• Title/Summary/Keyword: Microfluidic Fuel Cell

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Synthesis of Pd and Pt Based Low Cost Bimetallic Anode Electrocatalyst for Glycerol Electrooxidation in Membraneless Air Breathing Microfluidic Fuel Cell

  • Panjiara, Deoashish;Pramanik, Hiralal
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.38-57
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    • 2021
  • The different weight ratios of Pd to Pt, i.e., 16:4, 10:10, 4:16 in Pd-Pt/C and Pd (20 wt. %) /C electrocatalysts with low metal loading were synthesized for glycerol electrooxidation in an air breathing microfluidic fuel cell (MFC). The cell performance on Pd-Pt (16:4)/C anode electrocatalyst was found best among all the electrocatalysts tested. The single cell when tested at a temperature of 35℃ using Pd-Pt (16:4)/C, showed maximum open circuit voltage (OCV) of 0.70 V and maximum power density of 2.77 mW/㎠ at a current density of 7.71 mA/㎠. The power density increased 1.45 times when cell temperature was raised from 35℃ to 75℃. The maximum OCV of 0.78 V and the maximum power density of 4.03 mW/㎠ at a current density of 10.47 mA/㎠ were observed at the temperature of 75℃. The results of CV substantiate the single cell performance for various operating parameters.

Electrochemical Oxidation of Hydrazine in Membraneless Fuel Cells

  • Durga, S.;Ponmani, K.;Kiruthika, S.;Muthukumaran, B.
    • Journal of Electrochemical Science and Technology
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    • v.5 no.3
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    • pp.73-81
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    • 2014
  • This paper describes the continuous flow operation of membraneless sodium perborate fuel cell using acid/alkaline bipolar electrolyte. Here, hydrazine is used as a fuel and sodium perborate is used as an oxidant under Alkaline-acid media configuration. Sodium perborate affords hydrogen peroxide in aqueous medium. In our operation, the laminar flow based microfluidic membranleless fuel cell achieved a maximum power density of $27.2mW\;cm^{-2}$ when using alkaline hydrazine as the anolyte and acidic perborate as the catholyte at room temperature with a fuel mixture flow rate of $0.3mL\;min^{-1}$. The simple planar structured membraneless sodium perborate fuel cell enables high design flexibility and easy integration of the microscale fuel cell into actual microfluidic systems and portable power applications.

Fabrication of Co-Planar Type Single Chamber SOFC with Patterned Electrodes (패턴된 전극을 가진 표면 전도형 단실형 고체산화물 연료전지의 제조)

  • Ahn, Sung-Jin;Kim, Yong-Bum;Moon, Joo-Ho;Lee, Jong-Ho;Kim, Joo-Sun
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.798-804
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    • 2006
  • Co-planar type single chamber solid oxide fuel cell with patterned electrode on a surface of electrolyte has been fabricated by robo-dispensing method and microfluidic lithography. The cells were composed of NiO-GDC-Pd or NiO-SDC cermet anode, $(La_{0.7}Sr_{0.3})_{0.95}MnO_3$ cathode, and yttria stablized zirconia electrolyte. The cell performance at $900^{\circ}C$ was investigated as a function of electrode geometries, such as anode-to-cathode distance, numbers of electrode pairs. Relationship between OCV and I-V characteristics at the optimized operation condition was also studied by DC source meter under the mixed gas condition of methane, air, and nitrogen. An increase of anode-facing-cathode area leads to lower OCV due to intermixing between product gases of anode and cathode, which in turn decreases the oxygen partial pressure difference.

Characterization of Microfluidic Channels using DVD Pick-up Fluorescent Scanner (광 픽업 방식 형광스캐너를 이용한 미소유체 특성 분석)

  • Yim, Vit;Kim, Jae-Hyun;Lee, Seung-Yop;Park, Jung-Yul
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.12
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    • pp.1102-1106
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    • 2008
  • Microfluidics deals with the behavior, precise control and manipulation of fluids at a micro scale. It has become increasingly prevalent in various applications such as biomedical applications (diagnostics, therapeutics, and cell/tissue engineering), inkjet head, and fuel cells etc. The issue of inspection and characterization of microfluidics has emerged as a major consideration in design, fabrication, and detection of microfluidic devices. In this paper, we characterize a diffusion based mixing in Y-microchannel using a fluorescent optical scanner based on a DVD pick-up module, which is widely used in optical storages. Using fluorescent dye, we measure the fluorescent intensity that represents the mixing patterns in Y-microchannel. We also compare these experimental results with computational fluid dynamics (CFD) simulation ones. It is shown that the proposed optical scanner can be used as an alternative measurement system with high performance and cost-effectiveness, compared to conventional optical tools such as epifluorescent microscopes using high resolution CCD camera and confocal microscopes with photomultiplier (PMT) detectors.