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Development of an Oraganic-Inorganic Hybrid Coating Solution for Improvement in Flame Retardant Properties of Wallpapers

벽지의 방염특성을 개선하기 위한 유-무기 하이브리드 코팅 용액 개발

  • Jeong, Gyu Jin (Optic & Electronic Component Materials Center, Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Kang, Tae Wook (Optic & Electronic Component Materials Center, Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Jin Ho (Optic & Electronic Component Materials Center, Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Bong Man (SUNKYUNG CO., LTD) ;
  • Seo, Eun Kyung (SUNKYUNG CO., LTD) ;
  • Bae, Byungseo (Material Convergence R&BD Team, Yeongwol Industrial Promotion Agency) ;
  • Kim, Sun Woog (Optic & Electronic Component Materials Center, Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering and Technology)
  • 정규진 (한국세라믹기술원 전자융합본부 광전자부품소재센터) ;
  • 강태욱 (한국세라믹기술원 전자융합본부 광전자부품소재센터) ;
  • 김진호 (한국세라믹기술원 전자융합본부 광전자부품소재센터) ;
  • 김봉만 ((주) 선경산업) ;
  • 서은경 ((주) 선경산업) ;
  • 배병서 (영월산업진흥원 소재융합사업팀) ;
  • 김선욱 (한국세라믹기술원 전자융합본부 광전자부품소재센터)
  • Received : 2021.10.20
  • Accepted : 2021.12.01
  • Published : 2022.03.01

Abstract

For enhancing the flame-retardant properties of wallpapers, we developed an organic-inorganic hybrid solution with ZrSiO4 as a functional ceramic powder, coated on non-woven fabric using dip coating, spray coating, and slot-die coating methods. Their flame retardant properties were characterized by a 45° combustion tester, which is manufactured according to the flame-retardant performance standard (KOFEIS 1001 and KS F 2819). In organic-inorganic hybrid solution, with increasing the concentration of acid-catalyst (acetic acid), the precipitation of ZrSiO4 powders increased, and the flame retardant properties decreased. The highest flame retardant result was obtained for the solution adding 5 wt% acetic acid. The optimization of the coating method and coating number resulted in the most excellent flame-retardant properties being obtained for the non-woven fabric coated for 5 or 7 times by dip coating method, and their flame-retardant properties corresponded to class 2 flame-retardant performance of wallpapers.

Keywords

Acknowledgement

본 연구는 2020년도 중소벤처기업부의 기술개발사업 지원에 의한 연구임[S2895814].

References

  1. Y. Hu, B. Yu, and L. Song, Novel Fire Retardant Polymers and Composite Materials, Chapter 3 (Woodhead Publishing, England, 2017), pp.53-59.
  2. Z. Wang, E. Han, and W. Ke, Prog. Org. Coat., 53, 29 (2005). [DOI: https://doi.org/10.1016/j.porgcoat.2005.01.004]
  3. K. H. Oh, H. J. Kim, and S. E. Lee, Fire Sci. Eng., 23, 111 (2009).
  4. S. Li, X. Lin, Z. Li and X. Ren, Compos. Commun., 14, 15 (2019). [DOI: https://doi.org/10.1016/j.coco.2019.05.005]
  5. S. Ullah and F. Ahmad, Polym. Degrad. Stab., 103, 49 (2014). [DOI: https://doi.org/10.1016/j.polymdegradstab.2014.02.016]
  6. B. S. Bae, Polym. Sci. Tech., 12, 716 (2001).
  7. J. Gu, G. Zhang, S. Dong, Q. Zhang, and J. Kong, Surf. Coat. Technol., 201, 7835 (2007). [DOI: https://doi.org/10.1016/j.surfcoat.2007.03.020]
  8. S. Li, F. Ding, X. Lin, Z. Li, and X. Ren, Fibers Polym., 20, 538 (2019). [DOI: https://doi.org/10.1007/s12221-019-8914-z]
  9. S. H. Jeong, J. H. Heo, J. W. Lee, M. J. Kim, C. H. Park, and J. H. Lee, ACS Appl. Mater. Interfaces, 13, 22935 (2021). [DOI: https://doi.org/10.1021/acsami.1c02021]
  10. P. Qi, X. Wang, Y. Wang, X. Gu, and S. Zhang, J. Ind. Text. (2020). [DOI: https://doi.org/10.1177/1528 083720938158]
  11. E. Jin and Y. J. Chung, J. Fire Sci., 38, 504 (2020). [DOI: https://doi.org/10.1177/0734904120948215]
  12. D. H. Son, Y. Y. Lee, S. J. Kim, S. S. Hong, G. D. Lee, and S. S. Park, Appl. Chem. Eng., 22, 691 (2011).
  13. Y. Ren, Y. Zhang, J. Zhao, X. Wang, Q. Zeng, and Y. Gu, J. Sol-gel Sci. Technol., 82, 280 (2017). [DOI: https://doi.org/10.1007/s10971-016-4273-z]
  14. X. Q. Cao, R. Vassen, F. Tietz, and D. Stoever, J. Eur. Ceram. Soc., 26, 247 (2006). [DOI: https://doi.org/10.1016/j.jeurceramsoc.2004.11.007]