Browse > Article
http://dx.doi.org/10.5805/SFTI.2013.15.6.985

The Effects of Annealing Temperature on The Physical Properties and Fine Structure of Poly(trimethylene terephthalate)(PTT) Fibers  

Jeong, Kyung Hui (Dept. of Biomaterial Science, Pusan National University)
Lee, Eon Pil (Dept. of Biomaterial Science, Pusan National University)
Lee, Jae Ho (Dept. of Biomaterial Science, Pusan National University)
Publication Information
Fashion & Textile Research Journal / v.15, no.6, 2013 , pp. 985-992 More about this Journal
Abstract
Polytrimethylene terephthalate(PTT) offers several advantageous properties such as good tensile strength, uniformity, stiffness, toughness, UV stability, resilience, stain resistance, outstanding elastic recovery, and dyeability. The effects of annealing temperature on physical properties and the structure of PTT filaments and yarn were investigated by measuring wide-angle X-ray diffraction (WAXD), density, optical birefringence, dynamic visco elasticity, and tensile testing. The intensity of maximum tan ${\delta}$ decreased and the temperature of maximum tan ${\delta}$ shifted to a higher temperature as the annealing temperature of filaments increased; however, it shifted to a lower temperature when the annealing temperature exceeded $130^{\circ}C$. In addition, crystallinity, density and D-spacing of (010) crystal face increased as the annealing temperature increased. Optical birefringence and specific stress were almost constant up to $100^{\circ}C$ and then decreased above $130^{\circ}C$. The shrinkage of PTT filament is 0 in boiling water when annealed above $130^{\circ}C$; consequently, the use of annealed fiber above $130^{\circ}C$ can remove thermal instability when dyeing PTT fiber. In the case of yarns, the thermal stability and physical properties of yarns showed the best effect when the ply number is less than 5, twist number is less than 400tpm, and the annealing time is 20minutes.
Keywords
PTT; annealing; tan ${\delta}$; birefringence; crystallinity;
Citations & Related Records
Times Cited By KSCI : 8  (Citation Analysis)
연도 인용수 순위
1 Bae, J. H., Kim, Y. H., & Kim, K. J. (1999). Intrinsic Birefringence of Poly(trimethylene Terphthalate). Proceedings of the Asian textile Conference, Kyoto, Japan, pp. 973-976.
2 Brown, H. S., & Chuah, H. H. (1997). Texturing of textile filament yarns based on polytrimethylene terephthalate. Chemical Fibers International, 47(1), 72-74.
3 Choi, H. (2003). Preparation and physical properties of Stretch fabrics using with poly(trimethylene terephthalate) fiber. Journal of the Korean Society for Clothing Industry, 5(1), 53-58.   과학기술학회마을
4 Choi, J. W., & Jang, B. S. (2006). A study on the tensile properties for poly(trimethylene terephthalate, PTT) 1${\times}$1 rib knitted fabrics. Journal of Korean Society Industrial Application, 9(4), 337-341.
5 Chuah, H. H. (1996). Corterra poly(trimethylene terephthalate)-new polymeric fiber for carpets. Chemical Fibers International, 46(6), 424-428.
6 Chung, H. G., Park, S. W., Kang, B. C., Song, M. H., Roh Y. H., & Yoon, H. S. (2005). Comparison of mechanical properties of warp knitted fabrics using PET and PTT yarn. Textile Science and Engineering, 42(5), 302-309.   과학기술학회마을
7 Dandurand, S. P., Perez, S., Revol, J. F., & Brisse, F. (1979). The crystal structure of poly(trimethylene terephthalate) by X-ray and electron diffraction. Polymer, 20(4), 419-426.   DOI   ScienceOn
8 Hong, S. H., Kim, R., Choi, C. N., Choi, H., Lee, W. E., & Cho, S. Y. (2003). Morphological structure of poly(trimethylene terephthalate) fibers annealed by passing on the plate heater. Polymer(Korea), 27(2), 106-112.   과학기술학회마을
9 Ji, B. C., Yoon, W. S., & Kim, S. Y. (1993). Structure and properties of zone-drawn PET film(I). Journal of the Korean Fiber Society, 30(4), 328-334.   과학기술학회마을
10 Kim, H. K., Kim, H. R., & Lee, J. J. (2008). Environmentally friendly dyeing of PTT with temporarily solubilized azo disperse dyes. Textile Science and Engineering, 45(4), 220-224.   과학기술학회마을
11 Kim, I. R. (2006). Change in physical properties of PTT and PET filament yarns due to heat treatment. Journal of the Korean Fiber Society, 43(4), 196-200.   과학기술학회마을
12 Kim. J. H., & Cho, H. H. (2005). Fine structure and physical properties of poly(ethylene 2,6-naphthalalene dicarboxylate) fibers with different thermal history. Journal of the Korean Fiber Society, 42(1), 21-28.   과학기술학회마을
13 Kim, N. H., Son, T. W., Jeong, M. G., Kim, Y. H., & Kim, D. S. (2003). Time dependent properties of partially oriented poly(trimethylene terephthalate)(PTT) fibers. Journal of the Korean Fiber Society, 40(3), 213-223.   과학기술학회마을
14 Kim, Y. H., Kim, K. J., & Lee, K. M. (1997). Melting and nonisothermal crystallization behaviors of poly(trimethylene terephthalate). Journal of the Korean Fiber Society, 34(12), 860-867.
15 Lee, D. H., Jeong, D. S., Kim, H. J., & Lee, M. C. (2003). Dying of PTT fiber(2) -Effect of solvent treatment on the dyeing and physical properties of PTT fiber. Journal of the Korean Society of Dyers and Finishers, 15(4), 208-216.
16 Oh, P. R., Kim, K. J., & Kim, Y. H. (1999). Dynamic mechanical analysis of drawn and annealed poly(trimethylene terephthalate) fiber. Journal of the Korean Fiber Society, 36(2), 132-139.   과학기술학회마을
17 Lee, D. H., Jeong, D. S., & Lee, M. C. (2002). Dying of PTT fiber(1)-Effect of heat setting on the dyeing and physical properties of PTT fiber. Journal of the Korean Society of Dyers and Finishers, 14(9), 268-276.
18 Lee, K. M., Lee, Kim, K. J., & Kim, Y. H. (1999). Isothermal crystallization behavior and some physical parameters of poly(trimethylene terephthalate). Polymer(Korea), 23(1), 56-65.
19 Nakamae, K., Nishino, T., Hatra, K., Yokoyama, F., & Matsumoto, T. (1986). Elastic moduli of crystalline region of poly(trimethylene terephthalate). Zairyo, 35(396), 1066-1070.
20 Pyda, M., Boller, A., Grebowicz, J., Chuah, H., Lebedev, B. V., & Wunderlich, B. (1998). Heat capacity of poly(trimethylene terephthalate). Journal of Polymer Science Part B: Polymer Physics, 36(14), 2499-2511.   DOI   ScienceOn
21 Seo, H. J., Kim, J. J., & Jeon, D. W. (2003). A study on the physical properties and subjective evaluation of the PTT(poly (trimethylene terephthalate)) fabric. Journal of Fashion Business, 7(4), 121-128.   과학기술학회마을
22 Sung, W. K. (2010). A study on the dyeing of PTT(polytrimethylene terephthalate)/ mixture fabrics with disperse dyes/acid dyes. Journal of the Korean Society for Clothing Industry, 12(1), 94-102.   과학기술학회마을   DOI   ScienceOn