Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Hydrogen Separation and Production using Proton-Conducting Ceramic Membrane Catalytic Reactors

프로톤 전도성 세라믹 멤브레인 촉매 반응기를 이용한 수소 분리 및 제조 기술

  • Seo, Minhye (Plant Engineering Division, Institute for Advanced Engineering) ;
  • Park, Eun Duck (Department of Energy Systems Research, Ajou University)
  • 서민혜 (고등기술연구원 플랜트엔지니어링센터) ;
  • 박은덕 (아주대학교 에너지시스템학부)
  • Received : 2019.05.28
  • Accepted : 2019.07.01
  • Published : 2019.10.01
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Abstract

Proton-conducting perovskite ceramic materials are highly promising for solid electrolytes as well as catalysts at high temperatures. Therefore, they possess an outstanding potential for the membrane reactor in which both reaction and separation occur at a same time. Especially, in the case of hydrogen production catalyst, hydrogen separation, and the membrane reactor coupled with catalyst and separation, extensive results have been reported on the effect of the dopant in the solid electrolytes, temperature, and composition of reactants on the performance. In this review, the recent research trend on the application of proton-conducting ceramic materials to hydrogen production catalyst, hydrogen separation, and membrane reactor is surveyed. Moreover, the potential application and prospect of these materials to the next-generation hydrogen production and separation is discussed.

프로톤 전도성 세라믹인 페로브스카이트 구조의 산화물은 고온 환경에서 고체 전해질 및 촉매로써 동시에 활용이 가능하여, 반응과 분리기능을 동시에 갖춘 멤브레인 반응기로 적용하기에 우수한 소재이다. 특히 수소 제조 촉매와 분리, 이를 결합한 멤브레인 반응기 개발에 관한 연구는 전해질 내 도핑 금속의 종류 및 온도, 반응물의 조성 등에 따라 다양한 연구 결과가 제시되고 있다. 이에 본 총설에서는 프로톤 전도성 세라믹반응기에서 메탄을 활용하여 수소 제조촉매와 멤브레인 반응기로 응용해 온 연구 동향을 살펴보고, 차세대 수소의 제조와 분리 기술로서의 응용분야 및 전망에 관해 고찰하고자 한다.

Keywords

References

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