• Title/Summary/Keyword: wet deposition

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Numerical Studies of Cloud Acidification Processes Using a One Dimensional Cumulus Cloud Model (일차원 적운모델을 이용한 산성강우 형성에 관한 수치적 연구)

  • 곽노혁;안상욱;홍민선
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.3
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    • pp.145-149
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    • 1991
  • A one dimensiional cumulus cloud model has been developed for the investigation of temporal and altitudinal variation of trace gases and the wet deposition rates of sulfate for different simulation conditions. The results show that the dynamic field, liquid mixing ratios and the solubility of trace gases affect the distribution of trace gases and the droplet pH. Temporal variation of the predicted surface precipitation and sulfate deposition rates agree well with the field data.

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The Concentration of Polychlorinated biphenyls and Bozenehexachlorides in Plants (식물 중 PCBs와 BHCs의 농도)

  • 최민규;김희강;천만영;김태욱;여현구;선우영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.94-95
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    • 2000
  • PCBs(polychlorinated biphenyls)와 BHCs(benzene hexachlorides)와 같은 SOCs(semivolatile organic compounds)는 모든 대륙에서 검출되어지고 있으며, 심지어 장거리 수송에 의해 청정지역인 북극에서도 검출되고 있다. 이들 성분들은 친지질성(lipophilic)으로 대부분이 가스상으로 존재하여 식물의 표면에 존재하는 지질(lipid)에 건성침착(dry deposition) 또는 습성 침착(wet deposition)된다. 이렇게 침착된 성분들의 농도는 대기중 농도와 밀접한 관계가 있다고 보고되고 있다(천만영,1998; Simonich and Mites, 1995). (중략)

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Comparison of Chemical Characteristics between Rain and Snow on the Western Coast of Korea (서해안 지역 강우와 강설의 화학적 특성 비교)

  • 강공언;방소영;신대윤
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.443-444
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    • 2001
  • 대기오염물질이 대기중에 배출되게 되면 그 일부는 오염 발생원의 인접한 지표면에 건성 침착하여 제거되지만 그 대부분은 장거리 이동하면서 2차 오염물질로 변환되어 건성침착 (dry deposition)하거나 강수시 습성 침착 (wet deposition)에 의해 지표면으로 제거된다 (원 굉, 1991, Legge and Krupa, 1990). 습성침착의 대표적인 형태로는 강우와 강설이 있으며, 이것은 대기중 오염물질이 지표로 제거되는 중요한 경로라 하겠다. (중략)

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Study on Wet chemical Etching Characterization of Zinc Oxide Film for Transparency Conductive Oxide Application (투명 전도성 산화물 전극으로의 응용을 위한 산화아연(ZnO) 코팅막의 습식 식각 특성연구)

  • Yoo, Dong-Geun;Kim, Myoung-Hwa;Jeong, Seong-Hun;Boo, Jin-Hyo
    • Journal of the Korean Vacuum Society
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    • v.17 no.1
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    • pp.73-79
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    • 2008
  • In order to apply for transparent conductive oxide(TCO), we deposited ZnO thin films on the glass at room temperature by RF magnetron sputtering method. Deposition conditions for high transmittance and low resistivity were optimized in our previous studies. Under the deposition condition with the RF power of 200 W, target to substrate distance of 30 mm and working pressure of 5 mTorr, highly conductive($7.4{\times}10^{-3}{\Omega}cm$) and transparent(over 85%) ZnO films were prepared. Highly oriented ZnO film in the [002] direction were obtained with specifically designed ZnO targets. Systematic study on dependence of deposition parameters on electrical and optical properties of the as-grown ZnO films were mainly investigated in this work. And for application tests using these films as transparent conductive oxide anodes, wet chemical etching behaviors of ZnO films were also investigated using various chemicals. Wet-chemical etching behavior of ZnO films were investigated using various acid solutions. The concentrations of these different acid solutions were controlled to study the etching shapes and etching rate. ZnO films were anisotropically etched at various concentrations and wet etching led to crater-like surface structure. Also we firstly found that the etching rate and etching shapes of ZnO films strongly depended on the etchant concentrations (i.e. pH) and the etching rate is exponentially decreased with increasing pH values regardless of the acid etchants.

Prediction of radioactivity releases for a Long-Term Station Blackout event in the VVER-1200 nuclear reactor of Bangladesh

  • Shafiqul Islam Faisal ;Md Shafiqul Islam;Md Abdul Malek Soner
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.696-706
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    • 2023
  • Consequences of an anticipated Beyond Design Basis Accident (BDBA) Long-Term Station Blackout (LTSBO) event with complete loss of grid power in the VVER-1200 reactor of Rooppur Nuclear Power Plant (NPP) of Unit-1 are assessed using the RASCAL 4.3 code. This study estimated the released radionuclides, received public radiological dose, and ground surface concentration considering 3 accident scenarios of International Nuclear and Radiological Event Scale (INES) level 7 and two meteorological conditions. Atmospheric transport, dispersion, and deposition processes of released radionuclides are simulated using a straight-line trajectory Gaussian plume model for short distances and a Gaussian puff model for long distances. Total Effective Dose Equivalent (TEDE) to the public within 40 km and radionuclides contribution for three-dose pathways of inhalation, cloudshine, and groundshine owing to airborne releases are evaluated considering with and without passive safety Emergency Core Cooling System (ECCS) in dry (winter) and wet (monsoon) seasons. Source term and their release rates are varied with the functional duration of passive safety ECCS. In three accident scenarios, the TEDE of 10 mSv and above are confined to 8 km and 2 km for the wet and dry seasons, respectively in the downwind direction. The groundshine dose is the most dominating in the wet season while the inhalation dose is in the dry season. Total received doses and surface concentration in the wet season near the plant are higher than those in the dry season due to the deposition effect of rain on the radioactive substances.

Fabrication and Characterization of Cf/SiC Composite with BN Interphase Coated by Wet Chemical Process (습식법으로 제조된 BN 중간층을 가진 Cf/SiC 복합재의 제조 및 물성 평가)

  • Koo, Jun-mo;Kim, Kyung Ho;Han, Yoonsoo
    • Journal of the Korean institute of surface engineering
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    • v.50 no.6
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    • pp.523-530
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    • 2017
  • In this study, we developed the h-BN interphase for ceramic matrix composites (CMCs) through a wet chemical coating method, which has excellent price competitiveness and is a simple process as a departure from the existing high cost chemical vapor deposition method. The optimum condition for nitriding an h-BN interphase using boric acid and urea as precursors were derived, and the h-BN interphase coating through a wet method on a carbon preform of 2.5 D was conducted to apply the optimum conditions to the CMCs. In order to control the coating property via the wet coating method, four parameters were investigated such as dipping time of the specimen in the precursor solution, the ratio of boric acid and urea in the precursor, the concentration of solution where the precursor was dissolved, and the cycle of dipping and dry process. The CMCs was fabricated through polymer impregnation and pyrolysis (PIP) processes and a three-point flexural strength test was conducted to verify the role of the coated h-BN interphase.

Experimental Studies on Wet Scavenging of Atmospheric Aerosols by Rain Drops

  • Park Jeong-Ho;Suh Jeong-Min;Choi Kum-Chan
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E3
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    • pp.87-94
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    • 2005
  • Wet scavenging by rain drops is a most important removal process of air pollutants. In order to study the scavenging mechanisms of aerosol particles, the characteristics of chemical components in the rain water were examined as a function of the amount of rainfall. Rain water were collected continuously and separated into the soluble and insoluble components. The elemental concentrations in both components were determined by a PIXE analysis. The physical and chemical characteristics of atmospheric aerosols during the rainfall events were measured simultaneously. The elemental concentrations in rain water decreased substantially just after rain started and then gradually declined in subsequential rain fall exceeding 1.0 mm. The large particles were scavenged more easily than the fine particles. Fe, Ti and Si in rain water were in high insoluble state. Contrarily, almost whole of S was dissolved in rain water.

Estimation and Characteristics of Atmospheric Deposition Flux of Polycyclic Aromatic Hydrocarbons (PAHs) into the Masan and Haengam Areas of Korea (마산과 행암 지역으로 유입되는 다환방향족탄화수소(PAHs)의 대기 침적 플럭스 산정과 특성)

  • Lee Su-Jeong;Moon Hyo-Bang;Choi Min-kyu
    • Journal of Environmental Science International
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    • v.15 no.2
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    • pp.121-131
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    • 2006
  • Atmospheric bulk (wet and dry) samples were monthly collected in Masan and Heangam areas of Korea, to assess the deposition flux and seasonal variation of polycyclic aromatic hydrocarbons (PAHs). Deposition fluxes of PAHs in bulk samples were determined using gas chromatography coupled to mass spectrometer detector (GC/MSD). Particle deposition fluxes from Masan and Haengam areas varied from 13 to $87\;g/m^2/year$ and from 5 to $52\;g/m^2/year$, respectively. PAHs deposition fluxes in atmospheric bulk samples in Masan and Haengam areas ranged from 135 to $464\;{\mu}g/m^2/year$ and from 62.2 to $194\;{\mu}g/m^2/year$, respectively. Atmospheric deposition fluxes of particles and PAHs in this study were comparable to or slightly lower values than those from different locations in Korea and other countries. PAHs profiles of atmospheric deposition bulk samples showed slightly different from two sampling areas, however the predominant species of PAHs were similar. Indeno (1,2,3-c,d)pyrene, benzo(g,h,i)perylene, phenanthrene compounds were the most detected PAHs in deposition bulk samples. Carcinogenic PAHs occupied the contribution of approximately $30-40\%$ of the total PAHs deposition fluxes. The non-metric multi-dimensional scaling (MDS) was used, to assess the differentiation of PAHs source between two sampling areas. The result suggests that PAHs contamination sources were different according to the location and season surveyed. There was no an apparent relationship between the PAHs deposition flux against temperature and rainfall amount, even though summer season with the highest temperature and the largest amount of precipitation showed the lowest PAHs deposition flux. Benzo(e)pyrene/benzo(a)pyrene ratio indicated that the photo-degradation process was one of important factors to the seasonal variation of PAHs with the lower deposition fluxes.

Deposition flux of dioxin-like polychlorinated biphenyls(DLPCBs) in urban environment of Busan (도심 지역의 다이옥신류 폴리염화비페닐류의 침적 플럭스)

  • Mun, Hyo-Bang;Lee, Su-Jeong;Choe, Hui-Gu;Ok, Gon
    • Journal of Environmental Science International
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    • v.13 no.5
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    • pp.469-478
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    • 2004
  • Atmospheric bulk (wet and dry) samples were monthly collected in an urban environment (Daeyeon-dong) of Busan over a year, to assess the deposition flux and seasonality of dioxin-like polychlorinated biphenyls (DLPCBs) using stainless steel pots. Deposition fluxes of DLPCBs in bulk samples were determined using high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC/HRMS). Particle deposition fluxes in the urban environment varied from 23 to 98 $mg^2$/year (mean 41 $gm^2$/year). DLPCB deposition fluxes in atmospheric bulk samples ranged from 0.09 to 0.77 ng-$TEQ/m^2$/year (mean 0.35 ng-$TEQ/m^2$/year). Seasonal atmospheric deposition fluxes of DLPCBs were high in winter and low in summer. Atmospheric deposition fluxes of particles and DLPCBs in this study were comparable to or slightly lower values than those of different locations in the world. Monthly DLPCB profiles in deposition bulk samples were similar over a year. Non-ortho PCBs were higher contributions to the total DLPCBs fluxes than mono-ortho PCBs. In particular, PCB 126 had the highest concentrartion (>75%) in all deposition samples, followed by PCB 169 and PCB 156. A highly positive correlation was found among the deposition fluxes of DLPCB species, suggesting the possibility of that the DLPCB contamination originated from one source. The deposition fluxes of DLPCBs were not significantly correlated with temperature and the amount of precipitation even though the summer season with the highest temperature and the largest amount of precipitation showed the lowest DLPCB deposition flux.