• Title/Summary/Keyword: white emission

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Ce3+ sensitize RE3+ (RE=Dy, Tb, Eu, Sm) doped LaPO4 nanophosphor with white emission tunability

  • Phaomei, G.;Yaiphaba, N.
    • Advances in nano research
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    • v.3 no.2
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    • pp.55-66
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    • 2015
  • Crystalline $Ce^{3+}$ co-doped $LaPO_4$:RE ($RE=Dy^{3+}$, $Tb^{3+}$, $Eu^{3+}$, $Sm^{3+}$) and mix doped rare earth ions of $Dy^{3+}$, $Tb^{3+}$ and $Eu^{3+}$ were prepared by the polyol method at $150^{\circ}C$. Strongly enhance luminescence intensity is obtained with the co-doping of $Ce^{3+}$ with $LaPO_4$:$Dy^{3+}$ and $LaPO_4$:$Tb^{3+}$ due to charge transfer (CT) occurring from $Ce^{3+}$ to $Dy^{3+}$ and $Ce^{3+}$ to $Tb^{3+}$, where as there is no significant changes in luminescence intensity of $Ce^{3+}$ co-doped $Eu^{3+}$ and $Sm^{3+}$ doped $LaPO_4$ samples. The luminescence color can be tuned from green to white by varying the excitation wavelength for the mix ions $Ce^{3+}$, $Dy^{3+}$, $Tb^{3+}$ and $Eu^{3+}$ doped with $LaPO_4$.

Color Variation Improvement by Introducing Double Emission Layers in WPLEDs

  • Kwon, Soon-Kab;Lee, Yong-Kyun;Park, Tae-Jin;Jeong, Su-Hyeon;Jeon, Woo-Sik;Kwon, Jang-Hyuk;Jang, Jin
    • Journal of Information Display
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    • v.7 no.3
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    • pp.19-22
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    • 2006
  • White polymeric light-emitting devices (WPLEDs) have been fabricated from polyfluorene-based (PFO) blue and MEH-PPV polymer blending systems. A device structure of ITO / PEDOT:PSS / Blending polymer / Blue polymer / LiF / Al was employed. This structure of double emission layers showed significant improvement of white color shift phenomenon. A current efficiency of 4.67 cd/A (3,900 $cd/m^{2}$, 6.4 V) and a brightness value of 17,600 $cd/m^{2}$ at 9.4 V with (0.34, 0.35) CIE coordinates at 5 V and (0.29, 0.29) at 9 V were achieved achieved.

Renewable Energy Policy in the UK - with Focus on Biomass (영국의 신재생에너지 정책-바이오매스를 중심으로)

  • Ryu, Chang-Kook
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.3
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    • pp.260-265
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    • 2008
  • As one of renewable energy sources, biomass is playing a major role in reducing the greenhouse gas emission in the UK. The country currently produces about 4.5% (18.1TWh in 2006) of the total electricity generation from renewables, where biomass-based sources accounts for 50% of the amount and the remainder mostly from hydro and windpower. In 2007, the UK government has announced its new energy policy through the Energy White Paper, which includes an ambitious national target of 60% cuts in carbon emission by 2050. Complementary strategic plans in key renewable energy technologies accompanied the Energy White Paper, including biomass strategy, waste strategy and low carbon transportation strategy. This paper summarizes the current status and policy of UK for renewable energy production with focus on the use of biomass and bioenergy.

Color tunable electroluminescence with polymer blends composed of PVK and copolymer containing SiPh-PPV and MEH-PPV unit

  • Oh, Gwang-Chae;Yun, Je-Jung;Park, Su-Mi;Son, Sung-Hee;Han, Eun-Mi;Jin, Sung-Ho;Gu, Hal-Bon;Choi, Hyun-Chual
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.736-739
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    • 2002
  • We report on white light emission from a light emitting diode(LED) prepared by blending a red emitting copolymer, m-SiPh PPV-co-MEH PPV, and a blue emitting polyvinylcarbazole (PVK). White light emission was realized when the weight ratio of the m-SiPh PPV-co-MEH PPV : PVK equals to 1 : 30, in which the commission Internationale de L'Eclairage coordinates were x=0.3266 and y=0.3438.

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Photoluminescence Properties of $Eu^{2+}$ and $Mn^{2+}$ Activated (Ba, Sr)$_2ZnS_3$ Red Phosphor with Optimal Composition for White LED.

  • Lee, Chi-Woo;Petrykin, Valery;Tezuka, Satoko;Kakihana, Masato
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1297-1299
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    • 2009
  • A series of $Eu^{2+}/Mn^{2+}$ co-activated $Ba_{1.98-x}Sr_xZnS_3$ red emission phosphors was synthesized using the polymerizable complex method. The excitation spectra of the materials contain two wide bands centered at 345nm and 445nm, implicating their possible use for white LED lighting applications. In addition, substitution of Sr for Ba by 20% (x=0.4) improved drastically the emission intensity as well as the internal quantum efficiency compared to those for Sr-free $Ba_2ZnS_3:Eu^{2+}/Mn^{2+}$ phosphor.

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Modeling of Mixed Phosphors in White Light Emitting Diode (백색 발광다이오드에서의 혼합 형광체 모델링)

  • Kim, Dowoo;Gong, Dayeong;Gong, Myeongkook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.7
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    • pp.567-574
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    • 2013
  • An optical model is proposed in the white LED using phosphor and LED chip. In this paper a new model that describes the absorption rate and quantum efficiency with increasing the mixing ratio of phosphor in silicone, and the allotment of the phosphor absorption optical power in the several phosphor mixing in the silicone. Single phosphor in silicone from the optical measurement data before and after molding, the solution to get the blue optical power and the phosphor emission optical power is proposed. By these solution the absorption rate and the quantum efficiency was obtained. The model with single phosphor mixing in the silicone the validity was confirmed.

Emission Properties of White Organic Light-Emitting Diodes with Blue Emitting Layer (청색 발광층에 의한 백색 OLED의 발광 특성)

  • Chun, Hyun-Dong;Na, Hyunseok;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.6
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    • pp.451-456
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    • 2013
  • To study emission properties of white phosphorescent organic light emitting devices (PHOLEDs), we fabricated white PHOLEDs of ITO(150 nm) / NPB(30 nm) / TcTa(10 nm) / mCP(7.5 nm) / light-emitting layer(25 nm) / UGH3(5 nm) / Bphen(50 nm) / LiF(0.5 nm) / Al(200 nm) structure. The total thickness of light-emitting layer with co-doping and blue-doping/co-doping using a host-dopant system was 25 nm and the dopant of blue and red was FIrpic and $Bt_2Ir$(acac) in UGH3 as host, respectively. The OLED characteristics were changed with position and thickness of blue doping layer and co-doping layer as light-emitting layer and the best performance seemed in structure of blue-doping(5 nm)/co-doping(20 nm) layer. The white PHOLEDs showed the maximum current density of $34.5mA/cm^2$, maximum brightness of $5,731cd/m^2$, maximum current efficiency of 34.8 cd/A, maximum power efficiency of 21.6 lm/W, maximum quantum efficiency of 15.6%, and a Commission International de L'Eclairage (CIE) coordinate of (0.367, 0.436) at $1,000cd/m^2$.

Synthesis and Luminescent Characteristics of Sr4Al14O25 Phosphor (Sr4Al14O25 형광체의 합성과 발광특성)

  • Han Sang Hyuk;Kim Young Jin
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.529-534
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    • 2004
  • $Sr_{4}Al_{14}O_{25}$ was synthesized by solid state reaction with flux. $H_{3}BO_3$ was used to synthesize $SrO-Al_{2}O_{3}$ phosphor system as a flux. The effect of doping system such as Eu+Dy, Eu, and Ce on the luminescent properties of $Sr_{4}Al_{14}O_{25}$ was investigated. Both PL spectra of $Sr_{4}Al_{14}O_{25}$:Eu and $Sr_{4}Al_{14}O_{25}$:Eu+Dy excited at 390 nm showed greenish-blue emission at about 490 nm, while the emission wavelength was shifted to 400 nm by doping Ce. The reduction of $Eu^{3+}$ ions to $Eu^{2+}$ could be accomplished by the annealing process under $N_{2}^{+}$ vacuum atmosphere, and attributed to the emission at 490 nm. It is verified that $Sr_{4}Al_{14}O_{25}$:Eu phosphor is suitable for white LEDs became of a broad absorption band peaking at 390 nm.

Two Wavelength OLED with the Stacked GDI602(691)/GDI602(Rubrene) Fluorescent Layer (Stacked GDI602(691)/GDI602(Rubrene) 형광층을 갖는 2-파장 유기발광소자)

  • Jang, Ji-Geun;Chang, Ho-Jung;Oh, Myung-Hwan;Kang, Jung-Won;Lee, Jun-Young;Gong, Myoung-Seon;Lee, Young-Kwan;Kim, Hee-Won
    • Korean Journal of Materials Research
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    • v.17 no.4
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    • pp.198-202
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    • 2007
  • A new organic light emitting device(OLED) with two peak wavelength(blue and yellow) emission was fabricated using the selective doping in a single fluorescent host , and its electrical and optical characteristics were investigated. The fabricated device showed the luminance and efficiency of 1600 $Cd/m^2$ and 2.4 Im/W under the applied voltage of 10V, respectively. And its electroluminescent spectra had two peak wavelengths of 470nm and 560nm emitting bluish white light. The OLED with dual wavelength emission in this experiment is likely to be developed as a white OLED with simpler fluorescent system than conventional devices.

Effect of Shell Structure of Artificial Lightweight Aggregates on the Emission Rate of Absorbed Water (인공경량골재의 표피층 구조가 흡수된 물의 방출속도에 미치는 영향)

  • Kang, Seung-Gu
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.750-754
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    • 2008
  • The artificial aggregates with dense surface layer (shell) was fabricated and the dependence of water emission rate upon the shell structures was studied. The EAF dust containing many flux components and waste white clay with ignition loss of above 48% were used as for liquid phase and gas forming agents during a sintering process respectively. In addition, the shell structure was modified with various processes and the modification effect on water emission rate was analyzed. The pores under $10{\mu}m$ were found in the sintered artificial light aggregates and disappeared by incorporating to a bigger pore during re-sintering. The water emission rate in an initial step depended on a void content of aggregates filled in a bottle rather than a shell structure. But, after 7 days where the water emission of the aggregate with a shell is above 40%, the shell of aggregates suppressed the water emission. The core of aggregates was exposed and most shell was lost when crushed to smaller size so, the ability for suppressing water emission of the crushed aggregates decreased. The activation energy for the water emission was $3.46{\pm}0.25{\times}10^{-1}$J/mol for the most specimens showing that the activation energy is irrelevant to the pore size distribution and shell structure.