• Title/Summary/Keyword: wet-work

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Recovery of Rare Earth Metal from Used Automotive Three-Way Catalyst (자동차용 폐 삼원촉매로부터의 희귀금속 회수공정 기술 동향)

  • Hong, Yeon Ki
    • Journal of Institute of Convergence Technology
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    • v.1 no.1
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    • pp.13-17
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    • 2011
  • The car industry is one of the technological applications which more rare earth metals employes as three-way catalysts. Therefore, the recovery of rare earth metals from the used automotive three-way catalysts could be important source to obtain these metals. This work presents the analysis of market and demand for rare earth metal in automotive three-way catalyst and introduces the dry and the wet processes for the recovery of rare earth metals from used three-way catalyst. Finally, the alternative methods to conventional wet processes was simply suggested based on the economic and ecological point of view.

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Enhancement of Field Emission Characteristics of CuO Nanowires Formed by Wet Chemical Process (습식공정으로 형성된 구리산화물 나노와이어의 전계방출특성 향상)

  • Sung Woo-Yong;Kim Wal-Jun;Lee Seung-Min;Lee Ho-Young;Park Kyung-Ho;Lee Soonil;Kim Yong-Hyup
    • Journal of Surface Science and Engineering
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    • v.37 no.6
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    • pp.313-318
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    • 2004
  • Vertically-aligned and uniformly-distributed CuO nanowires were formed on copper-coated Si substrates by wet chemical process, immersing them in a hot alkaline solution. The effects of hydrogen plasma treatment on the field emission characteristics of CuO nanowires were investigated. It was found that hydrogen plasma treatment enhanced the field emission properties of CuO nanowires by showing a decrease in turn-on voltage, and an increase in emission current density, and stability of current-voltage curves. However, the excessive hydrogen plasma treatment made the I-V curves unstable. It was confirmed by XPS (X-ray Photoelectron Spectroscopy) analysis that hydrogen plasma treatment deoxidized CuO nanowires, thereby the work function of the nanowires decreased from 4.35 eV (CuO) to 4.1 eV (Cu). It is thought that the decrease in the work function enhanced the field emission characteristics. It is well-known that the lower the work function, the better the field emission characteristics. The results suggest that the hydrogen plasma treatment is very effective in achieving enhanced field emission properties of the CuO nanowires, and there may exist an optimal hydrogen plasma treatment condition.

Measurement of Nitrogen and Sulfur Deposition to Lake Paldang (팔당호로의 질소와 황성분 침적 측정)

  • Ghim Young Sung;Jin Hyoun Cheol
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.39-48
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    • 2005
  • Nitrogen and sulfur deposition was measured on Lake Pal dang from March 2002 to October 2003. Wet and dry depositions were separately measured using wet- and dry-only samplers, respectively. In order to measure the dry deposition to the water body, a dry deposition sampler composed of three pans filled with pure water, called the deposition water, was used. Since ammonium was generally in excess in ambient air, more than half of ammonium was present in the gaseous form. Ammonium concentration was also generally higher than the sum of major anion concentrations in the deposition water because gaseous species were much easily deposited than the species in fine particles. Nevertheless, the contribution of gaseous ammonia to the deposition of ammonium was not high as well as that of particulate ammonium while the contribution of gaseous nitric acid was much higher than that of particulate nitrate. Annual wet deposition fluxes of nitrogen and sulfur were five and six times higher than their dry deposition fluxes, respectively. Except for ammonium, the dry deposition flux estimated in the present work was a half of the previous results. This was mainly caused by much smaller dry deposition velocities over the water than over the ground.

Wet Fine Grinding of Rice Husk Ash using a Stirred Ball Mill (교반 볼밀을 이용한 왕겨재의 습식 미세분쇄에 관한 연구)

  • Park, S.J.;Kim, M.H.;Choi, Y.K.
    • Journal of Biosystems Engineering
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    • v.31 no.1 s.114
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    • pp.33-38
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    • 2006
  • This work was conducted to find the operating characteristics of an efficient wet grinding system designed to obtain fine rice husk ash powder. Once the rice husk was combusted and the thermal energy was recovered from the furnace, the ash was fed and pulverized in the grinding system resulting a fine powder to be used as a supplementary adding material to the portland cement. Grinding time (15, 30, 45 min), impeller speed (250, 500, 750 rpm), and mixed ratio (6.7, 8.4, 11.l, 20.9) were three operating factors examined for the performance of a wet-type stirred ball mill grinding system. For the operating conditions employed, mean diameter of fine ash powder, specific energy input, and grinding energy efficiency were in the range of $2.83{\sim}9.58{\mu}m,\;0.5{\sim}6.73kWh/kg,\;and\;0.51{\sim}3.27m^2/Wh$, respectively. With the wet-type stirred ball mill grinding system used in this study, the grinding energy efficiency decreased with the increase in total grinding time, impeller speed, and mixed ratio. The difference in specific surface area of powder linearly increased with logarithm in total number of impeller revolution and the grinding energy efficiency linearly decreased. Grinding time of 45 min, impeller speed of 500 rpm, and mixed ratio of 6.7 were chosen as the best operating condition. At this condition, mean particle diameter of the fine ash, grinding energy efficiency, grinding throughput, and specific energy input were $2.84{\mu}m,\;2.28m^2/Wh,\;0.17kg/h$, and 2.03kWh/kg, respectively. Wet fine grinding which generates no fly dust causing pollution and makes continuous operation easy, is appeared to be a promising solution to the automatization of rice husk ash grinding process.

Change of Physical Property of Rubber Compound by Terpene Modified Phenolic Resin Structure (테르펜 개질 페놀 수지 구조에 따른 배합고무 물성 변화)

  • Kim, Kun Ok;Kim, Do-Heyoung;Song, Yo Soon
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.310-316
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    • 2020
  • Terpene-modified phenolic resins were used to improve the tires wet traction related to the driving safety and also rolling resistance related to fuel efficiency. In this work, alpha-pinene, beta pinene, and delta limonene resins, which constitute different basic structures of terpene-modified phenolic resins, were individually added to the tread compounds of tires and their physical properties were compared with those of the alkyl phenol resin compounds. Alkyl phenolic resins showed no significant difference in tangent delta from terpene-modified phenolic resins at 0 ℃, which is related to wet traction, but showed higher tangent delta at 80 ℃, which is related to rolling resistance, indicating smaller fuel efficiency improvement effects. Among the terpene-modified phenolic resins, beta pinene one showed improved wet traction and fuel efficiency compared to those of other resins. Delta limonene resin showed the best wet traction improvement effect, and alkyl phenolic resins showed relatively high tensile strength and abrasion property. All terpene-modified resins exhibited better rolling resistance than those of alkyl phenolic ones so that they can be said to have better fuel efficiency improvement effects and also to improve other properties compared to those of blanks. Terpene-modified phenolic resins could be used when mixing tire compounds referring to the properties of the phenolic resins revealed in this work, which could result in preparing compounds with improved wet traction and rolling resistance.

Delay Factors Based on the Importance of Finish Work in Apartment Construction Project (공동주택 마감공사 중요도 기반 작업지연 요인 분석)

  • Lee, Seung-Hoon;Lee, Sang-Hyo;Kim, Ju-Hyung;Kim, Jae-Jun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2010.05a
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    • pp.125-129
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    • 2010
  • The ultimate goal of construction is to complete the given work in the most economical and safest way within the required construction period while meeting the quality standards specified in the design drawing. There are a few characteristics of finish work. First, executed in subdivided processes, finish work involves a very diverse and complex structure. Second, there are no criteria for each segmented process with regard to the appropriate time of input. Third, it is not very necessary to set priorities for lead and lag works. This study intends to provide information on the completion of a project in accordance with the required duration by setting priorities in the delay of each detailed process of finish work to minimize delay in finish work. In this study, finish work is divided into wet work and other types of finish work, and the importance of each process is classified based on the given details of each process. In addition, the study employs a survey to analyze delay factors of a designer, a constructor, and a supplier. Using the survey results, the study sets priorities in delay of final work to provide information on the completion of an apartment project within the planned construction period.

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Spatial Changes in Work Capacity for Occupations Vulnerable to Heat Stress: Potential Regional Impacts From Global Climate Change

  • Kim, Donghyun;Lee, Junbeom
    • Safety and Health at Work
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    • v.11 no.1
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    • pp.1-9
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    • 2020
  • Background: As the impact of climate change intensifies, exposure to heat stress will grow, leading to a loss of work capacity for vulnerable occupations and affecting individual labor decisions. This study estimates the future work capacity under the Representative Concentration Pathways 8.5 scenario and discusses its regional impacts on the occupational structure in the Republic of Korea. Methods: The data utilized for this study constitute the local wet bulb globe temperature from the Korea Meteorological Administration and information from the Korean Working Condition Survey from the Occupational Safety and Health Research Institute of Korea. Using these data, we classify the occupations vulnerable to heat stress and estimate future changes in work capacity at the local scale, considering the occupational structure. We then identify the spatial cluster of diminishing work capacity using exploratory spatial data analysis. Results: Our findings indicate that 52 occupations are at risk of heat stress, including machine operators and elementary laborers working in the construction, welding, metal, and mining industries. Moreover, spatial clusters with diminished work capacity appear in southwest Korea. Conclusion: Although previous studies investigated the work capacity associated with heat stress in terms of climatic impact, this study quantifies the local impacts due to the global risk of climate change. The results suggest the need for mainstreaming an adaptation policy related to work capacity in regional development strategies.

A Study of Skid Resistance Characteristics by Deicing Chemicals (제설제 사용으로 인한 노면 미끄럼저항 특성 연구)

  • Lee, Seung Woo;Woo, Chang Wan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.5D
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    • pp.813-819
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    • 2006
  • Skid Resistance is a index to represent the friction between tire and road surface, which influences driving safety. Skid resistance varies with the conditions of tire, abrasion of road surface, vehicle speed, drying, wet and freezing condition of road surfaces. Especially, freezing occurs when temperature drops below $0^{\circ}C$ followed by snow or rain causes decrease of skid resistance. To recover the decreased skid resistance deicing work is applied. As a results of deicing works, freezing condition is changed into wet condition. However the wet road surfaces containing the remaining deicings agents may not show the skid resistance of normal wet condition. In this study, skid resistances in the condition of freezing, deicing process and deicing agents remained after snow-removal are evaluated. The test results, skid resistance recover quickly when Pre-wetted salt spreading and NaCl was used as deicing method. Skid resistance of Deicing agents remained on the road surface showed that concrete is higher than asphalt. superior effect. Recovery rate of skid resistance by comparison wet condition is 54~80%.

Fibril Removal from Lyocell by Enzymatic Treatment -Compare NaOH Pre-treatment with Treating Enzyme (전처리에 의한 리오셀의 피브릴레이션 변화 -NaOH와 효소 처리 중심으로-)

  • Park, Ji-Yang;Kim, Ju-Hea;Jeon, Dong-Won;Park, Young-Hwan
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.8
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    • pp.1323-1332
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    • 2006
  • Lyocell is a regenerated cellulose fiber manufactured by an environmentally-friendly process. Since the fiber has more crystalline region compared to rayon, lyocell shows higher wet-strength than rayon. Although fibril generation of lyocell is lower than that of rayon because of the reason, the fibril generated during the wet process deteriorates the smooth look and soft touch of the fabric. The efficient way to remove the fibril yet retain the strength property was investigated in this work. In order to scour and remove the fibril from the fabric, cellulase enzymes were introduced and the traditional scouring was carried to be compared. Weight loss, dye-ability, and strength of treated fabric were measured after the treatments. Scanning electron microscopy was used to observe the surface of the fiber. Among the cellulases used in this work, Denimax 992L showed the best results for removal of fibril with low weight loss and tensile strength loss. The optimal conditions for the enzymatic treatment could be chosen depending on a characteristic for final purpose of the lyocell product.

Wet Chemical Surface Modification of ITO by Self Assembled Monolayer for Organic Thin Film Transistor (유기 트랜지스터를 위한 자가조립단층을 이용한 ITO의 습식 표면개질)

  • Jee, Seung-Hyun;Kim, Soo-Ho;Ko, Jae-Hwan;Park, Hoon;Lee, Kwang-Hoon;Yoon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.450-450
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    • 2007
  • Indium tin oxide (ITO), which is used as an electrode in organic thin film transistors (OTFT), was modified with a self-assembled monolayer (SAM) by wet chemical surface modification. The surface of the ITO was treated by dipping method in a solution of 2-chloroethane phosphonic acid (2-CEPA) at room temperature. The work function in the ITO which was modified with the SAM in the 2-CEPA had 5.43eV. A surface energy and a transmittance were unchanged in an error range. On this study, therefore, possibility of ohmic contact is showed in the interface between the ITO and the organic semiconductors. These results suggest that the treatment of the ITO with the SAM can greatly enhance the performance of the OTFT.

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