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Gap-Fill Characteristics and Film Properties of DMDMOS Fabricated by an F-CVD System

  • Lee, Woojin (Process Development Team, Semiconductor R&D Center, Samsung Electronics Co., LTD.) ;
  • Fukazawa, Atsuki (ASM Japan K.K., R&D Process Development) ;
  • Choa, Yong-Ho (Functional Nano-Materials Research Lab, Department of Chemical Engineering, Hanyang University)
  • Received : 2016.07.01
  • Accepted : 2016.07.14
  • Published : 2016.09.27

Abstract

The deposition process for the gap-filling of sub-micrometer trenches using DMDMOS, $(CH_3)_2Si(OCH_3)_2$, and $C_xH_yO_z$ by flowable chemical vapor deposition (F-CVD) is presented. We obtained low-k films that possess superior gap-filling properties on trench patterns without voids or delamination. The newly developed technique for the gap-filling of submicrometer features will have a great impact on IMD and STI for the next generation of microelectronic devices. Moreover, this bottom up gap-fill mode is expected to be universal in other chemical vapor deposition systems.

Keywords

References

  1. M. Borhr and Y. A. Elmansy, IEEE Trans. Electron Devices, 45, 620 (1998). https://doi.org/10.1109/16.661223
  2. The International Technology Roadmap for Semiconductors. 2004 Update.
  3. Z. C. Wu, Z. W. Shiung, C. C. Chiang, W. H. Wu, M. C. Chen, S. M. Jeng, W. Chang, P.F. Chou, S. M. Jang, C. H. Yu and M. S. Liang, J. Electrochem. Soc., 148, F115 (2001). https://doi.org/10.1149/1.1368108
  4. G. Y. Lee, D. C. Edelstein, R. Conti, W. Cote, K.-S. Low, D. Dobuzinsky, G. Feng, K. Dev, P. Wrschka, P. Shafer, R. Ramachandran, A. Simpson, E. Liniger, E. Simonyi, T. Dalton, T. Spooner, C. Jahnes, E. Kaltalioglu and A. Grill, Advanced Metallization Conference, SanDiego, 3-5 (2000).
  5. A. Grill and V. Patel, Mater. Res. Soc. Symp. Proc., 612, D2.9.1. (2000).
  6. H. j. Lee, J. S. Goo, S. H. Kim, J. G. Hong, H. D. Lee, H. H. Kang, S. I. Lee and M. Y. Lee, Jpn. J. Appl. Phys., 39, 3924 (2000). https://doi.org/10.1143/JJAP.39.3924
  7. V. Belot, R. Corriu, D. Leclercq, P. H. Mutin and A. Vioux, Chem. Mater., 3, 127 (1991). https://doi.org/10.1021/cm00013a029
  8. A. Hozumi, H. Sekoguchi and O. Takai, J. Electochem. Soc., 144, 2824 (1997). https://doi.org/10.1149/1.1837901
  9. P. G. Pai, S. S. Chao, Y. Takagi and G. Lucovski, J. Vac. Sci. Technol. A, 4, 689 (1986). https://doi.org/10.1116/1.573833
  10. E. Ritter, Opt. Acta, 9, 197 (1962). https://doi.org/10.1080/713826414
  11. K. C. Shin, H. B. Lee, O. K. Kwon, H. S. Park, W. Koh and S.W. Kang, J. Electrochem. Soc., 149, G109 (2002). https://doi.org/10.1149/1.1430230