• Title/Summary/Keyword: zeta전위

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Zeta-potential Measurement on Glass Surface by Measuring Electro-osmotic Velocity inside a Micro-channel (마이크로 채널 내부 전기삼투 유속 측정을 통한 유리표면의 Zeta-potential 측정)

  • Han, Su-Dong;Lee, Sang-Joon
    • 한국가시화정보학회:학술대회논문집
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    • 2005.12a
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    • pp.80-84
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    • 2005
  • Many important properties in colloidal systems are usually determined by surface charge ($\zeta$-potential) of the contacted solid surface. In this study, $\zeta$-potential of glass $\mu$-channel was evaluated from the electro-osmotic velocity distribution. The electro-osmotic velocity inside a glass $\mu$-channel was measured using a micro-PIV velocity field measurement technique. This evaluation method is more simple and easy to approach, compared with the traditional streaming potential technique. The $\zeta$-potential in the glass $\mu$-channel was measured for two different mole NaCl solutions. The effect of an anion surfactant, sodium dodecyl sulphate (SDS), on the electro-osmotic velocity and $\zeta$-potential in the glass surface was also studied. In the range of $0\∼6$mM, the surfactant SDS was added to NaCl solution in four different mole concentrations. As a result, the addition of SDS increases $\zeta$-potential in the surface of the glass $\mu$-channel. The measured $\zeta$-potential was found to vary from-260 to-70mV. When negatively charged particles were used, the flow direction was opposite compared with that of neutral particles. The $\zeta$-potential has a positive sign for the negative particles.

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Characterization of relationship between particle size and powder properties for $BaTiO_3$ ($BaTiO_3$의 입도와 분체특성과의 상관 관계 연구)

  • Chun, M.P.;Cho, J.H.;Kim, B.I.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.6
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    • pp.244-251
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    • 2005
  • The relationship between particle size of hydro-thermally synthesized barium titanate powders (BT01, BT02, BT03, BT04, BT05) and the powder properties was investigated by means of particle size, specific surface area, zeta potential, XPS, XRD and SEM. Particle size determined by laser light scattering is closely related with specific surface area and the tetragonality (c/a) obtained from XRD. The specific surface area of the samples inversely decreased with increasing particle size except BT03 powder. BT03 sample showed higher surface area than BT04 sample of equivalent particle size, which was attributed mostly to the agglomeration of particles in terms of SEM image and XRD analysis. Zeta potential increased with increasing particle size with the exception of BT02 and BT03 which showed larger minus value of zeta potential in comparison with other BT powders. Beta potential results of BT02 and BT03 are considered to be related with the dissolution of $Ba^{2+}$ ion in these powers which was examined by XPS.

Measurement of Zeta-potential of Electro-osmotic Flow Inside a Micro-channel (마이크로 채널 내부 전기삼투 유동의 Zeta-potential 계측)

  • Han Su-Dong;Lee Sang-Joon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.10 s.253
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    • pp.935-941
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    • 2006
  • Many important properties in colloidal systems are usually determined by surface charge $({\zeta}-potential)$ of the contacted solid surface. In this study, ${\zeta}-potential$ of glass ${\mu}-channel$ was evaluated from the electro-osmotic velocity distribution. The electro-osmotic velocity inside a glass f-channel was measured using a micro-PIV velocity field measurement technique. This evaluation method is more simple and easy to approach, compared with the traditional streaming potential technique. The ${\zeta}-potential$ in the glass ${\mu}-channel$ was measured fur two different mole NaCl solutions. The effect of an anion surfactant, sodium dodecyl sulphate (SDS), on the electro-osmotic velocity and f-potential in the glass surface was also studied. In the range of $0{\sim}6mM$, the surfactant SDS was added to NaCl solution in few different mole concentrations. As a result, the addition of SDS increases ${\zeta}-potential$ in the surface of the glass ${\mu}-channel$. The measured $\zeta-potential$ was found to vary from -260 to -70mV. When negatively charged particles were used, the flow direction was opposite compared with that of neutral particles. The ${\zeta}-potential$ has a positive sign for the negative particles.

Zeta Potential Measurement of Micro Bubbles Generated by Electrolysis (전기분해(電氣分解)시 알루미늄 극판(極板)에서 발생(發生)한 미세기포(微細氣泡)의 제타전위(電位) 측정(測定))

  • Kim, Won-Tae;Han, Moo-Young;Lee, Sung-Woo;Han, Yi-Seon
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.4
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    • pp.343-349
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    • 2000
  • Techniques such as dissolved air flotation and electroflotation, which utilize micro bubbles, are increasingly used for water and wastewater treatment. Most studies have concentrated on particle characteristics. Pretreatments that manipulate particle size and zeta potential were considered important. A recent study, which modeled the collision mechanism between micro bubbles and particles in dissolved air flotation, suggested bubble characteristics should also be important. Hydrogen micro bubbles were generated electrolytically and their zeta potentials measured under various conditions using a novel electrophoresis method. Effects of several parameters were investigated. Bubble zeta potentials were found to be pH dependent, and to have a negative value around neutral pH, becoming zero or positive at lower pH. The pH at zero zeta potential was 5.0 under study conditions. Using artificial solution and tap water, at fixed pH, bubble zeta potentials varied with solution composition. Zeta potentia]s of bubbles were affected by the types of cations and anions in solution but not by the voltage applied. These findings will help improve efficiencies of particle removal processes that utilize micro bubbles. As bubble zeta potential varies with solution composition, it needs to be measured for each composition to understand those effects, which increase removal efficiency.

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A Study on the Stability of DOPC Liposome (염의 농도에 따른 DOPC 리포좀의 안정성에 관한 연구)

  • Won, Doo-Hyun;Kim, Sun-Young;Lim, Gyu-Nam;Park, Soo-Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.1
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    • pp.55-60
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    • 2011
  • In this study, DOPC liposomes were prepared with distilled water, phosphate buffer and phosphate buffered saline to evaluate the effects of salt on the stability of DOPC liposome. The changes in physical properties (likeparticle size and zeta potential) of liposome were measured after adding the salt. Liposomes were diluted 40 times and 80 times with hydration solvent to confirm the effect of dilution. Consequently, the stability of liposome was maintained up to 40 times dilution with hydration solvent. The liposome that prepared with distilled water was diluted with distilled water, phosphate buffer and phosphate buffered saline, and the liposome that prepared with phosphate buffer was diluted with phosphate buffer and phosphate buffered saline to evaluate the salt-induced changes in particle size and zeta potentia. As results, the particle size increased slightly and zeta potential became closer to 0 when the salt concentration was increased. In conclusion, particle size and zeta potential of liposome could be reasonable factors to evaluate the stability of liposome. In addition, we suggest that salt concentration of hydration solvent has a significant effect on the stability of liposome.

Characteristics of oyster shell using zeta potential (제타 전위에 의한 참굴 패각의 특성연구)

  • Lee, Seung-Woo;Shin, Na-Young;Choi, Cheong-Song
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.890-893
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    • 2001
  • Zeta potential measurement not only can provide surface information on colloidal biomaterials but more importantly can be used in bioprocess control and products quality control. In this study, zeta potentials for intracrystalline proteins of each layers from oyster shell prepared in 1mM NaCl at different pH were measured. Also, in forming calcite crystals with intracrystalline proteins as an additive extracted from oyster shell, the zeta potentials were measured. These studies were performed to verify the primary role of intracrystalline proteins in controlling the formation, morphological development and crystallography of the biocomposite.

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Determination of Optimum Dosage of Polymer by Zeta potential in the Wastewater Treatment (수처리 시 Zeta전위 측정에 의한 응집제 주입량 결정)

  • Cho, Jun-Hyung;Kang, Mee-Ran
    • Journal of Forest and Environmental Science
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    • v.22 no.1
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    • pp.27-31
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    • 2006
  • Sedimentation characteristics such as SS, COD removal efficiency of wastewater in the toilet paper mill using recycled paper were examined by zeta potential. Optimum dosage of coagulant were determined by turbidity, SS, COD and then equation for treatment efficiency was suggested. Mechanical strength of floc was determined by turbidity.

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A Qualitative Analysis on the Surface States at the Undoped Polycrystalline Si and GaAs Semiconductor Interfaces Using the Zeta Potential (Zeta 전위에 의한 도핑되지 않은 다결정 Si 및 GaAs 반도체 계면의 표면준위에 관한 정성적 해석)

  • Chun, Jang-Ho
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.24 no.4
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    • pp.640-645
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    • 1987
  • Surface states and interfacial phenomena at the undoped polycrystalline semiconductor particale-electrolyte interfaces were qualitatively analyzed based on the zeta potentials which were measured with microelectrophoresis measurements. The suspensions were composed of the undoped polycrystaline silicon(Si) or gallium arsenide (GaAs) semiconductor particles stalline Si and GaAs particles in the KCl electrolytes was 3.73~6.2x10**-4 cm\ulcornerV.sec and -2.3~1.4x10**-4cm\ulcornerV.sec at the same conditions, respectively. The range of zeta potentials corresponding to the electrophoretic mobilities is 47.8~80.1mV and -30.1~17.9mV, respectively. The variation of the zeta potentials of the undoped polycrystalline Si was similar to the doped crystalline Si. On the other hand, two points of zeta potential reversal occurred at the undoped polycrystalline GaAs-KCl electrolyte interfaces. The surface states of the undoped polycrystalline Si and GaAs were dominated by positively charged donor surface states. These surface states are attributed to adsorbed ion surface states (slow states) at the semiconductor oxide layer-electrolyte interfaces.

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