Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Synthesis of Pd and Pt Based Low Cost Bimetallic Anode Electrocatalyst for Glycerol Electrooxidation in Membraneless Air Breathing Microfluidic Fuel Cell

  • Panjiara, Deoashish (Department of Chemical Engineering and Technology, Indian Institute of Technology (Banaras Hindu University)) ;
  • Pramanik, Hiralal (Department of Chemical Engineering and Technology, Indian Institute of Technology (Banaras Hindu University))
  • Received : 2020.06.15
  • Accepted : 2020.08.16
  • Published : 2021.02.28
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Abstract

The different weight ratios of Pd to Pt, i.e., 16:4, 10:10, 4:16 in Pd-Pt/C and Pd (20 wt. %) /C electrocatalysts with low metal loading were synthesized for glycerol electrooxidation in an air breathing microfluidic fuel cell (MFC). The cell performance on Pd-Pt (16:4)/C anode electrocatalyst was found best among all the electrocatalysts tested. The single cell when tested at a temperature of 35℃ using Pd-Pt (16:4)/C, showed maximum open circuit voltage (OCV) of 0.70 V and maximum power density of 2.77 mW/㎠ at a current density of 7.71 mA/㎠. The power density increased 1.45 times when cell temperature was raised from 35℃ to 75℃. The maximum OCV of 0.78 V and the maximum power density of 4.03 mW/㎠ at a current density of 10.47 mA/㎠ were observed at the temperature of 75℃. The results of CV substantiate the single cell performance for various operating parameters.

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References

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