The Journal of Korean Academy of Prosthodontics (대한치과보철학회지)

The Korean Academy of Prosthodonitics (대한치과보철학회)
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Evaluation of titanium surface properties by $Nd:YVO_4$ laser irradiation: pilot study

$Nd:YVO_4$ 레이저 조사에 따른 티타늄의 표면특성 평가: 예비 연구

  • Kim, Ae-Ra (Department of Prosthodontics, School of Dentistry, Chonnam National University) ;
  • Park, Ji-Yoon (Department of Dental Science, School of Dentistry, Chonnam National University) ;
  • Kim, Yeon (Department of Dental Science, School of Dentistry, Chonnam National University) ;
  • Jun, Sei-Won (Department of Dental Science, School of Dentistry, Chonnam National University) ;
  • Seo, Yoon-Jeong (Department of Prosthodontics, School of Dentistry, Chonnam National University) ;
  • Park, Sang-Won (Department of Prosthodontics, School of Dentistry, Chonnam National University)
  • 김애라 (전남대학교 치의학전문대학원 보철학교실) ;
  • 박지윤 (전남대학교 치의학전문대학원 치의학과) ;
  • 김연 (전남대학교 치의학전문대학원 치의학과) ;
  • 전세원 (전남대학교 치의학전문대학원 치의학과) ;
  • 서윤정 (전남대학교 치의학전문대학원 보철학교실) ;
  • 박상원 (전남대학교 치의학전문대학원 보철학교실)
  • Received : 2013.06.07
  • Accepted : 2013.07.04
  • Published : 2013.07.31
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Abstract

Purpose: This study was conducted to evaluate the roughness and surface alternations of three differently blasted titanium discs treated by $Nd:YVO_4$ Laser irradiation in different conditions. Materials and methods: Thirty commercially pure titanium discs were prepared and divided into three groups. Each group was consisted of 10 samples and blasted by $ZrO_2$ (zirconium dioxide), $Al_2O_3$ (aluminum oxide), and RBM (resorbable blasted media). All the samples were degreased by ultrasonic cleaner afterward. Nine different conditions were established by changing scanning speed (100, 300, 500 mm/s) and repetition rate (5, 15, 35 kHz) of $Nd:YVO_4$ Laser (Laser Pro D-20, Laserval $Korea^{(R)}$, Seoul, South Korea). After laser irradiation, a scanning electron microscope, X-ray diffraction analysis, energy dispersive X-ray spectroscopic analysis, and surface roughness analysis were used to assess the roughness and surface alternations of the samples. Results: According to a scanning electron microscope (SEM), titanium discs treated with laser irradiation showed characteristic patterns in contrast to the control which showed irregular patterns. According to the X-ray diffraction analysis, only $Al_2O_3$ group showed its own peak. The oxidation tendency and surface roughness of titanium were similar to the control in the energy dispersive X-ray spectroscopic analysis. The surface roughness was inversely proportional to the scanning speed, whereas proportional to the repetition rate of $Nd:YVO_4$. Conclusion: The surface microstructures and roughness of the test discs were modified by the radiation of $Nd:YVO_4$ laser. Therefore, laser irradiation could be considered one of the methods to modify implant surfaces for the enhancement of osseointegration.

연구 목적: 본 연구는 서로 다른 세가지 블라스팅 처리를 한 티타늄 디스크에$Nd:YVO_4$ 레이저 조사 조건을 달리한 후 조사하여 티타늄의 표면 거칠기 및 표면 변화를 관찰하기 위함이다. 연구 재료 및 방법: 디스크 형태의 상용 순수 티타늄 시편을 30개 준비하여 시료 표면을 각각 10개씩 $ZrO_2$ (zirconium dioxide), $Al_2O_3$ (aluminium oxide), RBM (resorbable blasted media)으로 블라스팅(blasting)하고 초음파 세척하였다. $Nd:YVO_4$ 레이저(Laser Pro D-20, Laserval $Korea^{(R)}$, Seoul, South Korea)에서 주사속도(100, 300, 500 mm/s)와 시간당 진동량(반복률) (5, 15, 35 kHz)을 다르게 하여 9가지 조건을 설정하였다. 레이저 조사 후 주사전자현미경, X-선 회절 분석 및 에너지 분산X선 분광분석, 표면 거칠기 분석을 통해 각 시편을 평가하고 분석하였다. 결과: 주사전자현미경의 결과 레이저 조사를 시행하지 않은 티타늄 표면은 방향성이 없는 불규칙한 형상을 보였고 레이저 조사를 처리한 시편은 특징적인 형태가 관찰되었다. X-선회절분석결과$ZrO_2$, RBM 의 고유피크는 관찰되지 않았으나 $Al_2O_3$분사한 군에서는 알루미나의 고유 피크가 관찰되었다. 에너지 분산X선 분광분석을 통해 관찰한 티타늄의 산화도 경향성과 표면 거칠기는 유사하였다. 표면 거칠기는 주사속도와 반복률에 따른 차이를 보였다(P<.05). 결론: 레이저 조사 조건에 따라 티타늄 디스크의 미세구조와 표면 거칠기가 변화되었다. 레이저 조사는 골유착을 증진시키기 위한 임플란트 표면을 변화시키는 방법중의 하나로 여길 수 있을 것이다.

Keywords

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