• Title/Summary/Keyword: waterborne

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Synthesis and Comparison of Properties of Waterborne Polyurethanes Using Polyols Containing 3-Methyl-1,5-Pentanediol (MPD) (3-Methyl-1,5-Pentanediol (MPD)을 함유한 폴리올을 이용한 수분산 폴리우레탄의 합성 및 특성 비교)

  • Kim, Na-Young;Sur, Suk-Hun
    • Journal of Adhesion and Interface
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    • v.22 no.2
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    • pp.39-46
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    • 2021
  • Waterborne polyurethanes (WPU) was synthesized using polyester polyol and polycarbonate polyol containing 3-Methyl-1,5-pentanediol (MPD) in a branched structure. To compare physical properties, WPUs were synthesized using polyester polyol obtained from 1,4-butanediol (BD) and adipic acid and polycarbonate polyol obtained from 1,6-hexane diol (HD)/ 1,4-butanediol (BD). This study investigated the effect of polyol molecular structure (molecular structure in soft segments) on the physical properties of WPUs. In the case of WPUs synthesized using polyols containing MPD, 100% modulus and tensile strength were lower than that without MPD, and elongation was higher. The transparency of WPU films with MPD were slightly better than WPU films without MPD.

Effect of Accelerated Weathering on the Leaching of Copper from Preservative Treated Wood (기상열화가 방부처리재의 구리성분 용탈에 미치는 영향)

  • Lee, Myung-Jae;Lee, Dong-Heub;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.4
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    • pp.38-43
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    • 2003
  • This is the second in a series of reports on the evaluation of weathering durability of waterborne preservative treated wood by accelerated weathering. The leaching of copper from ACQ-, CCA-, and CuAz-treated samples during weathering was increased by UV irradiation, when compared between full weathering and water-only weathering. The FTIR spectra of the weathered ACQ-, CCA, CuAz-treated samples at 1731 cm-1, 1625 cm-1, 1510 cm-1, which are related to the fixation of copper, were different from those of unweathered controls. This result means that UV irradiation can weaken the chemical bond between lignin and copper and/or extraction of lignin-copper complex can be occured when lignin erode away by weathering.

Preparation and Properties of Eco-friendly Waterborne Polyurethane-urea Primer for Thermoplastic Polypropylene Applied to Automobile Interiors (자동차 내장재용 열가소성 폴리프로필렌에 적용되는 선처리제용 친환경 수분산 폴리우레탄-우레아의 제조 및 성질)

  • Shin, Jong Sub;Park, Jin Myeong;Lee, Young Hee;Kim, Han Do
    • Clean Technology
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    • v.20 no.3
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    • pp.232-240
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    • 2014
  • The significance of thermoplastic polyolefin polypropylene (PP) lies in its potential to replace polyvinyl chloride (PVC), the most widely used material for automobile interiors (door trim, dash board), which discharges harmful compounds in certain conditions. Another benefit of PP (0.855 amorphous - 0.946 crystalline $g/cm^3$) is its low density compared to that of PVC ($1.1-1.45g/cm^3$), which reduces vehicle weight. Market demand for eco-friendly water-based adhesive/coating material is rising significantly as a substitute for solvent-based adhesive/coating material which emits VOC and causes harmful working conditions. Under such context, in this study, a series of eco-friendly waterborne polyurethane-urea primer (a paint product that allows finishing paint to adhere much better than if it were used alone) for hydrophobic PP were prepared from different mix of DMPA content, NCO/OH molar ratio, various wt% of silicone diol and various soft segment content, among which DMPA of 21 mole %, NCO/OH molar ratio of 1.2, modified silicone diol of 5 wt% and soft segment content of 73 wt% led to good adhesion strength. Additionally, the incorporation of optimum content of additives (0.5 wt% dispersing agent, 0.5 wt% levelling agent, 1.5 wt% antifoaming agent, 3.0 wt% matting agent) into the optimum waterborne polyurethane-urea also enabled good stability, levelling, antifoaming and non-glossy.

Epidemiological investigation on the outbreak of foodborne and waterborne disease due to Norovirus with delayed notification (노로바이러스에 기인한 수인성·식품매개감염병 집단발생의 지연신고에 대한 역학조사)

  • Ha, Mikyung;Kim, Hyeongsu;Kim, Yong Ho;Na, Min Sun;Yu, Mi Jung
    • Journal of agricultural medicine and community health
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    • v.43 no.4
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    • pp.258-269
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    • 2018
  • Objectives: There was an outbreak of foodborne and waterborne disease among high school students at Okcheon in June, 2018. First attack occurred June $5^{th}$ but seven days later it was notified. The purpose of this investigation was to evaluate the pathogen of outbreak and cause of delayed notification. Methods: First, we did a questionnaire survey for 61 cases and 122 controls to find what symptoms they had and whether they ate foods or drank water from June $2^{nd}$ to June $12^{th}$. Second, we investigated the environment of cafeteria and drinking water. Third, we examined specimen of cases and environment to identify bacteria or virus. Results: Attack rate of this outbreak was 7.8%. Drinking water was strongly suspected as a source of infection in questionnaire survey but we could not find the exact time of exposure. Norovirus was identified in specimen of cases (2 students), drinking water (at main building and dormitory) and cafeteria (knife, dishtowel, hand of chef) Conclusions: We decided norovirus as the pathogen of this outbreak based on the clinical features of cases with diarrhea vomiting, abdominal pain and recovery within 2 or 3 days after onset, outbreak due to drinking water and microbiologic examination, And the cause of delayed notification might be the non-existence of the nurse teacher at that time and the lack of understanding of teachers on immediate notification under the outbreak. To prevent the delayed notification, notification system about outbreak of foodborne and waterborne disease in school is needed to be improved.

Preparation and Properties of Crosslinked Waterborne Polyurethane/Poly(vinyl alcohol) Blend Films (가교된 수분산폴리우레탄/폴리비닐알콜 블렌드 필름의 제조 및 특성)

  • Kang, Bo-Kyung;Kwak, Yong-Sil;Lee, Young-Hee;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.289-290
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    • 2003
  • Polymer blending constitutes a most useful method for the improvement or modification of the physicochemical properties of polymeric materials. So polymer blends have gained an increasing interest in both industrial and scientific fields. Some of the polymer blends exhibit unusual properties, unexpected from homopolymers. An important property of a polymer blend is the miscibility of its component, because it affects the mechanical properties, the morphology, its permeability and dogradation [1,2]. (omitted)

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Effects of Several Surfactants in the WBPU/Octadecane as a Phase Change Material (상전이 물질을 함유하는 수분산 PU에서 계면활성제의 효과)

  • Jang, Jae-Hyuk;Lee, Young-Hee;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.287-288
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    • 2003
  • Polyurethane(PU) materials have been generally used in the automobile, paint, furniture, adhesive, and textile industries. The use of Waterborne PU was motivated form the environmental point of view, i.e. reduction of solvent emissions into the atmosphere(volatile organic compounds, VOC)[1]. Generally speaking, phase change materials (PCM) have the capability of absorbing or releasing thermal energy to reduce or eliminate heat transfer at the temperature range of the particular temperature stabilizing material[2]. (omitted)

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Preparation and Properties of Polyaniline Co-doped with Dodecyl benzenesulfonic Acid/Hydrochloric Acid and Its Blend with Wateborne-Polyurethane (Dodecylbenzene Sulfonic Acid/Hydrochloric Acid Co-doping System을 이용한 Polyaniline 합성 및 Polyaniline/Waterborne-Polyurethane 블렌드에 관한 연구)

  • Kwon, Ji-Yun;Lee, Young-Hee;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.36-39
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    • 2003
  • Conducting polymers are finding increasing number of applications in various electronic devices such as chemical sensors, electrochromic display, light emitting diodes, etc. Polyaniline(PANI) ranks among highly prospective conduction polymers. PANI was first synthesis in 1862[1] and has been extensively studied as a conducting polymer since the 1980s[2]. The side range of electrical, electrochemical and optical properties coupled with good environmental stability makes PANI potentially attractive for application as an electronic material. (omitted)

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Preparation and Properties of Waterborne Polyurethane-Urea Hydrogels Based on Poly(ethylene glycol): -Effect of EDA and DMPA Content- (Poly(ethylene glycol)을 이용한 수분산 폴리우레탄 hydrogels의 제조와 물성 -EDA 및 DMPA함량의 영향-)

  • Kwak, Yong-Sil;Kang, Bo-Kyung;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.33-35
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    • 2003
  • Over the last 30 years, water-swellable and water-insoluble hydrogels have been extensively investigated and developed, leading to a large family of materials which have found use in a wide range of biomedical applications such as carriers of soft tissues, wound healing, ophthalmological applications, membranes for artificial kidney, and materials for blood compatible and other medical devices[1-3]. (omitted)

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Evaluation of the membrane filtration and elution for detection of Giardia lamblia cysts in water (수중 Giardia lamblia cysts 검출을 위한 멤브레인 여과 및 용출에 대한 연구)

  • Hong, Uk-Seon;Kim, Gyeong-Ju;Lee, Gi-Se
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.422-423
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    • 2000
  • The protozoan parasite Giardia lamblia has been implicated as the causative agents of many outbreaks of waterborne intestinal illness. Accurate evaluation of Giardia lamblia removal in water treatment process requires a reliable method for measuring the concentrations of these pathogens in water. The relative recovery of Giardia cysts was assessed for seeded samples of distilled water. Cysts preparation was done by encystment in vitro. Membrane filtration was evaulated with cellulose acetate, polycarbonate, polypropylene, polyethersulfone, nylon membranes. Elution conditions were varied to improve cyst recovery.

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Temporal and Spatial Variability of Sound Propagation Characteristics in the Northern East China Sea (동중국해 북부해역에서 음파전달 특성의 시공간적 변동성)

  • Park, Kyeongju;Chu, Peter Cheng
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.2
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    • pp.201-211
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    • 2015
  • Acoustic propagation in shallow water with changing environments is a major concern of navy. Temporal and spatial variability of acoustic propagation in the northern East China Sea (ECS) is studied, using the 11 years hydrographic data and the Bellhop acoustic model. Acoustic propagation in the northern ECS is highly variable due to extensive interaction of various ocean currents and boundaries. Seasonal variations of transmission loss (TL) with various source depths are highly affected by sharp gradient of sound speed and bottoms interaction. Especially, various bottom sediment types lead to severely degrading a waterborne propagation with bottom loss. In particular, the highly increased TL near the ocean front depends on the source position, and the direction of sound propagation.