In this study, the behavior of water droplet impacting on a thin horizontal wire was visualized by time-delay photography. The impact behavior modes, critical capture speed and trapped mass were analyzed by changing the droplet size, velocity, wire diameter and eccentricity ratio. As the Weber number increased, the hanging, merging, and splitting modes appeared sequentially for the case of central impact, and the hanging and non-splitting modes appeared for the case of off-center impact. The boundary We number of each mode was affected by the diameter ratio. The critical capture speed was affected much by the degree of eccentricity. For all diameter ratios, it was higher for the case of central impact than for off-center impact. The trapped mass was larger for the case of central impact than for off-center impact and it increased with the smaller We number and the larger diameter ratio.