Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
권호 표지

Preparation and Properties of Polyimides Having Highly Flexible Linkages and Their Nanocomposites with Organoclays

  • Cho, Young-Ho (School of Applied Chemistry and Chemical Engineering, Sungkyunkwan University) ;
  • Park, Jong-Min (School of Applied Chemistry and Chemical Engineering, Sungkyunkwan University) ;
  • Park, Yun-Heum (Hyperstructured Organic Research Center)
  • Published : 2004.02.01
Download PDF
⟨ Previous Next ⟩

Abstract

A highly flexible polyimide (PI) was synthesized successfully from ethylene glycol bis(anhydrotrimellitate) (TMEG) and 1,3-bis(4-aminophenoxy)benzene (TPER) for its application in electronics. To enhance the thermal stability and mechanical properties of this novel PI, we prepared PI nanocomposite films using nanoparticles of clays that had been treated with organic intercalating agents (organoclays). We used two types of organoclays: montmo-rillonite (MMT) treated with hexadecylamine (C$\_$16/) and MMT treated with dimethyl dihydrogenated tallow quaternary ammonium (l5A). PI/organoclay hybrid films were obtained by first preparing poly(amic acid) (PAA)/organoclay films and then converting the PAA to polyimide by thermal conversion. PAA was characterized by FT-IR and $^1$H-NMR spectroscopy and the conversion of PAA to PI was confirmed by FT-IR spectroscopy. We analyzed the dispersion of the organoclays in the PI film by X-ray diffraction. The thermal stability and mechanical properties of the hybrid films were also investigated.

Keywords

References

  1. J. Appl. Polym. Sci. v.55 A.Usuki;A.Koiwai;Y.Kojima;M.Kawasumi;A.Okada;T.Kurauchi;O.Kamigatio https://doi.org/10.1002/app.1995.070550113
  2. Macromolecules v.28 R.A.Vaia;K.D.Jandt;E.J.Kramer;E.P.Giannelis
  3. J. Appl. Polym. Sci. v.61 D.C.Lee;L.W.Jang
  4. Macromol. Res. v.13 J.G.Ryu;J.W.Lee;H.Kim
  5. Korea Polym. J. v.8 M.B.Ko;J.Kim;C.R.Choe
  6. Macromolecules v.33 X.Huang;S.Lewis;W.Brittain;R.Vaia https://doi.org/10.1021/ma991709x
  7. Polymer v.40 H.Tyan;Y.Liu;K.Wei https://doi.org/10.1016/S0032-3861(98)00716-2
  8. Polymer v.42 J.Huang;Z.Zhu;J.Yin;X.Qian;Y.Sun https://doi.org/10.1016/S0032-3861(00)00411-0
  9. Polymer v.41 M.Okamoto;S.Moritaa;H.Taguchia;Y.H.Kim;T.Kotaka;H.Tateyama https://doi.org/10.1016/S0032-3861(99)00655-2
  10. J. Appl. Polym. Sci. v.75 Z.Chen;C.Huang;S.Liu;Y.Zhang;K.Gong https://doi.org/10.1002/(SICI)1097-4628(20000207)75:6<796::AID-APP8>3.0.CO;2-#
  11. Appl. Clay Sci. v.15 C.L.Peter;W.Zhen;J.P.Thomas https://doi.org/10.1016/S0169-1317(99)00017-4
  12. Layered Silicate-Polymer Intercalation Compounds Y.Komori;K.Kuroda
  13. Polymer-Clay Nanocomposite M.Kato;A.Usuki
  14. Polymer v.43 D.M.Delozier;R.A.Orwoll;J.F.Cahoon;N.J.Johnston;J.G.Smith Jr.;J.W.Connell https://doi.org/10.1016/S0032-3861(01)00640-1
  15. J. Mater. Res. v.8 A.Usuki;M.Kawasumi;Y.Kojima;A.Okada;T.Kurauchi;O.Kamigaito https://doi.org/10.1557/JMR.1993.1174
  16. J. Polym. Sci., Part B:Polym. Phys. v.38 H.L.Tyan;K.H.Wei;T.E.Hsieh https://doi.org/10.1002/1099-0488(20001115)38:22<2873::AID-POLB20>3.0.CO;2-T
  17. J. Appl. Polym. Sci. v.79 G.U.Aijuan;F.C.Chang https://doi.org/10.1002/1097-4628(20010110)79:2<289::AID-APP100>3.0.CO;2-V
  18. Macromolecules v.14 J.F.Wolfe;F.E.Arnold https://doi.org/10.1021/ma50005a004
  19. Polyimides:Synthesis, Characterization, and Applications K.L.Mittal
  20. Advances in Polyimide Science and Technology Technomic C.Feger;M.M.Khojasteh;M.S.Htoo
  21. Macromole. Res. v.11 H.D.Park;K.Y,Ahn;Wahabma
  22. Korea Polym. J. v.9 M.Lee;T.J.Shin;S.W.Lee
  23. Polyimides:Fundamentals and Applications M.K.Ghosh;K.L.Mittal
  24. J. Appl. Polym. Sci. v.80 S.H.Hsiao;G.S.Liou;L.M.Chang https://doi.org/10.1002/app.1306
  25. Polym. Int. v.49 Y.Tong;Y.Li;F.Xie;M.Ding https://doi.org/10.1002/1097-0126(200011)49:11<1543::AID-PI535>3.0.CO;2-B
  26. J. Polym. Sci. Part B:Polym. Phys. v.39 J.H.Chang;D.K.Park;K.J.Ihn https://doi.org/10.1002/1099-0488(20010301)39:5<471::AID-POLB1020>3.0.CO;2-6
  27. Polymeric Materials Encyclopedia;J.C.Salamone(ed.) K.Asao;M.Mitoh
  28. J. Polym. Sci. Polym. Chem. Ed. v.22 Y.Imai;N.N.Malder;M.Kakimoto https://doi.org/10.1002/pol.1984.170220920
  29. J. Polym. Sci., Part A:Polym. Chem. v.29 H.J.Jeong;Y.Ohish https://doi.org/10.1002/pola.1991.080290106
  30. J. Polym. Sci. Part A:Polym. Chem. v.29 H.J.Jeong;M.Kakimoto;Y.Imai https://doi.org/10.1002/pola.1991.080291321
  31. Polymeric Material Encyclopedia C.P.Yang;J.H.Lin;J.C.Salamone(ed.)
  32. Eur. Polym. J. v.36 J.H.Chang;K.M.Park https://doi.org/10.1016/S0014-3057(99)00280-3
  33. J. Polym. Sci. Part A:Polym. Chem. v.35 K.Yano;A.Usuki;A.Okada https://doi.org/10.1002/(SICI)1099-0518(199708)35:11<2289::AID-POLA20>3.0.CO;2-9
  34. KP Patent, 0031687 SAEHAN. Co. Lid.
  35. Solid State Technol. v.39 T.DiStefano;J.Fjelstad
  36. Polymer v.42 J.C.Huang;Z.K.Zhu;J.Yin;X.F.Qian;Y.Y.Sun https://doi.org/10.1016/S0032-3861(00)00411-0
  37. Polymer v.40 Y.Yang;Z.Zhu;J.Yin;X.Wang;Z.Qi https://doi.org/10.1016/S0032-3861(98)00675-2
  38. J. Polym. Sci., Part A:Polym. Chem. v.31 K.Yano;A.Usuk;A.Okada;T.Kurauchi;O.Kamigaito https://doi.org/10.1002/pola.1993.080311009
  39. Polymer(Korea) v.26 Y.U.An;J.H.Chang;Y.H.Park;J.M.Park
  40. Mater. Sci. Eng. R. v.28 M.Alexandre;P.Dubois https://doi.org/10.1016/S0927-796X(00)00012-7