Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Emulsification of the Mixture of Catalytic Pyrolysis Oil Obtained under Methane and Nitrogen Environment in Diesel Using Span 80 and Atlox 4916 as Surfactants

  • Farooq, Abid (School of Environmental Engineering, University of Seoul) ;
  • Park, Young-Kwon (School of Environmental Engineering, University of Seoul)
  • Received : 2021.04.01
  • Accepted : 2021.04.26
  • Published : 2021.06.10
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Abstract

Emulsions were prepared using a mixture of bio-oil obtained from the pyrolysis of sawdust in an N2 environment and Quercus mongolica in a CH4 environment for both non-catalytic and catalytic cases. Both prepared emulsions were examined by measuring the physical stability and Fourier transform infrared spectroscopy. The emulsion with HLB 5.8 (Span 80 and Atlox 4916) for the ratio of bio-oil (B-oil and C-oil): surfactant: diesel = 10% : 3% : 87% showed stability for 15 days. Combining oils produced in N2 and CH4 environments could be a potential solution for generating high-quality emulsions with a high heating value.

Keywords

Acknowledgement

This work was supported by the New and Renewable Energy Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP), granted financial resource from the Ministry of Trade, Industry & Energy, Republic of Korea (No. 2017-3010092430).

References

  1. A. Abdullah, A. Ahmed, P. Akhter, A. Razzaq, M. Zafar, M. Hussain, N. Shahzad, K. Majeed, S. Khurrum, M. S. A. Bakar, and Y.-K. Park, Bioenergy potential and thermochemical characterization of lignocellulosic biomass residues available in Pakistan, Korean J. Chem. Eng., 37, 1899-1906 (2020). https://doi.org/10.1007/s11814-020-0624-0
  2. G. Ozsin, M. Kilic, E. Apaydin-Varol, A. E. Putun, and E. Putun, A thermo-kinetic study on co-pyrolysis of oil shale and polyethylene terephthalate using TGA/FT-IR, Korean J. Chem. Eng., 37, 1888-1898 (2020). https://doi.org/10.1007/s11814-020-0614-2
  3. Y. Liu, Y. Wu, M. Su, W. Liu, X. Li, and F. Liu, Developing Bronsted-Lewis acids bifunctionalized ionic liquids based heteropolyacid hybrid as high-efficient solid acids in esterification and biomass conversion, J. Ind. Eng. Chem., 92, 200-209 (2020). https://doi.org/10.1016/j.jiec.2020.09.005
  4. S.-K. Choi, Y.-S. Choi, Y.-W. Jeong, S.-Y. Han, and Q. V. Nguyen, Combustion characteristics of fuel blends of coffee waste-derived oil and polystyrene foam waste-derived oil in a pilot-scale burner, J. Korea Soc. Waste Manag., 37, 574-582 (2020). https://doi.org/10.9786/kswm.2020.37.8.574
  5. L. Zhu and Z. Zhong, Effects of cellulose, hemicellulose and lignin on biomass pyrolysis kinetics, Korean J. Chem. Eng., 37, 1660-1668 (2020). https://doi.org/10.1007/s11814-020-0553-y
  6. Q. K. Tran, S. Han, H. V. Ly, S.-S. Kim, and J. Kim, Hydrodeoxygenation of a bio-oil model compound derived from woody biomass using spray-pyrolysis-derived spherical γ-Al2O3-SiO2 catalysts, J. Ind. Eng. Chem., 92, 243-251 (2020). https://doi.org/10.1016/j.jiec.2020.09.012
  7. L. Santamaria, G. Lopez, A. Arregi, M. Artetxe, M. Amutio, J. Bilbao, and M. Olazar, Catalytic steam reforming of biomass fast pyrolysis volatiles over Ni-Co bimetallic catalysts, J. Ind. Eng. Chem., 91, 167-181 (2020). https://doi.org/10.1016/j.jiec.2020.07.050
  8. R. S. Tshikesho, A. Kumar, R. L. Huhnke, and A. Apblett, Catalytic co-pyrolysis of red cedar with methane to produce upgraded bio-oil, Bioresour. Technol., 285, 121299 (2019). https://doi.org/10.1016/j.biortech.2019.03.138
  9. B.-J. Lin, W.-H. Chen, W. M. Budzianowski, C.-T. Hsieh, and P.-H. Lin, Emulsification analysis of bio-oil and diesel under various combinations of emulsifiers, Appl. Energy, 178, 746-757 (2016). https://doi.org/10.1016/j.apenergy.2016.06.104
  10. C. Song, M. Y. Gim, Y. H. Lim, and D. H. Kim, Enhanced yield of benzene, toulene, and xylene from the co-aromatization of methane and propane over gallium supported on mesoporous ZSM-5 and ZSM-11, Fuel, 251, 404-412 (2019). https://doi.org/10.1016/j.fuel.2019.04.079
  11. Y.-T. Cheng, J. Jae, J. Shi, W. Fan, and G. W. Huber, Production of renewable aromatic compounds by catalytic fast pyrolysis of lignocellulosic biomass with bifunctional Ga/ZSM-5 catalysts, Angew. Chem. Int., 51, 1387-1390 (2012). https://doi.org/10.1002/anie.201107390
  12. G. J. Woo and Y.-M. Kim, Effect of torrefaction on the catalytic pyrolysis of miscanthus over HZSM-5 and HY, J. Korea Soc. Waste Manag., 37, 542-548 (2020). https://doi.org/10.9786/kswm.2020.37.8.542
  13. S. Moogi, J. Jae, H. P. R. Kannapu, A. Ahmed, E. D. Park, and Y.-K. Park, Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition, Bioresour. Technol., 315, 123835 (2020). https://doi.org/10.1016/j.biortech.2020.123835
  14. Y.-H. Lee, C.-H. Jeong, H.-D. Jin, G. Y. Jeong, H.-J. Byeon, H.-M. Kim and D.-W. Jeong, A study on the optimization of fast pyrolysis system and deoxygenation for bio-oil production of unused agricultural by-products, J. Korea Soc. Waste Manag., 37, 531-541 (2020). https://doi.org/10.9786/kswm.2020.37.8.531
  15. M. Ikura, M. Stanciulescu, and E. Hogan, Emulsification of pyrolysis derived bio-oil in diesel fuel, Biomass Bioenergy, 24, 221-232 (2003). https://doi.org/10.1016/S0961-9534(02)00131-9
  16. K. Liu, W. Zhao, T. Guo, Q. Lei, Y. Guan, D. Wang, M. Cui, S. Fu, J. Zhao, Z. Zong, and X. Wei, Emulsification and performance measurement of bio-oil with diesel, Waste Biomass Valori., 12, 2933-2944 (2019).
  17. X. Jiang and N. Ellis, Upgrading bio-oil through emulsification with biodiesel: Mixture production, Energy Fuels, 24, 1358-1364 (2010). https://doi.org/10.1021/ef9010669
  18. A. Farooq, H. W. Lee, J. Jae, E. E. Kwon, and Y.-K. Park, Emulsification characteristics of ether extracted pyrolysis-oil in diesel using various combinations of emulsifiers (span 80, atlox 4916 and zephrym pd3315) in double reactor system, Environ. Res., 184, 109267 (2020). https://doi.org/10.1016/j.envres.2020.109267
  19. Q. Yin, S. Wang, X. Li, Z. Guo, and Y. Gu, Review of bio-oil upgrading technologies and experimental study on emulsification of bio-oil and diesel, 2010 Int. Conf. Opt. Image Proce., pp 343-347 (2010).
  20. Y. Li, T. Wang, W. Liang, C. Wu, L. Ma, Q. Zhang, X. Zhang, and T. Jiang, Ultrasonic preparation of emulsions derived from aqueous bio-oil fraction and 0# diesel and combustion characteristics in diesel generator, Energy Fuels, 24, 1987-1995 (2010). https://doi.org/10.1021/ef9010934
  21. Z. G. Guo, S. R. Wang, and X. Y. Wang, Emulsification of bio-oil heavy fraction with diesel by mechanical and ultrasonic technologies, Appl. Mech. Mater., 316-317, 1133-1137 (2013). https://doi.org/10.4028/www.scientific.net/AMM.316-317.1133