KSCE Journal of Civil and Environmental Engineering Research (대한토목학회논문집)

Korean Society of Civil Engeneers (대한토목학회)
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On the Crystalline Structures of Iron Oxides formed During Removal Process of Iron in Water

수중의 철 제거 시 생기는 산화철의 결정구조에 관한 연구

  • 조봉연 (동국대학교 공과대학 토목환경공학과)
  • Received : 2005.04.13
  • Accepted : 2005.11.09
  • Published : 2006.01.31
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Abstract

The samples collected from two reactors are analyzed by X-ray diffraction and M$\ddot{o}$ssbauer spectroscopy in this study. It is concluded that the iron oxide crystal attached on anthracite media which possesses catalytic ability is identified to be Ferrihydrite, regardless of the value of pH from the analysis of the iron oxide. Iron oxide in Batch reactor is identified to be Microcrystalline goethite.

2종류의 제철 반응조에 있어서, 각종의 반응조건 하에 생성한 산화철을 x-ray회절과 M$\ddot{o}$ssbauer spectroscopy실험으로 철산화 물질을 동정한 결과, 여재 표면에 부착한 철 산화물의 결정은 pH 조건에 관계없이 Ferrihydrite($Fe_5HO_8{\cdot}4H_2O$)이었으며, Batch(회분) 실험에서 생긴 철 산화 물질은 가수분해에 의해 생긴 것으로, Microcrystalline Goethite 이었다.

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References

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