Fig. 1. Distribution of soil sampling sites in (a) Samcheonpo and (b) Hadong areas.
Fig. 2. Spatial distribution of heavy metals in the Samcheonpo power plant area.
Fig. 3. Spatial distribution of heavy metals in the Hadong power plant area.
Fig. 4. The percentage distribution of heavy metals fraction of Samcheonpo soils by sequential extraction. -S and –D in each sample name represent surface and subsurface, respectively.
Fig. 5. The percentage distribution of heavy metals fraction of Hadong soils by sequential extraction. -S and –D in each sample name represent surface and subsurface, respectively.
Table 1. Classes of geoaccumulation index (Igeo) (Müller, 1981)
Table 2. Classes of enrichment factor (EF) (Sutherland, 2000)
Table 3. Values of pH, cation exchange capacity (CEC) and organic matter content of the Samcheonpo soil samples (units: CEC, meq/100 g, organic matter, %)
Table 4. Values of pH, cation exchange capacity (CEC) and organic matter content of the Hadong soil samples (units: CEC, meq/100 g, organic matter, %)
Table 5. Concentrations of heavy metals in the Samcheonpo soils (unit: mg/kg except Hg of μg/kg). The numbers in parentheses represent Korean Soil Warning Criteria for Area 1
Table 6. Concentrations of heavy metals in the Hadong soils (unit: mg/kg except Hg of μg/kg). The numbers in parentheses represent Korean Soil Warning Criteria for Area 1.
Table 6. Continued.
Table 7. Geoaccumulation index (Igeo) of the Samcheonpo soils
Table 8. Geoaccumulation index (Igeo) of the Hadong soils
Table 9. Enrichment factor of the Samcheonpo soils
Table 10. Enrichment factor of the Hadong soils
참고문헌
- Abbasi, S.A., Nipaney, P.C., and Soni, R. (1989) Environmental status of cobalt and its micro determination with 7-nitroso-8-hydroxy-quinoline-5-sulfonic acid in waters, aquatic weeds and animal tissues. Anal. Lett., v.22, p.225-235. https://doi.org/10.1080/00032718908051196
- Alloway, B.J. (1995) Heavy metals in soils, 2nd Ed. Chapman & Hall, Glasgow, UK, 155p.
- Alloway, B.J. (2008) Zinc in soils and crop nutrition, 2nd Ed. International Zinc Association and International Fertilizer Association, Brussels, Belgium, 16p.
- Bhuiyan, M.A.H., Parvez, L., Islam, M.A., Dampare, S.B., and Suzuki, S. (2010) Heavy metal pollution of coal mine-affected agricultural soils in the northern part of Bangladesh. J. Hazard. Mater., v.173, p.384-392. https://doi.org/10.1016/j.jhazmat.2009.08.085
- Blaser P., Zimmermann, S., Luster, J., and Shotyk, W. (2000) Critical examination of trace element enrichments and depletions in soils: As, Cr, Cu, Ni, Pb, and Zn in Swiss forest soils. Sci. Tot. Environ., v.249, p.257-280. https://doi.org/10.1016/S0048-9697(99)00522-7
- Boyle, J. (2004) A comparison of two methods for estimating the organic matter content of sediments. J. Paleolimn., v.31, p.125-127. https://doi.org/10.1023/B:JOPL.0000013354.67645.df
- Buat-Menard, P. and Chesselet, R. (1979) Variable influence of the atmospheric flux on the trace metal chemistry of oceanic suspended matter. Earth Planet. Sci. Lett., v.42, p.398-411.
- Chabukdhara, M. and Nema, A.K. (2012) Assessment of heavy metal contamination in Hindon River sediments: A chemometric and geochemical approach. Chemosphere, v.87, p.945-953. https://doi.org/10.1016/j.chemosphere.2012.01.055
- Chen, J., Liu, G., Kang, Y., Wu, B., Sun, R., Zhou, C., and Wu, D. (2013) Atmospheric emissions of F, As, Se, Hg, and Sb from coal-fired power and heat generation in China. Chemosphere, v.90, p.1925-1932. https://doi.org/10.1016/j.chemosphere.2012.10.032
- Cheng, K., Tian, H.Z., Zhao, D., Lu, L., Wang, Y., Chen, J., Liu, X.G., Jia, W.X., and Huang, Z. (2014) Atmospheric emission inventory of cadmium from anthropogenic sources. Int. J. Environ. Sci. Technol., v.11, p.605-616. https://doi.org/10.1007/s13762-013-0206-3
- Cox, D.P. (1979) Copper in the environment, part I: Ecological cycling, Ed. Nriagu, J.O. Wiley, New York, p.19-42.
- Environmental Health and Engineering (EH&E) (2011) Emissions of hazardous air pollutants from coal-fired power plants, Environmental Health and Engineering, Inc., Newton, MA, 11p.
- Emsley, J. (2001) Chromium - Nature's building blocks: An A-Z guide to the elements. Oxford University Press, New York, 136p.
- Enamorado-Baez, S.M., Gomez-Guzman, J.M., Chamizo, E., and Abril, J.M. (2015) Levels of 25 trace elements in high-volume air filter samples from Seville (2001-2002): Sources, enrichment factors and temporal variations. Atmos. Res., v.155, p.118-129. https://doi.org/10.1016/j.atmosres.2014.12.005
- Fay, J.A. and Golomb, D.S. (2002) Energy and the environment. Oxford University Press, New York, 112p.
- Fernandez-Turiel, J.L., Carvalho, W., Cabanas, M., Querol, X., and Lopez-Soler, A. (1994) Mobility of heavy metals from coal fly ash. J. Environ. Geol., v.23, p.264-270. https://doi.org/10.1007/BF00766741
- Heinrichs, H., Schultz, D.B., and Wedepohl, K.J. (1980) Terrestrial geochemistry of Cd, Bi, Tl, Pb, Zn and Rb. Geochim. Cosmochim. Acta, v.44, p.1519-1532. https://doi.org/10.1016/0016-7037(80)90116-7
- Ketris, M.P. and Yudovich, Y.E. (2009) Estimations of Clarkes for Carbonaceous biolithes: World averages for trace element contents in black shales and coals. Int. J. Coal Geol., v.78, p.135-148. https://doi.org/10.1016/j.coal.2009.01.002
- Kim, G.H., Kim, G.Y., Kim, J.K., S, D.M., Seo, J.S., Son, B.K., Yang, J.E., Um, K.C., Lee, S.E., Jeong, K.Y., Jeong, D.Y., Jeong, Y.T., Jeong, J.B., and Hyeon, H.N. (2009) Soil science, 2nd Ed. Hyangmoon-sa, Seoul, Korea, 195p. (in Korean)
- Korean Statistical Information Service (KOSIS), 2019.03.08, http://kosis.kr.
- Mandal, A. and Sengupta, D. (2006) An assessment of soil contamination due to heavy metals around a coalfired thermal power plant in India. Environ. Geol., v.51, p.409-420. https://doi.org/10.1007/s00254-006-0336-8
- Marett, L.S. (2007) Trace metal particulates in coal-fired power plant emissions. MS Thesis, University of Georgia, USA, p.8.
- Maurizio, B., Angela, N., and Giuseppe, S. (2015) Soil contamination evaluation by enrichment factor (EF) and geoaccumulation index (Igeo). Senses Sciences, v.2, p.94-97.
- Merian, E. (1991) Metals and their compounds in the environment Part I. VCH Verlagsgesellschaft mbH, Weinheim, Germany, p.6.
- Ministry of Environment (MOE) (2018) Report on soil measurement network and soil contamination actual condition in 2017. 2019.03.08, http://webbook.me.go.kr/DLi-File/091/027/003/5671217.pdf.
- Mirjana, C. Snezana, D. Milan, D. Ranko, D., and Bosko, G. (2016) Environmental assessment of heavy metals around the largest coal fired power plant in Serbia. Catena., v.139, p.44-52. https://doi.org/10.1016/j.catena.2015.12.001
- Muller, G. (1969) Index of geoaccumulation in the sediments of the Rhine River. J. Geol., v.2, p.108-118.
- Muller, G. (1981) Die Schwermetallbelstung der sedimente des Neckars und seiner Nebenflusse: eine Bestandsaufnahme. Chemical Zeitung., v.105, p.157-164.
- Nowrouzi, M. and Pourkhabbaz, A. (2014) Application of geoaccumulation index and enrichment factor for assessing metal contamination in the sediments of Hara Biosphere Reserve, Iran. Chem. Speciation Bioavail., v.26, p.99-105. https://doi.org/10.3184/095422914X13951584546986
- Reiman, C. and Decarital, P. (2000) Intrinsic flaws of element enrichment factors (Efs) in environmental geochemistry. Environ. Sci. Technol., v.34, p.5084-5091. https://doi.org/10.1021/es001339o
- Richard, F.C. and Bourg, A.C.M. (1991) Aqueous geochemistry of chromium: A review. Water Res., v.25, p.807-816. https://doi.org/10.1016/0043-1354(91)90160-R
- Roh, A.S., Park, J.S., Kim, Y.H., and Kang, S.S. (2015) Status and changes in chemical properties of paddy soil in Gyeonggi Province. Korean J. Soil. Sci. Fert., v.48, p.968-972. (in Korean)
- Shao, X., Cheng, H., Li, Q., and Lin, C. (2013) Anthropogenic atmospheric emissions of cadmium in China. Atmos. Environ., v.79, p.155-160. https://doi.org/10.1016/j.atmosenv.2013.05.055
- Song, C.-W., Han, H.-J., and Lee, J.-U. (2019) Investigation on heavy metal distribution in soils around Boryeong coal-fired power plant. J. Korean Soc. Miner. Energy Resour. Eng., v.56, p.10-22. (in Korean) https://doi.org/10.32390/ksmer.2019.56.1.010
- Srinivasa, G.S., Ramakrishna, R.M., and Govil, P.K. (2010) Assessment of heavy metal contamination in soils at Jajmau (Kanpur) and Unnao industrial areas of the Ganga Plain, Uttar Pradesh, India. J. Hazard. Mater., v.174, p.113-121. https://doi.org/10.1016/j.jhazmat.2009.09.024
- Suh, J.W., Yoon, H.O., and Jeong, C.H. (2008) The distribution characteristics and contaminated of heavy metals in soil from Dalcheon Mine. J. Miner. Soc. Korea, v.21, p.57-65. (in Korean)
- Sutherland, R.A. (2000) Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii. Environ. Geol., v.39, p.611-627. https://doi.org/10.1007/s002540050473
- Taylor, S.R. (1964) Abundance of chemical elements in the continental crust - a new table. Geochim. Cosmochim. Acta, v.28, p.1273-1285. https://doi.org/10.1016/0016-7037(64)90129-2
- Taylor, S.R. and McLennan, S.M. (1995) The geochemical evolution of the continental crust. Rev. Geophys., v.33, p.241-265. https://doi.org/10.1029/95RG00262
- Tessier, A., Campbell, P.G.C., and Bisson, M. (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem., v.51, p.844-851. https://doi.org/10.1021/ac50043a017
- Tian, H., Zhao, D., Cheng, K., Lu, L., He, M., and Hao, J. (2012) Anthropogenic atmospheric emissions of antimony and its spatial distribution characteristics in China. Environ. Sci. Technol., v.46, p.3973-3980. https://doi.org/10.1021/es2041465
- Uduma, A.U. and Awagu, E.F. (2013) Manganese as a reference element for the assessment of zinc enrichment and depletion in selected farming soil of Nigeria. Res. J. Environ. Earth Sci., v.5, p.497-504. https://doi.org/10.19026/rjees.5.5679
- Wang, Q., Shen, W., and Ma, Z. (2000) Estimation of mercury emission from coal combustion in China. Environ. Sci. Technol., v.34, p.2711-2713. https://doi.org/10.1021/es990774j
- Wang, W., Qin, Y., Song, D., and Wang, K. (2008) Column leaching of coal and its combustion residues, Shizuishan, China. Int. J. Coal Geol., v.75, p.81-87. https://doi.org/10.1016/j.coal.2008.02.004
- Xianfei, H., Jiwei, H., Fanxin, Q., Wenxuan, Q., Rensheng, C., Mingyi, F., and Xianliang, W. (2017) Heavy metal pollution and ecological assessment around the Jinsha coal-fired power plant (China). Int. J. Environ. Res. Public Health., v.14, p.1-12. https://doi.org/10.3390/ijerph14010001
- Yaroshevsky, A.A. (2005) Abundances of chemical elements in the Earth's crust. Geochem. Int., v.44, p.48-55. https://doi.org/10.1134/S001670290601006X