• Title/Summary/Keyword: yellowish

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The $PbWO_{4}:Nb$ single crystal growth and its optical properties ($PbWO_{4}:Nb$ 단결정의 성장과 그 광학적 특성)

  • 장경동;김도형;양희선;이상걸;박효열;이진호;이동욱;이상윤
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.2
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    • pp.141-148
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    • 1999
  • High quality pure and Nb-doped $PbWO_{4}$ Single Crystal were grown from a 50 %~50 % mixture of Lead oxide (PbO) and Tungsten oxide $(WO_{3})$ by Czochralski method in Iridium crucible. The stoichiometric deviation correspond to the selective loss of the crystal constituents is found to be responsible for the yellowish coloration of $PbWO_{4}$. Through the X-ray powder diffraction experiment, we have investigated the lattice constant variations of each $PbWO_{4}$ crystals. We also present information on their photoluminescence (PL), optical absoption properties and Raman spectra. The temperature dependence of PL intensity and FWHM (Full Width Half Maximum) were measured in the temperature range 10 K~300 K. One observes a slight temperature dependence in the low temperature region and PL intensity decreases over 200 K by thermal quenching. The activation energy, Huang-Rhys coupling constant and inhomogenious brodenning acquired from their temperature dependence.

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A newborn girl with harlequin ichthyosis genetically confirmed by ABCA12 analysis

  • Kim, Jihye;Ko, Jung Min;Shin, Seung Han;Kim, Ee-Kyung;Kim, Han-Suk
    • Journal of Genetic Medicine
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    • v.16 no.2
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    • pp.62-66
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    • 2019
  • Harlequin ichthyosis (HI, OMIM #242500) is one of the most severe skin diseases among the autosomal recessive congenital ichthyoses, with high morbidity and mortality, particularly in newborns. Clinically, it is characterized by a typical appearance of generalized, thick, yellowish, hyperkeratotic plates with deep erythematous fissures on the skin. Herein, we present the case of a newborn girl with HI that was genetically confirmed by targeted gene panel analysis. The premature baby was encased in an opaque white membrane with erosion covering the skin of the entire body except the lips, with her hands and feet restricted by the membrane. Humidification, emollient, and retinoic acid treatment were started; the thick ichthyosis gradually peeled off and the underlying skin was only covered with thin scales. Targeted gene panel analysis using next-generation sequencing and validation with Sanger sequencing and quantitative polymerase chain reaction analyses confirmed compound heterozygous mutations of the ABCA12 gene (p.N1380S and a partial gene deletion encompassing exon 9). The parents were carriers for each of the identified mutations. Early recognition of the genetic etiology of congenital ichthyosis can, thus, facilitate genetic counseling for patients and their families.

Characteristics of the 3rd day of 5th instar silkworm powder: effect of preparation method

  • Jo, You-Young;Kim, SooHyun;Lee, Ji Hae;Kweon, HaeYong;Ju, Wan-Teak;Kim, Hyun-Bok;Kim, Kee-Young;Kim, Seong-Wan;Kim, Su-Bae
    • International Journal of Industrial Entomology and Biomaterials
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    • v.40 no.1
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    • pp.22-27
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    • 2020
  • Silkworm powder was prepared from 3rd day of 5th instar silkworm through various drying technology including freeze drying, hot wind drying, infrared drying, and microwave drying. The shape of silkworm dried was different with the drying methods. Freeze drying and microwave drying silkworm looked its original form, but hot wind drying and infrared drying silkworm looked shriveled and crumpled. The color of silkworm powder freeze-dried changed from yellowish green to hazel with lowering freezing temperature. Heavy metals including Pb, Cd, As, and Hg were lower the food criteria. The results of 1-deoxynojirimycin analysis was shown that BaekOkJam and GoldenSilk silkworm powder was satisfied the criteria of functional food, but YeonNokJam silkworm powder was lower than the criteria. The amino acid composition of silkworm was similar regardless of the frozen temperature in freeze drying process.

The Development of Enzymatic Mordanting Using Laccase for Phenolic Natural Dye (라카아제 촉매 활성에 의한 홍차 염색물의 매염효과)

  • Lee, Hye Bin;Song, Ji Eun;Shim, Eui Jin;Kim, Hye Rim
    • Fashion & Textile Research Journal
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    • v.20 no.3
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    • pp.323-330
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    • 2018
  • This study aim is to provide new coloration method by laccase-catalyzation on natural phenolic dyeing process. In this study, silk was dyed with black tea, which is one of polyphenolic dye, extracted in distilled water. The dyed samples were catalyzed by laccase as the eco-friendly mordanting process. To optimize the conditions of laccase-catalyzed coloration, conditions were varied by different mordanting methods (one-bath, two-bath), temperature and treatment time. The dye affinity in terms of the value of K/S, $L^*$, $a^*$, $b^*$, and H, V, C was measured by Computer Color Matching System (CCM, CM-2600d, Spectra Magic NX, Korea). The effect of laccase-catalyzed coloration on washing fastness was evaluated and compared with the synthetic mordant (Al, Cu, and Fe). As the result of color analysis of dyed silk, the optimum conditions of laccase-catalyzed coloration were determined to post-mordanting by one-bath at $50^{\circ}C$ for 3 hours. Under the optimum laccase-catalyzed conditions, the dyed silk was shown the color of yellowish-red. After laccase-catalyzed coloration on the dyed silk, the improvement of washing fastness was obtained compared with mordanted silk by synthetic mordant (Al, Cu, and Fe). Therefore, the present study was demonstrated that the effective enzymatic mordanting method by laccase for phenolic natural dyeing with vivid color and good fastness.

A Study on the Role of -SO3- Ions in the Dehydration Limit of Poly(styrene-co-styrenesulfonic acid) Membrane

  • Ko, Kwang-Hwan;Kim, Joon-Seop;Lee, Chang Hoon
    • Elastomers and Composites
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    • v.52 no.3
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    • pp.180-186
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    • 2017
  • In this work, the effect of low-temperature dehydration of a poly(styrene-co-styrenesulfonic acid) (PSSA) membrane was investigated by differential scanning calorimetry, fourier transform infrared spectroscopy (FT-IR), electron magnetic resonancespectroscopy (EMR), and $^1H$- and $^{13}C$ solid-state nuclear magnetic resonance spectroscopy. These analyses were performed at room temperature for powdered PSSA specimens with and without dehydration and the following key observations were made. First, FT-IR analysis showed that low-temperature dehydration not only transformed the [${SO_3}^-{\cdots}H^+$] ionic pair in the non-hydrated PSSA to an $SO_3H$ group, but also induced the formation of -C=C- double bonds in the dehydrated PSSA. Second, the ${-SO_3}^{\bullet}$ radical was unambiguously identified by EMR spectroscopy. Third, H-abstraction was detected by $^1H$ magic-angle spinning spectroscopy. Finally, an unexpected color shift from white for the non-hydrated PSSA to a yellowish brown for the dehydrated sample was observed. In order to explain these experimental results, it was proposed that the formation of the intermediate hydrogen ($H^{\bullet}$) or hydroxyl radical ($HO^{\bullet}$) species was initiated by the dehydration process. The sespecies attacked the $SO_3H$ group and the tertiary proton at the ${\alpha}-carbon$, resulting in the formation of $-SO^{\bullet}$ radicals and -C=C- double bonds, which correlated with the color shift in the dehydrated PSSA sample. The semechanisms are useful for understanding the simultaneous loss of an aromatic ring and -SO- groups in the PSSA fuel cell membrane.

Modern Fashion Design Development by using Motifs and Colors of Flower and Bird Pictures in Folk Painting (민화의 화조화에 나타난 모티브와 색채를 활용한 현대 패션디자인 개발)

  • Yum, Misun
    • Journal of the Korea Fashion and Costume Design Association
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    • v.18 no.2
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    • pp.115-125
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    • 2016
  • This study analyzes the characteristics of the motifs and colors in flower and bird paintings which contain and present Korea's unique aesthetics based on its richest data among all other types of Korean folk paintings. With a theoretical exploration of folk paintings and an analysis of the motifs and colors, textile design with an aim to present highly valued korean modern fashion design was developed. Two hundred and seventy flower and bird paintings were selected from relevant materials, resulting in an extraction of 5,068 colors. A palette of representative colors was made based on densely distributed hues and tones. The research can be summarized as follows: Flower and bird paintings contain flowers, birds, trees and animals and the motifs in the paintings stand for spirituality, philosophies from different times and other symbols of our nation. Each of the motifs in these paintings is a prayer for good luck, especially conjugal harmony and fecundity to bring about happiness and richness. Colors in flower and bird paintings are characteristic of the order: YR(25.5%)>R(19.2%)>Y(10.6%)>PB(9.2%)>G(7.9%), with low-chromatic YR and highly bright R taking up a larger percent. The order of tones is: d(13.5%)>dk (10.5%)>s(10.4%)>dkg(10.0%)>sf(9.1%)and the tone is dark in general. YR, taking up the largest percent, was dull, light, and soft. As for the achromatic colors, the order is: W(5.2%)>Gy(1.9%)>Bk(0.7%). Based on the above analyzed color data, those colors which were high in their hue and tone were extracted to present representative colors. In this way, representative colors like yellow, yellowish red, red, green, and purplish blue were extracted. This was the basis to present motifs and colors originating from subjects of folk paintings in various patterns using Illustrator CS6, to create modern fashion design.

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The Physicochemical Characteristics and Antioxidant Properties of Commercial Nurungji Products in Korea (국내 시판 누룽지의 물리화학적 특성 및 항산화 성질 연구)

  • Yang, Ji-won;Choi, Il Sook
    • Korean journal of food and cookery science
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    • v.32 no.5
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    • pp.575-584
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    • 2016
  • Purpose: Nurungji is a traditional Korean food made by yellowish scorched rice. After getting gelatinization of rice, a thin crust of scorched rice will usually be left in the bottom of the traditional cooking pot. In this study, physicochemical characteristics and antioxidant properties of five commercial nurungji products (CNP1, CNP2, CNP3, CNP4, and CNP5) were evaluated. Methods: Physicochemical properties of the five commercial nurungji products were evaluated with AOAC method. The antioxidant activities were assessed using the 1,1-diphenyl-2-picryl hydrazyl (DPPH), 2,2-azinobis-(3-ethyl-benozothia zoline-6-sulfonic acid)(ABTS), ferric reducing antioxidant power (FRAP), and reducing power assays. Results: Water content was the highest in CNP3, followed by CNP1, CNP2, CNP5, and CNP4. Crude ash content of all nurungji was less than 1%. In Hunter color parameter, the significantly highest a value (redness) and b value (yellowness) were measured in the CNP4 product, meanwhile the lowest in CNP3 (p<0.05). The nurungji products of CNP4 and CNP5 had the significantly higher content in total polyphenols and total flavonoids, compared to those of other products. CNP3 and CNP2 had the lowest in total polyphenols and total flavonoids, respectively. CNP4 and CNP5 products showed the significantly higher values in antioxidant activities, whereas CNP3 had the lowest activity. Conclusion: The high value of antioxidant activities in CNP4 and CNP5 might have been affected primarily by the total polyphenols with increasing browning color during the heat treatment.

Asian Plum Diversity Based on Phenotypic Traits in Republic of Korea

  • Kwon, Jung-Hyun;Nam, Eun-Young;Jun, Ji-Hae;Chung, Kyeong-Ho;Yun, Seok-Kyu;Kim, Sung-Jong;Do, Yun-Soo
    • Korean Journal of Plant Resources
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    • v.31 no.3
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    • pp.254-267
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    • 2018
  • The phenotypic traits of 63 Asian plum varieties were investigated for three years to select those with superior qualities for breeding. Eight morphological characteristics of the flowers and fruits (e.g., stigma position, fruit skin, and flesh color) were evaluated. Phenological characteristics (e.g., blooming time and ripening time) were also monitored. Being useful traits for breeding, fruit quality factors (e.g., fruit weight, skin color, flesh color, soluble solids content, and titratable acidity) were evaluated as well. The majority of the fruits were cordate (36%) and circular (23%) in shape. Approximately 78% of the varieties showed a red skin color, whereas 67% had yellowish fruit flesh. Fruit ripening occurred from June 28th to September 5th, spanning 69 days. The average fruit weight and soluble solids content were 77.2 g and $12.2^{\circ}Brix$, respectively. Regarding correlations among the characteristics, the most significant correlation coefficients were for the ripening time and fruit size parameters. Such information of Asian plum varieties will be useful for future breeding programs.

Antibiosis against Super Bacteria from Natural Dyeing with Elm Bark Extract (느릅나무껍질 추출액을 이용한 천연염색의 슈퍼박테리아에 대한 항균성)

  • Choi, Na Young;Park, Hee-Su
    • Fashion & Textile Research Journal
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    • v.17 no.5
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    • pp.838-843
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    • 2015
  • In this study, a cotton knit was dyed with elm bark extract; subsequently, the dyed fabric was measured according to the types of mordants and the preprocessing cationizers used. Additionally, antibiosis against super bacteria was examined. The results follow. First, the color of the dyed cotton knit appeared reddish and yellowish for fabrics treated with non-mordants and mordants. When preprocessing with a cationizer was conducted, the dyeing properties were the best. Second. even when mordants were not used for dyeing, color fastness after washing, sweating, and rubbing was generally good Grade 4 and 5. Color fastness after exposure to sunlight was the best Grade 4 for fabric prepared with ferrous sulfate as the mordant. Third. as for antimicrobial properties, or resistance to super bacteria, the growth of bacteria was suppressed in a meaningful way for fabrics treated with non-mordants and mordants, compared to the control group fabric. The dyeing methods with the most powerful antimicrobial effects were dyeing after preprocessing with a cationizer and preparing fabric with copper sulfate as the mordant. The results stated above show that in case of dyeing with elm bark extract, preprocessing of the cotton knit with a cationizer and dying with copper mordant displayed high levels of antimicrobial properties that were useful for resisting super bacteria. Of these the dyeing properties were the best when preprocessing with a cationizer.

Comparisons of Physical and Chemical Methods for Dealing with Biologically Pre-Treated Livestock Wastewater as a Post-Treatment (축산폐수 생물학적 처리수의 후처리를 위한 물리·화학적 단위 공정 비교)

  • Choi, Yong-Su;Hong, Seok-Won;Kwon, Gi-han;Jung, Il-Ho
    • Journal of Korean Society on Water Environment
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    • v.20 no.2
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    • pp.110-119
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    • 2004
  • The combination of biological and physical/chemical technologies is a promising technique to reduce highly concentrated pollutants in livestock wastewater. It is suggested to treat livestock wastewater efficiently as follows: firstly, biodegradable organic matters, nitrogen and some of phosphorus should be removed by a biological treatment process and then residual non-biodegradable organic matters, color and phosphorus be eliminated by physicochemical technologies. In this study, therefore, the integrations of chemical coagulation, activated carbon adsorption, Fenton oxidation and ozonation were evaluated to provide appropriate post-treatment processes for biologically pre-treated livestock wastewater. After chemical coagulation followed by ozonation or Fenton oxidation process, the quality of treated wastewater could meet the discharge limit in Korea. However, a yellowish brown color still remained in the treated wastewater after a single method such as coagulation and Fenton oxidation was applied. The ozonation was found to be the most effective technology for the decolorization. Neither simple biological nor physicochemical treatment provides adequate decolorization and sufficient depletion of organics in livestock wastewater so far. Consequently, the integration of Fenton oxidation and ozonation with a biological treatment process is recommended to treat livestock wastewater in terms of removal efficiency.