Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
권호 표지

Atom Transfer Radical Polymerization of Hexadecyl Acrylate Using CuSCN as the Catalyst

  • Xu, Wenjian (School of Chemistry and Chemical Engineering, Suzhou University) ;
  • Zhu, Xiulin (School of Chemistry and Chemical Engineering, Suzhou University) ;
  • Cheng, Zhenping (School of Chemistry and Chemical Engineering, Suzhou University) ;
  • Chen, Jianying (School of Chemistry and Chemical Engineering, Suzhou University) ;
  • Lu, Jianmei (School of Chemistry and Chemical Engineering, Suzhou University)
  • Published : 2004.02.01
Download PDF
⟨ Previous Next ⟩

Abstract

The atom transfer radical polymerization (ATRP) of hexadecyl acrylate (HDA) was carried out in Ν,Ν-dimethylformamide (DMF) in the presence of CuSCN/Ν,Ν,Ν′,Ν"Ν"-pentamethyldiethylenetriamine (PMDETA). The results indicate that the polymerization is well-controlled: a linear increase of molecular weights occurs with respect to conversion and the polydispersities are relatively low. In particular, the use of CuSCN as the catalyst resulted in faster polymerization rates for hexadecyl acrylate than did those using either CuBr or CuCl; the polydis-persity, however, was larger than those obtained in the cases when CuBr and CuCl were used. In addition, we report the thermodynamic data and activation parameters for the solution ATRP of hexadecyl acrylate.

Keywords

References

  1. Macromolecules v.32 J.Xia;K.Matyjaszewski https://doi.org/10.1021/ma990036f
  2. Polym. Int. v.49 X.P.Chen;K.Y.Qiu https://doi.org/10.1002/1097-0126(200011)49:11<1529::AID-PI564>3.0.CO;2-B
  3. Macromol. Chem. Phys. v.199 K.Matyjaszewski;M.Wei;J.Xia;S.G.Gaynor https://doi.org/10.1002/(SICI)1521-3935(19981001)199:10<2289::AID-MACP2289>3.0.CO;2-A
  4. Macromol. Rapid Commun. v.19 W.X.Wang;D.Y.Yang;P.Xia;Q.Zhang https://doi.org/10.1002/(SICI)1521-3927(19981201)19:12<647::AID-MARC647>3.0.CO;2-V
  5. J. Am. Chem. Soc. v.119 K.Matyjaszewski;T.E.Patten;J.Xia https://doi.org/10.1021/ja963361g
  6. Macromolecules v.28 V.Percec;B.Barboiu https://doi.org/10.1021/ma00127a057
  7. J. Polym. Sci., Part A:Polym. Chem. v.36 S.Coca;C.Jasieczek;K.L.Beers;K.Matyjaszewski https://doi.org/10.1002/(SICI)1099-0518(19980715)36:9<1417::AID-POLA9>3.0.CO;2-P
  8. Macromol. Chem. Phys. v.198 K.Matyjaszewski;S.Coca;C.B.Jasieczek https://doi.org/10.1002/macp.1997.021981219
  9. Macromolecules v.30 T.Grmaud;K.Matyjaszewski https://doi.org/10.1021/ma961796i
  10. Macromolecules v.30 D.M.Haddleton;C.B.Jasieczek;M.J.Hannon;A.J.Shooter https://doi.org/10.1021/ma961074r
  11. Macromolecules v.30 J.L.Wang;T.Grimaud;K.Matyjaszewski https://doi.org/10.1021/ma970636j
  12. J. Am. Chem. Soc. v.120 V.Percec;B.Barboiu;H.J.Kim https://doi.org/10.1021/ja9713845
  13. Macromolecules v.31 X.Zhang;J.Xia;K.Matyjaszewski https://doi.org/10.1021/ma980477j
  14. Macromolecules v.32 J.Qiu;S.G.Gaynor;K.Matyjaszewski
  15. Macromolecules v.32 K.Matyjaszewski;S.M.Jo;H.J.Paik;D.A.Shipp https://doi.org/10.1021/ma9905526
  16. Macromolecules v.30 K.Matyjaszewski;S.M.Jo;H.J.Paik;S.G.Gaynor https://doi.org/10.1021/ma9706384
  17. Macromolecules v.33 J.T.Rademacher;M.Baum;M.E.Pallack;Brittain, W. J. Simonsick;W.J.Jr. https://doi.org/10.1021/ma991550o
  18. Macromolecules v.32 M.Teodorescu;K.Matyjaszewski https://doi.org/10.1021/ma990175x
  19. Macromolecules v.32 M.Senoo;Y.Kotani;M.Kamigaito;M.Sawamoto https://doi.org/10.1021/ma9909814
  20. Chem. Commun. E.J.Ashford;V.Naldi;R.ODell;N.C.Billingham;S.P.Armes
  21. Macromolecules v.32 J.Xia;X.Zhang;K.Matyjaszewski https://doi.org/10.1021/ma9816968
  22. U.S.Pat. 5,834,408 M.K.Mishra;R.G.Saxton
  23. U.S.Pat. 6,2000,596 Schwartzmill, H. Donald;Randen;A.Weil
  24. J. Appl. Polym. Sci. v.86 P.J.Saikia;Goswami;S.D.Baruah https://doi.org/10.1002/app.10972
  25. J. Macromol. Sci. Pure v.38 K.L.Beer;K.Matyjaszewski https://doi.org/10.1081/MA-100103876
  26. Macromol. Rapid Commun. v.21 N.K.Singha;B.Klumperman https://doi.org/10.1002/1521-3927(20001101)21:16<1116::AID-MARC1116>3.0.CO;2-W
  27. Macromolecules v.30 J.H.Xia;K.Matyjaszewski https://doi.org/10.1021/ma971009x
  28. J. Polym. Sci. Part A:Polym. Chem. v.40 H.Q.Zhang;R.V.D.Linde https://doi.org/10.1002/pola.10460
  29. Macromolecules v.32 K.A.Davis;H.J.Paik;K.Matyjaszewski https://doi.org/10.1021/ma9815051
  30. Macromolecules v.30 K.A.Hutchinson;S.Beuermann;D.A.Paquet. Jr.;J.H.Mcminn https://doi.org/10.1021/ma970176u
  31. J. Appl. Polym. Sci. v.85 P.J.Saikia;A.Goswami;S.D.Baruah https://doi.org/10.1002/app.10687