulating activity was also enhanced by crude phenolic compound (GWE) of G. amansii in a dose-dependent manner. Investigation of production of several cytokines in Peyer's patch cells upon stimulation with GWE in vivo revealed the levels of granulocyte-macrophage colony-stimulating factor (GM-CSF) and interleukin (IL)-6 increased. Results suggest that the phenolic compound from G. amansii represents immunopotentiator and biological response modifier at in vitro and in vivo levels.

A Study on Thermal and Mechanical Properties of Elastic Epoxy with Water Aging (탄성형 에폭시의 흡습 열화에 따른 열적 및 기계적 특성에 관한 연구)

  • 이관우;민지영;한기만;최용성;박대희
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.6
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    • pp.293-299
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    • 2004
  • In this paper, thermal and mechanical properties of electric epoxy with water aging were discussed. We made elastic epoxy specimen adding a ratio of 0〔phr〕20〔phr〕, 35〔phr〕 and 53〔phr〕 with modifier to existing epoxy. We studied mechanical property of elastic resin after absorption in water from 0 to 484 hours. As a result, diffusion factor of elastic epoxy showed 20-21${\times}$10$^{-4}$ $\textrm{mm}^2$/s and general epoxy showed 9.5${\times}$10$^{-4}$ $\textrm{mm}^2$/s. Elastic property increased linearly according to addiction and decreased according to water absorption. Tensile strength was reduced according to addition. It was affected by water absorption of micro-void of elastic epoxy. Hardness inclined to decrease after increasing according to absorbed time. In water-absorption state, it was experimented a change of heat flow by temperature of elastic epoxy and change of thermal expansion coefficient. DSC (Differential Scanning Calorimetry) and TMA (Thermomechanical Analysis) equipments were used to measure Tg. A temperature ringe of DSC was from -0($^{\circ}C$) to 200($^{\circ}C$). One of TMA was from -0($^{\circ}C$) to 350($^{\circ}C$). In addition, we investigated structural analysis of water absorbed specimen using SEM (Scanning Electron Microscope).

The preparation and characterization of poly(ethylene terephthalate)(PET)/layered silicate nanocomposite (PET 나노복합재료의 제조 및 특성분석)

  • 천상욱;손세범;곽승엽
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.21-24
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    • 2003
  • In general, to enhance physical properties of PET-layered silicate nanocomposites $(P_{et}LSNs)$, it has been well known that the organic modifiers should introduce into gallery regions. However, the organic modifiers in$(P_{et}LSNs)$ may result in thermal decomposition by melt processing at high temperature, and it necessarily lead to deteriorate various physical properties of final products. Therefore, in this study, $(P_{et}LSNs)$ excluding and including organic modifiers were prepared by solution method $(S-P_{et}LSNs_{eom} and S-P_{et}LSNs_{iom})$ and we (focused on the effects of the organic modifiers in $P_{et}$ LSNs with exfoliation structure on the crystallization behaviors, the optical transparency, the thermal stability and the mechanical property. The absence and existence of organic modifiers in $S-P_{et}LSNs_{eom} and S-P_{et}LSNs_{iom}$ were investigated by EA and TGA, and nano-structure of silicate layers in $S-P_{et}LSNs$ was evaluated by using WXRD, SAXS and TEM. $S-P_{et}LSNs_{eom} and S-P_{et}LSNs_{iom}$ were mixed with neat PET as masterbatches by melt method $(M-P_{et}LSNs_{eom} and M-P_{et}LSNs_{iom})$, and also neat PET was mixed with organically modified layered silicates (OLS) by conventional direct melt method $(D-P_{et}LSNs) at 270^{\circ}C$. As results, it was found that $M-P_{et}LSNs_{eom}, M-P_{et}LSNs_{iom}, and D-P_{et}LSN$ showed a exfoliated structure and exhibited faster crystallization rate, better thermal stability and mechanical property than those of neat PET due to the dispersed and detaminated silicate layers in PET matrix. Whereas, considering organic modifiers effect, $M-P_{et}LSNs_{eom} and D-P_{et}LSN$ exhibited slower crystallization rate, poorer optical, thermal and mechanical properties, in comparison to $M-P_{et}LSNs_{eom}> due to the thermal decomposition of organic modifier in $D-P_{et}LSNs$ during melt method.

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A New Organic Modifiers for Anti-Stiction (부착방지를 위한 새로운 표면 개질 물질)

  • Kim, Bong-Hwan;Chun, Kuk-Jin;Lee, Yoon-Sik
    • Journal of Sensor Science and Technology
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    • v.11 no.2
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    • pp.102-110
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    • 2002
  • The chemical and mechanical characteristics of a new surface modifier, dichlorodimethysilane (DDMS, $(CH_3)_3SiCl_2$), for stiction-free polysilicon surfaces are reported. The main strategy is to replace the conventional monoalkyltrichlorosilane(MTS, $RSiCl_3$) such as octadecyltrichlorosilane (ODTS) or 1H,1H,2H,2H-perfluorodecyltrichlorosilane (FDTS) with dialkyldichlorosilane (DDS, $R_2SiCl_2$) with twit short chains, especially DDMS. DDMS, with shorter chains in aprotic media, rapidly deposits on the chemically oxidized polysilicon surface at room temperature and successfully prevents long cantilevers of 3 mm in length from in-use as well as release stiction. DDMS-modified polysilicon surfaces exhibit satisfactory hydrophobicity, long term stability and thermal stability, which are comparable to those of FDTS. DDMS as an alternative to FDTS and ODTS provides a few valuable advantages; ease in handling and long-term storage in solution, low temperature-dependence and low cost. In addition to the new modifier molecule, the simplified process of direct release right after washing the modified surface with isooctane was proposed to cut the processing time.

The Meaning of "modern style (hyundae-sik)" in Related Documents of the ROK Office in the 1950s (1950년대의 한국에서 신축 정부청사 관련 문건에 나타난 "현대식"의 의미)

  • Lee, Sumin;Woo, Don-Son
    • Journal of architectural history
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    • v.27 no.5
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    • pp.17-26
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    • 2018
  • In 1961, the Republic of Korea's first newly-constructed government building was completed. The government building, as ROK office, was erected as a twin with the USOM office in Sejong-ro. The reason why the ROK office and the USOM office were erected as a twin building is that the two offices were part of Foreign Operation Administration's Seoul Buildings Project in 1954. Within the project, the FOA office and the ROK office were rarely separated, and naturally, the ROK office was built according to the US standards. The planning, design, and construction phases which led by the US government were involved in the US architecture, engineering-construction companies. Because those AEC companies were familiar with the US technology and standards. In the phase of construction, Korean companies took part in the process under the supervise of Vinnell Corporation. The US expected to transfer its 'modern' and 'developed' technology through this process. The completed ROK office was widely known as the 'modern style (hyundae-sik)' building, which was body forth as glasses and new facilities. These factors were what the US emphasized for exporting architecture. The modifier, 'modern style (hyundae-sik)', given to the ROK office in the 1950s was a synonym for any new feeling that had never been seen hitherto. The newness of the ROK office, the 'modern style (hyundae-sik)' building, was specified as materials and facilities that indicates modern technology while in the absence of adequate knowledge.

The Effect of Sr Addition and Mold Preheating Temperature on the Solidification and Microstructure of Al-7wt%Si-0.3wt%Mg Alloy (Al-7wt%Si-0.3wt%Mg 합금의 응고 및 미세조직에 미치는 Sr 첨가와 금형예열온도의 영향)

  • Kwon, Il-Soo;Kim, Kyoung-Min;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.608-614
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    • 1997
  • The effect of mold preheating temperature on the microstructure such as grain size, eutectic silicon morphology was investigated for the Al-7wt%Si-0.3wt%Mg alloy. Microstructural variations have been characterized as a function of Sr addition and cooling rate during solidification. Microstructures were correlated with cooling rate, local solidification time and eutectic nucleation temperature, etc. In this study, Sr addition caused increase of local solidification time, undercooling and reduction of eutectic plateau temperature. In logarithmic scale, local solidification time was in inverse proportion to cooling rate. Eutectic nucleation temperature was in inverse proportion to cooling rate of logarithmic scale. Increasing the cooling rate refined dendrite arm spacing and eutectic silicon. Dendrite arm spacing was logarithmically in inverse proportion to cooling rate. Without modifier addition, eutectic silicon was modified at cooling rate of $7^{\circ}C/s$ or higher.

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Liquid Chromatographic Resolution of Tocainide and Its Analogues on a Doubly Tethered Chiral Stationary Phase Based on (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic Acid

  • Kim, Hee-Jin;Choi, Hee-Jung;Hyun, Myung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.31 no.3
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    • pp.678-682
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    • 2010
  • A doubly tethered chiral stationary phase (CSP) based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid were applied to the liquid chromatographic resolution of racemic tocainide, an antiarrhythmic agent, and its analogues. The chiral recognition efficiency of the doubly tethered CSP for tocainide and its analogues was generally greater than that of the corresponding singly tethered CSP especially in terms of the resolution ($R_S$). The resolution of tocainide and its analogues on the doubly tethered CSP were dependent on the content and the type of the organic and acidic modifiers in aqueous mobile phase and the column temperature. Especially, the retention behaviors of analytes on the doubly tethered CSP with the variation of the content of organic modifier in aqueous mobile phase were opposite to those on the corresponding singly tethered CSP and these opposite retention behaviors were rationalized by the lipophilicity differences of the two CSPs.