한국해양환경ㆍ에너지학회지 (Journal of the Korean Society for Marine Environment & Energy)

  • 제13권4호
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  • Pages.249-262
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  • 2010
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  • 2288-0089(pISSN)
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  • 2288-081X(eISSN)
한국해양환경•에너지학회 (The Korean Society for Marine Environment and Energy)
권호 표지

해양환경시료(해저퇴적물과 해양생물)에 축적된 석유계총탄화수소(TPHs) 분석에 대한 공정시험기준 제안

A Proposal of Standard Method for the Analysis of Total Petroleum Hydrocarbons (TPHs) in Marine Sediments and Biota

  • 투고 : 2010.04.16
  • 심사 : 2010.10.22
  • 발행 : 2010.11.25
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초록

석유계총탄화수소(Total Petroleum Hydrocarbons, TPHs)는 해양에 존재하는 주요 오염물질이지만 현재 해양환경공정시험기준에는 TPHs 함량분석 기준이 해수를 제외한 해저퇴적물과 해양생물에 대해서는 등재되어 있지 않기 때문에 유류 오염 관리에서 투명성이 결여될 수 있다. 한편 토양의 TPHs 함량을 조사하는 시험방법은 토양오염공정시험기준에 포함되어있다. 따라서 본 연구에서는 토양오염공정시험기준의 TPHs 시험방법을 근간으로 하여 실제 해양환경시료인 해저퇴적물과 해양생물 수 종의 시료를 대상으로 이의 적용성을 GC-MSD를 이용하여 정량적으로 검토하였다. 이 검토 결과를 바탕으로 분석 정도 관리를 위한 회수율 검정 방법을 새로이 제안하였고, 해저퇴적물에 포함된 황, 해양생물내의 지질, 그리고 다양한 극성물질들이 TPHs 정량에 미치는 영향을 제거하기 위한 정제과정을 추가하여 해양환경시료의 TPHs 함량시험방법을 새로 제안하였다.

Regulatory test method for Total Petroleum Hydrocarbons (TPHs) in the marine sediment and biota has not still been established even though TPHs are one of the major pollutants in marine environment. Based on the Korean Soil Standard Method (SSM) for TPHs, we considered a new treatment method for determining TPHs in marine environmental samples by using a Gas chromatography coupled with Mass spectrometric detector. We suggested an improved recovery test for quality control procedures and introduced analytical procedures of removing sulfur, polar organic materials, water and saponification for removing neutral lipids in marine bottom sediments and biota.

키워드

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