Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preparation and Characterization of Nickel(Ⅱ) and Copper(Ⅱ) Tetaaza Macrocyclic Complexes with Isonicotinate Ligands

  • Published : 2002.08.20
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Abstract

The complexes [Ni(L)(INT)2]${\cdot}$5H2O (1) and [Cu(L)(H2O)](Cl)(INT)${\cdot}$3H2O (2) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.18 ,07.12 ]docosane, INT = isonicotinate) have been prepared and characterized by X-ray crystallography, electronic absorption, and cyclic voltammetry. The crystal structure of 1 reveals an axially elongated octahedral geometry with two axial isonicotinate ligands. The electronic spectra, magnetic moment, and redox potentials of 1 also show a high-spin octahedral geometry. However, 2 shows that the coordination environment around the copper atom is a distorted square-pyramid with an axial water molecule. The spectra and electrochemical behaviors of 2 are also discussed.

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References

  1. Tu, C.; Silverman, D. N. Biochemistry 1989, 28, 7913. https://doi.org/10.1021/bi00445a054
  2. Merz, K. M.; Hoffmann, J. R.; Dewar, M. J. S. J. Am. Chem. Soc.1989, 111, 5637.
  3. Pocker, Y.; Deits, T. L. J. Am. Chem. Soc. 1982, 104, 2424. https://doi.org/10.1021/ja00373a016
  4. Kimura, E.; Koike, T.; Shionoya, M.; Shiro, M. Chem. Lett. 1992,787.
  5. Kimura, E. Prog. Inorg. Chem. 1994, 41, 443. https://doi.org/10.1002/9780470166420.ch6
  6. Bernhardt, P. V.; Hetherington, J. C.; Jones, L. A. J. Chem. Soc.,Dalton Trans. 1996, 4325.
  7. Kumar, K.; Chang, C. A.; Tweedle, M. F. Inorg. Chem. 1993, 32,587. https://doi.org/10.1021/ic00057a017
  8. Lehn, J. M.; Sauvage, J. P. J. Am. Chem. Soc. 1975, 97, 6700. https://doi.org/10.1021/ja00856a018
  9. Kumar, K.; Tweedle, M. F. Inorg. Chem. 1993, 32, 4193. https://doi.org/10.1021/ic00072a008
  10. Choi, K.-Y.; Ryu, H.; Suh, I.-H. Polyhedron 1998, 17, 1241. https://doi.org/10.1016/S0277-5387(97)00393-8
  11. Choi, K.-Y.; Kim, Y.-J.; Ryu, H.; Suh, I.-H. Inorg. Chem.Commun. 1999, 2, 176. https://doi.org/10.1016/S1387-7003(99)00041-6
  12. Choi, K.-Y.; Kim, J. C.; Jensen, W. P.; Suh, I.-H.; Choi, S.-S. ActaCrystallogr 1996, C52, 2166.
  13. Choi, K.-Y.; Oh, M. R.; Suh, I.-H. Chem. Lett. 1997, 141.
  14. Choi, K.-Y. J. Chem. Crystallogr. 1999, 28, 875. https://doi.org/10.1023/A:1022894318159
  15. Choi, K.-Y.; Chun, K. M.; Suh, I.-H. Polyhedron 2001, 20,57. https://doi.org/10.1016/S0277-5387(00)00593-3
  16. Escuer, A.; Vicente, R.; El Fallah, M. S.; Solans, X.; Font-Bardia,M. J. J. Chem. Soc., Dalton Trans. 1993, 2975.
  17. Escuer, A.; Vicente, R.; Ribas, J.; El Fallah, M. S.; Solans, X.Inorg. Chem. 1993, 32, 1033. https://doi.org/10.1021/ic00058a046
  18. Kang, S.-G.; Kweon, K. K.; Jung, S. K. Bull. Korean Chem. Soc.1991, 12, 483.
  19. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467.
  20. Sheldrick, G. M. SHELXL-97, Program for the Refinement ofCystal Structures; University of G ttingen: Germany, 1997.
  21. Choi, K.-Y.; Chun, K.-M.; Suh, I.-H. Polyhedron 1999, 18,2811. https://doi.org/10.1016/S0277-5387(99)00192-8
  22. Jide, X.; Shisheng, N.; Yuguan, L. Inorg. Chem. 1988, 27, 4651. https://doi.org/10.1021/ic00298a029
  23. Satate, Y.; Ihara, Y.; Senda, H.; Suzuki, M.; Uehara, A. Inorg.Chem. 1992, 31, 3248. https://doi.org/10.1021/ic00041a016
  24. Fallis, I. A.; Farrugia, L. J.; Macdonald, N. M.; Peacock, R. D. J.Chem. Soc., Dalton Trans. 1993, 2759.
  25. Choi, K.-Y.; Suh, I.-H. Polyhedron 1997, 16, 2393. https://doi.org/10.1016/S0277-5387(96)00578-5
  26. Choi, K.-Y.; Ryu, H.; Suh, I.-H. Inorg. Chim. Acta 2000, 299,268. https://doi.org/10.1016/S0020-1693(99)00492-2
  27. Holmes, R. R. J. Am. Chem. Soc. 1984, 106, 3745. https://doi.org/10.1021/ja00325a006
  28. Nakamoto, K. Infrared and Raman Spectra of Inorganic andCoordination Compounds, 4th ed.; John Wiley and Sons: NewYork, 1986.
  29. Nielson, D. O.; Larsen, M. L.; Willett, R. D.; Legg, J. I. J. Am.Chem. Soc. 1971, 93, 5079. https://doi.org/10.1021/ja00749a020

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