• Title/Summary/Keyword: water-splitting flux

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Controlling Water Splitting Characteristics of Anion-Exchange Membranes by Coating Imidazolium Polymer (이미다졸륨 고분자 코팅을 통한 음이온교환막의 물분해 특성 제어)

  • Kim, Do-Hyeong;Park, Jin-Soo;Kang, Moon-Sung
    • Membrane Journal
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    • v.25 no.2
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    • pp.152-161
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    • 2015
  • In this study, novel pore-filled anion-exchange membranes (PFAEMs) with low electrical resistance, high permselectivity, and low water-splitting flux property under a concentration polarization condition have been developed for the enhancement in the efficiency of electrochemical water treatment processes. The base membranes have been prepared by filling a copolymer containing quaternary ammonium groups with an excellent ion-exchange capability into a porous polyolefin substrate, showing a high performance superior to that of a commercial membrane. In addition, it was confirmed that the electrochemical membrane performances are preserved while the water-splitting flux is effectively controlled by coating an imidazolium polymer onto the surface of the base membrane. The prepared PFAEMs revealed remarkably low electrical resistances of about 1/6~1/8 compared to those of a commercial membrane, and simultaneously low water-splitting flux comparable with that of cation-exchange membranes under a concentration polarization condition.

Numerical Simulation of Free Surface Flows Using the Roe's Flux-difference Splitting Scheme (Roe의 Flux-difference Splitting 기법을 이용한 자유표면 유동 모사)

  • Shin, Sang-Mook;Kim, In-Chul;Kim, Yong-Jig
    • Journal of the Society of Naval Architects of Korea
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    • v.47 no.1
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    • pp.11-19
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    • 2010
  • A code is developed to simulate incompressible free surface flows using the Roe's flux-difference splitting scheme. An interface of two fluids is considered as a moving contact discontinuity. The continuities of pressure and normal velocity across the interface are enforced by the conservation law in the integral sense. The fluxes are computed using the Roe's flux-difference splitting scheme for two incompressible fluids. The interface can be identified based on the computed density distribution. However, no additional treatment is required along the interface during the whole computations. Complicated time evolution of the interface including topological change can be captured without any difficulties. The developed code is applied to simulate the Rayleigh-Taylor instability of two incompressible fluids in the density ratio of 7.2:1 and the broken dam problem of water-air. The present results are compared with other available results and good agreements are achieved for the both cases.

Calculation of overtopping discharge with time-dependent aspects of an embankment failure (시간에 따른 제방붕괴 양상을 고려한 월류량 산정)

  • Kim, Hyung-Jun;Kim, Jong-Ho;Jang, Won-Jae;Cho, Yong-Sik
    • Journal of the Korean Society of Hazard Mitigation
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    • v.7 no.3
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    • pp.69-78
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    • 2007
  • In this study, a time-dependent aspect of an embankment failure is considered to simulate a flood inundation map and calculate overtopping discharge induced by an embankment failure. A numerical model has been developed by solving the two dimensional nonlinear shallow water equations with a finite volume method on unstructured grids. To analyze a Riemann problem, the HLLC approximate Riemann solver and the Weighted Averaged Flux method are employed by using a TVD limiter and the source term treatment is also employed by using the operator splitting method. Firstly, the numerical model is applied to a dam break problem and a sloping seawall. Obtained numerical results show good agreements with experimental data. Secondly, the model is applied to a flow induced by an embankment failure by assuming that the width and elevation of embankment are varied with time-dependent functions. As a result of the comparison with each numerical overtopping discharge, established flood inundation discharges in the previous studies are overestimated than the result of the present numerical model.

SIMULATION OF RELATIVE MOTION OF FLOATING BODIES INCLUDING EFFECTS OF A FENDER AND A HAWSER (방현재와 계류삭 효과를 고려한 부유체의 상대운동 모사)

  • Shin, Sangmook
    • Journal of computational fluids engineering
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    • v.20 no.1
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    • pp.1-9
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    • 2015
  • A developed code is applied to simulate relative motion of floating bodies in a side-by-side arrangement, including effects of a fender and a hawser. The developed code is based on the flux-difference splitting scheme for immiscible incompressible fluids and the hybrid Cartesian/immersed boundary method. To validate the developed code for free surface flows around deforming boundaries, the water wave generation is simulated, which is caused by bed movement. The computed wave profile and time histories of wave elevation are compared with other experimental and computational results. The effects of a fender and a hawser are modeled by asymmetric force acting on the floating bodies according to a relative displacement with the bounds, in which the fender and the hawser exert no force on the bodies. It has been observed that the floating body can be accelerated by a gap flow due to a phase difference caused by the free surface. Grid independency is established for the computed time history of the body velocity, based on three different size grids.

Free Surface Flow in a Trench Channel Using 3-D Finite Volume Method

  • Lee, Kil-Seong;Park, Ki-Doo;Oh, Jin-Ho
    • Journal of Korea Water Resources Association
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    • v.44 no.6
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    • pp.429-438
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    • 2011
  • In order to simulate a free surface flow in a trench channel, a three-dimensional incompressible unsteady Reynolds-averaged Navier-Stokes (RANS) equations are closed with the ${\kappa}-{\epsilon}$ model. The artificial compressibility (AC) method is used. Because the pressure fields can be coupled directly with the velocity fields, the incompressible Navier-Stokes (INS) equations can be solved for the unknown variables such as velocity components and pressure. The governing equations are discretized in a conservation form using a second order accurate finite volume method on non-staggered grids. In order to prevent the oscillatory behavior of computed solutions known as odd-even decoupling, an artificial dissipation using the flux-difference splitting upwind scheme is applied. To enhance the efficiency and robustness of the numerical algorithm, the implicit method of the Beam and Warming method is employed. The treatment of the free surface, so-called interface-tracking method, is proposed using the free surface evolution equation and the kinematic free surface boundary conditions at the free surface instead of the dynamic free surface boundary condition. AC method in this paper can be applied only to the hydrodynamic pressure using the decomposition into hydrostatic pressure and hydrodynamic pressure components. In this study, the boundary-fitted grids are used and advanced each time the free surface moved. The accuracy of our RANS solver is compared with the laboratory experimental and numerical data for a fully turbulent shallow-water trench flow. The algorithm yields practically identical velocity profiles that are in good overall agreement with the laboratory experimental measurement for the turbulent flow.