Browse > Article
http://dx.doi.org/10.5012/bkcs.2002.23.8.1062

Preparation and Characterization of Nickel(Ⅱ) and Copper(Ⅱ) Tetaaza Macrocyclic Complexes with Isonicotinate Ligands  

Choi, Ki-Young
Kim, Moon-Jip
Kim, Dae-Sue
Kim, Yong-Son
Kim, Jae-Hyun
Ryu, Hai-Il
Lim, Youn-Mook
Kang, Seung-Gu
Shin, Ueon-Sang
Lee, Kyu-Chul
Hong, Choon-Pyo
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.8, 2002 , pp. 1062-1066 More about this Journal
Abstract
The complexes [Ni(L)(INT)2]${\cdot}$5H2O (1) and [Cu(L)(H2O)](Cl)(INT)${\cdot}$3H2O (2) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.18 ,07.12 ]docosane, INT = isonicotinate) have been prepared and characterized by X-ray crystallography, electronic absorption, and cyclic voltammetry. The crystal structure of 1 reveals an axially elongated octahedral geometry with two axial isonicotinate ligands. The electronic spectra, magnetic moment, and redox potentials of 1 also show a high-spin octahedral geometry. However, 2 shows that the coordination environment around the copper atom is a distorted square-pyramid with an axial water molecule. The spectra and electrochemical behaviors of 2 are also discussed.
Keywords
Crystal structures; Macrocyclic; Isonicotinate; Nickel(Ⅱ) and copper(Ⅱ)complexes;
Citations & Related Records

Times Cited By Web Of Science : 8  (Related Records In Web of Science)
Times Cited By SCOPUS : 8
연도 인용수 순위
1 Escuer, A.; Vicente, R.; Ribas, J.; El Fallah, M. S.; Solans, X.Inorg. Chem. 1993, 32, 1033.   DOI   ScienceOn
2 Choi, K.-Y.; Kim, J. C.; Jensen, W. P.; Suh, I.-H.; Choi, S.-S. ActaCrystallogr 1996, C52, 2166.
3 Choi, K.-Y.; Suh, I.-H. Polyhedron 1997, 16, 2393.   DOI   ScienceOn
4 Kimura, E. Prog. Inorg. Chem. 1994, 41, 443.   DOI
5 Tu, C.; Silverman, D. N. Biochemistry 1989, 28, 7913.   DOI   ScienceOn
6 Merz, K. M.; Hoffmann, J. R.; Dewar, M. J. S. J. Am. Chem. Soc.1989, 111, 5637.
7 Pocker, Y.; Deits, T. L. J. Am. Chem. Soc. 1982, 104, 2424.   DOI
8 Choi, K.-Y. J. Chem. Crystallogr. 1999, 28, 875.   DOI   ScienceOn
9 Kang, S.-G.; Kweon, K. K.; Jung, S. K. Bull. Korean Chem. Soc.1991, 12, 483.
10 Sheldrick, G. M. SHELXL-97, Program for the Refinement ofCystal Structures; University of G ttingen: Germany, 1997.
11 Jide, X.; Shisheng, N.; Yuguan, L. Inorg. Chem. 1988, 27, 4651.   DOI
12 Fallis, I. A.; Farrugia, L. J.; Macdonald, N. M.; Peacock, R. D. J.Chem. Soc., Dalton Trans. 1993, 2759.
13 Escuer, A.; Vicente, R.; El Fallah, M. S.; Solans, X.; Font-Bardia,M. J. J. Chem. Soc., Dalton Trans. 1993, 2975.
14 Holmes, R. R. J. Am. Chem. Soc. 1984, 106, 3745.   DOI
15 Choi, K.-Y.; Ryu, H.; Suh, I.-H. Inorg. Chim. Acta 2000, 299,268.   DOI   ScienceOn
16 Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467.
17 Choi, K.-Y.; Chun, K. M.; Suh, I.-H. Polyhedron 2001, 20,57.   DOI   ScienceOn
18 Kumar, K.; Tweedle, M. F. Inorg. Chem. 1993, 32, 4193.   DOI   ScienceOn
19 Bernhardt, P. V.; Hetherington, J. C.; Jones, L. A. J. Chem. Soc.,Dalton Trans. 1996, 4325.
20 Nakamoto, K. Infrared and Raman Spectra of Inorganic andCoordination Compounds, 4th ed.; John Wiley and Sons: NewYork, 1986.
21 Choi, K.-Y.; Chun, K.-M.; Suh, I.-H. Polyhedron 1999, 18,2811.   DOI   ScienceOn
22 Kimura, E.; Koike, T.; Shionoya, M.; Shiro, M. Chem. Lett. 1992,787.
23 Lehn, J. M.; Sauvage, J. P. J. Am. Chem. Soc. 1975, 97, 6700.   DOI
24 Nielson, D. O.; Larsen, M. L.; Willett, R. D.; Legg, J. I. J. Am.Chem. Soc. 1971, 93, 5079.   DOI
25 Choi, K.-Y.; Oh, M. R.; Suh, I.-H. Chem. Lett. 1997, 141.
26 Satate, Y.; Ihara, Y.; Senda, H.; Suzuki, M.; Uehara, A. Inorg.Chem. 1992, 31, 3248.   DOI
27 Choi, K.-Y.; Kim, Y.-J.; Ryu, H.; Suh, I.-H. Inorg. Chem.Commun. 1999, 2, 176.   DOI   ScienceOn
28 Kumar, K.; Chang, C. A.; Tweedle, M. F. Inorg. Chem. 1993, 32,587.   DOI   ScienceOn
29 Choi, K.-Y.; Ryu, H.; Suh, I.-H. Polyhedron 1998, 17, 1241.   DOI   ScienceOn