• Title/Summary/Keyword: working gas

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Fabrication of CO2 Gas Sensors Using Graphene Decorated Au Nanoparticles and Their Characteristics (Au 나노입자가 코팅된 그래핀 기반 CO2 가스센서의 제작과 그 특성)

  • Bae, Sang-Jin;Kim, Kang-San;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.22 no.3
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    • pp.197-201
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    • 2013
  • This paper describes the fabrication and characterization of graphene based carbon dioxide ($CO_2$) gas sensors. Graphene was synthesized by thermal decomposition of SiC. The resistivity $CO_2$ gas sensors were fabricated by pure graphene and graphene decorated Au nanoparticles (NPs). The Au NPs with size of 10 nm were decorated on graphene. Au electrode deposited on the graphene showed Ohmic contact and the sensors resistance changed following to various $CO_2$ concentrations. Resulting in resistance sensor using pure graphene can detect minimum of 100 ppm $CO_2$ concentration at $50^{\circ}C$, whereas Au/graphene can detect minimum 2 ppm $CO_2$ concentration at same at $50^{\circ}C$. Moreover, Au NPs catalyst improved the sensitivity of the graphene based $CO_2$ sensors. The responses of pure graphene and Au/graphene are 0.04% and 0.24%, respectively, at $50^{\circ}C$ with 500 ppm $CO_2$ concentration. The optimum working temperature of $CO_2$ sensors is at $75^{\circ}C$.

Measurement of the Ar Recovery Time of a Cryopump and Analysis on the Ar Instability (크라이오펌프 알곤 회복시간 측정과 알곤 불안정성 분석)

  • In, Sang Ryul;Lee, Dong Ju
    • Journal of the Korean Vacuum Society
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    • v.22 no.5
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    • pp.225-230
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    • 2013
  • Cryopump removes gas molecules by condensation and adsorption. Therefore, cryo-surface temperature and corresponding vapor pressure influence directly the pumping performance. If the surface temperature of any part is neither low nor high, there occurs the desorption of gas molecules condensed or adsorbed, and the emitted molecules can be captured again, which leads to a time-consuming and fluctuating change of the pressure. Though every gas can show such a pressure instability at a specified temperature range, the instability generated in a sputter system using Ar as a working gas and operating with a cryopump is especially undesirable. In this paper the cause of the argon instability is analyzed and corrective is provided through the measurement of the Ar recovery time.

A Study on the Characteristics of Local Corrosion for Gas Absorption Refrigeration and Hot Water Systems in LiBr-$H_2O$ Working Fluids (LiBr작동유체 중에서 가스흡수식 냉온수기의 국부부식 특성에 관한 연구)

  • Uh- Joh Lim;Ki-Cheol Jeong;Byoung-Du Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.6
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    • pp.714-720
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    • 2003
  • Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

An Experimental Study about the Running of a Gas Turbine by using Hydrogen and Oxygen (수소와 산소를 이용한 가스터빈의 구동에 관한 실험 연구)

  • Kang, J.S.;Oh, B.S.
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.1
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    • pp.5-10
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    • 1997
  • Because of environmental pollution and reserve limitations of fossil fuels, several alternative energies have been developing. One of them, the hydrogen is researched as a highly probable solution. In this study pure hydrogen gas and oxygen gas are burned in combustor to reduce the emission, and a gas turbine is used. Cooling water around the combustor recovers the cooling heat loss to useful work by being expanded from liquid to vapor, being injected into the combustor and making pressure rise with working fluid to get more turbine power. Because pure hydrogen and oxygen are used, there is no carbonic emission such as CO, $CO_2$, HC nor $NO_x$, and $SO_x$. The power is obtained by turbine system, which makes lower noise and vibration than any reciprocating engine. Running of a turbine is searched under various conditions of hydrogen flow rate and water injection rate. Maximum speed of the turbine is obtained when the combustion reaches steady state. It is enable to determine the optimum rate between hydrogen flow and water injection which makes turbine run maximum speed.

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Reactive ion etching characterization of SiC film deposited by thermal CVD method for MEMS application (MEMS 적용을 위한 thermal CVD 방법에 의해 증착한 SiC막의 etching 특성 평가)

  • Choi, Gi-Yong;Choi, Duck-Kyun;Park, Ji-Yeon;Kim, Tae-Song
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.868-871
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    • 2003
  • In recent years, silicon carbide has emerged as an important material for MEMS application. In order to fabricate an SiC film based MEMS structure by using chemical etching method, high operating temperature is required due to high chemical stability. Therefore, dry etching using plasma is the best solution. SiC film was deposited by thermal CVD at the temperature of $1000^{\circ}C$ and pressure of 10 torr. SiC was dry etched with a reactive ion etching (RIE) system, using $SF_6/O_2$ and $CF_4/O_2$ gas mixture. Etch rate have been investigated as a function of oxygen concentration in the gas mixture, RF power, and working pressure. Etch rate was measured by surface profiler and FE-SEM. $SF_6/O_2$ gas mixture has been shown high etch rate than $CF_4/O_2$ gas mixture. Maximum etch rate appeared at 450W of RF power. $O_2$ dilute mixtures resulted in an increasing of etch rate up to 40%, and the superior anisotropic cross section was observed.

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The analysis on TMA gas-sensing characteristics of ZnO thin film sensors (ZnO 막막 센서의 TMA 가스 검지 특성 분석)

  • 류지열;박성현;최혁환;김진섭;이명교;권태하
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.12
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    • pp.46-53
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    • 1997
  • The TMA gas sensors are fabricated with the ZnO-based thin films grown by a RF magnetron sputtering method. The hall effect measurement and AES analysis are carried out to investigate the effects of the sputtering gases and dopants which effect on the electrical resistivity and sensitivity to TMA gas. We measure the cfhanges of the surface carrier concentration, haall electron mobility, electrical resistivity, surface condition, and depth profile of the films. The ZnO-based thin film sensors sputtered in oxygen, or added with dopants showed a high sruface carrier concentration, film sensors sputtered in oxygen and doped with 4.0 wt.% $Al_{2}$O$_{3}$, 1.0 wt.% TiO$_{2}$, and 0.2 wt% v$_{2}$O$_{5}$ showed the highest surface carrier concentration of 5.952 * 10$^{20}$ cm$^{-3}$ , hall electron mobility of 176.7 cm$^{2}$/V.s, lowest electrical resistivity of 6*10$^{-5}$ .ohm.cm and highest sensitivity of 12. These results were measured at a working temperature of 300.deg. C to 8 ppm TMA gas.

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Gas cooling heat transfer coefficient for $CO_2$-PEC9 mixture under supercritical condition (초임계조건에서 $CO_2$-PEC9 혼합물의 물성예측을 통한 냉각 열전달특성 연구)

  • Yun, Rin
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.821-826
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    • 2009
  • Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems. Oils are always required in a vapor-compression cycle, and thus actual working fluid in the system is $CO_2$-oil mixtures even though the oil concentrations are low at the heat exchangers and the expansion device. The cooling heat transfer coefficients for $CO_2$-oil mixtures under supercritical condition are required to designing of the gas cooler in the $CO_2$ refrigeration system properly. In the present study, the gas cooling heat transfer coefficients for $CO_2$-PEC9 was estimated by using the Gnileinski correlation, and the Kim and Ghajar model through the previous prediction models for the thermo-physical properties of $CO_2$-oil mixture. The Gnileinski correlation was used when the oil wt.% in the mixture is less than 1.0, and for the higher oil concentration the Kim and Ghajar model was applied. The estimated results agree with the experimental results conducted by the Dang et al.

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An Experimental Study on the affect of Non-condensable Gas Quantity on the Heat Transfer Performances in a Variable Conductance Heat Pipe (VCHP에서 불응축 가스량이 열전달 성능에 미치는 영향에 관한 실험적 연구)

  • Park, K.H.;Lee, K.W.;Lee, W.H.;Lee, K.J.;Suh, J.S.
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.19-24
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    • 2003
  • This paper is to research the heat transfer characteristic in copper-water variable conductance heat pipes(VCHP) with a non-condensable gas and gas reservoir. The heat transfer characteristics in the VCHP have not yet been studied much researches. VCHP are used in many applications. These applications range from thermal control of components and systems on satellites, to precise temperature calibration duties, conventional electronics temperature control and thermal diodes. The practical use of VCHP is a simple way to control the temperature of satellites. As the quantity of NCG was increased, there was an increase in the saturation vapor temperatures. As the input heat has loaded from 90 W to 110 W, the difference of the evaporator surface is lower than $10^{\circ}C$.

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OPTIMAL SPUTTERING CONDITIONS FOR HIGH-DENSITY MAGNETIC RECORDING MEDIA BY FTS

  • Noda, Kohki;Kawanabe, Takashi;Naoe, Masahiko
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.824-828
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    • 1996
  • Co-based alloy thin films ddeposited by fcing targets sputtering(FTS) were investigated for use in high-density magnetic recording media to determine how their magnetic properties are dependent on the sputtering conditions, and thus to find appropriate parameters that allow the sputtering and thin films to meet the specificiations for magnetic properties. FTS can discharge at lower working gas pressure than other sputtering methods such as dcmagnetron sputteing because the plasma is sufficiently confined by a magnetic field applied perpendicular to both of the target planes, which results in plasma-free substrates. Co-Cr-Ta films were deposited by FTS on glass and silicon substrates at substrate temperature between room temperature and $350^{\circ}C$, and at argon gas pressure between 0.1 and 10mTorr. The films were also deposited on polyimide tapes at substrate temperature of $130^{\circ}C$ and argon gas pressure of 1 mTorr. The effective advantages of Ta as an additional element were investigated, using the same films on the tapes. As a result of the experiment, it was found that better magnetic properties were obtained in the ranges of higher temperature and lower argon gas pressure with background pressure in thr range of $1.5 \times 10^{-6}$ Torr. Ta addition at 2 to 4 atomic percent almost havled the Co-Cr grain sizes, indicating that Ta addition at an appropriate atomic percent is effective for improving the microstructure and characteristics of Co-Cr films.

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Simulation of Energy Conversion Characteristics of OMACON LM-MHD Systems (OMACON형 LM-MHD 시스템에서의 에너지전환특성 시뮬레이션)

  • 김창녕
    • Journal of the Korea Society for Simulation
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    • v.6 no.2
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    • pp.1-14
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    • 1997
  • The characteristics of the flow and energy conversion in OMACON liquid-metal MHD system are investigated. Numerical simulation of two-phase flow in the OMACON system without magnetic field was carried out by the Phoenics code and the energy conversion characteristics are studied in association with the fact that the mechanical energy loss at the nozzle of the OMACON system are to be converted into electrical energy. In this system, working fluid (gas) is injected through the mixer located at the bottom of the riser, and is mixed with hot liquid metal. Therefore in the riser two-phase flow is developed under the influence of the gravity. In this study, the interaction between the gas and liquid is considered by the use of IPSA(InterPhase Slip Algorithm) where standard drag coefficient has been used. It has been assumed that in the flow regime the liquid is continuous and the gas is dispersed. For the liquid and gas, the continuity equations, momentum equations and energy equations are solved respectively in association with void fraction in the flow field. In order to calculate the energy conversion efficiency, firstly the ratio of the mechanical energy loss of liquid metal flow at the nozzle to the input thermal energy is considered. Secondly flow pattern of liquid metal in the generator has been analyzed, and the characteristics of the conversion of the mechanical energy into the electrical energy has been investigated. For an representative case where Hartmann number is 540 and magnetic field is 0.35 T, the present analysis shows that the energy conversion efficiency is 0.653. This result is considered to be reasonable in comparison with published experimental results.

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