• Tribology and Lubricants
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• 제19권1호
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• pp.1-8
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• 2003

Recently, PM-high speed steel(PM-HSS) has reportedly been a good alternative material for rolling mill because of its superior performance to conventional HSS. This paper has been aimed to investigate the possibility for application to rolling contact element for PM-HSS by X-ray diffraction technique. The X-ray elastic constant for PH-HSS has been found by X-ray diffraction during the four-point bending test. Residual stress and half-value breadth on the contact surface during rolling contact fatigue process by X-ray diffraction have also been measured. The result of this study shows that the application of X-ray diffraction technique to PM-HSS could be as possible alternative material as conventional HSS. Half-value breadth on rolling contact surface by X-ray diffraction is not changed during rolling contact fatigue process. On the other hand, the residual stress is changed. This suggests that dislocation reaction has been hardly occurred in rolling contact, depending on super-saturated carbon in PM-HSS.

• 한국해양공학회지
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• 제8권2호
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• pp.105-114
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• 1994

초경합금은 기계적 성질이 다른 WC의 분상상과 Co의 결합상으로 구성되어 있다. 만일 이합금이 거시적으로 균일하게 변형을 하면, 각 상들은 이들의 응력상태에 따라 다르게 변형될 것이다. 따라서 WC-Co 합금의 변형특성과 강화기구를 명확히 알기 위해서는 각상의 미시적 변형과 파괴기구를 검토할 필요가 있다. 본 연구에서는 시편에 굽힘하중을 가하여, X선 회절로 분산상인 WC상 및 결합상인 Co상의 X선적 탄성정수와 응력정수를 측정하였다. WC-Co합금중의 WC상과 Co상의 상응력은 WC(112)면과 CO(311)면의 회절로서 결정하였다. 그리고 이 상응력들을 복합법칙의 적용가능성에 대하여 검토하였다.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2000년도 제32회 추계학술대회 정기총회
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• pp.44-49
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• 2000

Recently, PM-high speed steel(PM-HSS) has reportedly been a good alternative material for rolling mill because of its superior peformance to conventional HSS. This paper has been aimed to investigate the possibility for application to rolling contact element for PM-HSS by X-ray diffraction technique. The X-ray elastic constant for PM-HSS has been found by X-ray diffraction during the four-point bending test. Residual stress and half-value breadth on the contact surface during rolling contact fatigue process by X-ray diffraction have also been measured. The result of this study shows that the application of X-ray diffraction technique to PM-HSS could be as possible alternative material as conventional HSS. Half-value breadth on rolling contact surface by X-ray diffraction is not changed during rolling contact fatigue process. On the other hand, the residual stress is changed. This suggests that dislocation reaction has been hardly occurred in rolling contact, depending on supersaturated carbon in PM-HSS.

• 한국재료학회지
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• 제4권7호
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• pp.792-797
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• 1994

6-31G $\ast$ $\ast$ basis set을 이용한 ab initio 양자역학적 방법에 의하여 2,4,6- trifluoroheptane구조를 구함으로서 syndiotactic isoregic PVF결정의 force field를 유도하였다. 또 그 결과를 PVF의 structure parameter및 elastic constant를 계산하는데 응용하였다. 그 결과 cell parameter는 각각 a(5.205$\AA$: chain axis), b(8.457 $\AA$) 및 c(4.621 $\AA$)로 나타났으며 X-ray data(5.04$\AA$, 8.57$\AA$, 및 4.95$\AA$)결과와 비교적 잘 일치함을 알 수 있었다. Defect 비존재하에서의 syndiotactic PVF결정의 Young's 모듈러스 계산값은 267Gpa로 나타났으며, polyvinylideme fluoride(277-293 GPa)및 polyethylene(264-337 GPa)결정의 경우와 비슷한 수준으로 나타났다. 또한 optimum geometry에서 얻어진 bulk modulus값은 experimental geometry 에서 얻어진 값보다 두배의 차이를 보였으며, 이것은 geometry 에 따른 elastic compliance constant(특히 $S_{33}$인자)가 크게 달라지기 때문인 것으로 나타났다.

• 한국재료학회지
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• 제11권7호
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• pp.545-549
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• 2001

고온 안정성의 유리계로 알려진 회토류 알루미나 규산염계중, Nd$_2$O$_3$-Al$_2$O$_3$-SiO$_2$(NdAS)계 유리의 응용범위를 찾고자 결정화유리를 제조하여 그 물성의 특성을 평가하였다. NdAS에 결정화제로 TiO$_2$를 첨가하여 내부결정화를 유도하여 생성된 결정화유리에 대하여 결정상과 잔류유리의 물리적, 열적, 기계적 물성을 측정하였다. NdAS-TiO$_2$유리계는 열처리와 조성 조건에 따라 생성된 표면 및 내부결정상은 같은 결정상을 갖는 것으로 X선회절의 결과로 확인되었으나, 알려 있지 않은 결정상으로 내부결정의 경우, 원자구성비는 $Nd_{4.6}Si_{7.2}Al_{4.0}Ti_{2.4}O_{32}$이었다. 결정화유리의 선팽창계수는 $5.4~6.2{\times}10^{-6}/^{\circ}C$ 정도로 경정성장이 일어날수록 증가되었다. 결정화유리중의 결정상의 경도와 탄성계수는각 각 12GPa, 220Gpa으로 나타난 것을 고려한다면 내부결정화에 의한 결정화유리의 물성은 고온 구조용 재료로 활용도가 넓을 것으로 본다.

• 한국의류산업학회지
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• 제15권6호
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• pp.985-992
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• 2013

Polytrimethylene terephthalate(PTT) offers several advantageous properties such as good tensile strength, uniformity, stiffness, toughness, UV stability, resilience, stain resistance, outstanding elastic recovery, and dyeability. The effects of annealing temperature on physical properties and the structure of PTT filaments and yarn were investigated by measuring wide-angle X-ray diffraction (WAXD), density, optical birefringence, dynamic visco elasticity, and tensile testing. The intensity of maximum tan ${\delta}$ decreased and the temperature of maximum tan ${\delta}$ shifted to a higher temperature as the annealing temperature of filaments increased; however, it shifted to a lower temperature when the annealing temperature exceeded $130^{\circ}C$. In addition, crystallinity, density and D-spacing of (010) crystal face increased as the annealing temperature increased. Optical birefringence and specific stress were almost constant up to $100^{\circ}C$ and then decreased above $130^{\circ}C$. The shrinkage of PTT filament is 0 in boiling water when annealed above $130^{\circ}C$; consequently, the use of annealed fiber above $130^{\circ}C$ can remove thermal instability when dyeing PTT fiber. In the case of yarns, the thermal stability and physical properties of yarns showed the best effect when the ply number is less than 5, twist number is less than 400tpm, and the annealing time is 20minutes.