• 제목/요약/키워드: water-film

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유하액막식 암모니아 흡수기에서 증기 유동방향에 따른 열 및 물질전달 특성 (Heat and Mass Transfer Characteristics of a Falling Film Ammonia Absorber with Respect to the Vapor Flow Direction)

  • 권경민;정시영;김병주;정은수
    • 설비공학논문집
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    • 제16권1호
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    • pp.16-25
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    • 2004
  • The flow and heat/mass transfer in the falling-film of a heat exchanger can be influenced by the motion of the surrounding refrigerant vapor. In this study, the effect of the vapor flow direction on the absorption heat transfer has been investigated for a falling-film helical coil which is frequently used as the absorber of ammonia/water absorption refrigerators. The experiments were carried out for different solution concentration. The heat and mass transfer performance was measured for both parallel and counter-current flow. The effect of vapor flow on the heat and mass transfer is found to be increased with decreasing solution concentration. In the experiments with low solution concentration, whose vapor specific volume is great, the counter-current flow of vapor resulted in uneven distribution of falling-film and reduced the heat transfer performance of the absorber. The direction of the vapor flow hardly affected the thermal performance as the solution concentration became stronger since the specific volume of the ammonia/water vapor was much smaller than that of the water vapor.

유기 EL 보호층으로 적용하기 위한 무기 복합 박막의 투습율 특성 연구 (Study on the Water Vapor Permeation Properties of the Inorganic Thin Composite Film for the Passivation Layer in the OLED)

  • 김광호;이주원;김영철;주병권;김재경
    • 한국전기전자재료학회논문지
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    • 제17권4호
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    • pp.432-438
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    • 2004
  • In this study, we investigated the WVTRs Properties of inorganic thin composite films(ITCFs) to be newly adopted as the passivation layer of the OLED to replace the inorganic compound material Because we thought that inorganic compound materials were limited to enhance the barrier property of thin film. So, ITCFs were fabricated by mixing the cooperated material with the base material. And then, ITCFs were deposited onto the plastic substrate using the electron beam evaporation system and the water vapor transmission rates(WVTRs) were measured using the Mocon equipment. As a result of the WVTR measurement, we could analyze the WVTR values for various ITCFs. ITCFs had a remarkably lower value than the inorganic compound film. Through the analysis of thin film, we can understand the crystal structure and mixed amount. Therefore, ITCFs can be used as the inorganic passivation layers of OLED with the inorganic compound film.

수면상 단분자막의 변위전류 (Displacement current of monolayer film on the water surface)

  • 송경호;박태곤;박근호
    • E2M - 전기 전자와 첨단 소재
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    • 제9권7호
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    • pp.674-679
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    • 1996
  • Using the home made Kuhn type LB (Langmuir - Blodgett) film's deposition apparatus, We measured the displacement current of monolayer film on the water surface. The obtained displacement current had each different pattern by the kind of solution while varying pressure of the monolayer. Solution of 4 - octyl - 4' - (5 - carboxyl - pentamethyleneoxy ) - azobenzene (8A5H) and stearic acid (CH$_{3}$(CH$_{2}$)$_{16}$COOH) (C18) were spreaded at the air water interface respectively, and the current induced by the dynamic behavior of molecules were pressed by barrier. Displacement current of 8A5H measured small current than C18 at same condition and it was positive direction when increasing pressure but it was negative direction when decreasing pressure. Also, Two patterns of displacement current were symmetrical form and appeared repeatedly. The C18 has unsymmetrical form of displacement current and weak current when decreasing pressure (expansion). The C18 molecules have two distinct peak values of displacement current that show that the orientations of molecules were changed largely at this points. From these results, we obtained that the 8A5H has more elasticity than the C18.8.C18.

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PREPARATION OF HYDROXYAPATITE COATINGS USING R.F. MAGNETRON SPUTTERING

  • Hosoya, Satoru;Sakamoto, Yukihiro;Hashimoto, Kazuaki;Takaya, Matsufumi;Toda, Yoshitomo
    • 한국표면공학회지
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    • 제32권3호
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    • pp.307-311
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    • 1999
  • The well-crystalline hydroxyapatite($Ca_{10}(PO_4)_6(OH)_2$ ; HAp) layer having a biocompatibility was successfully coated onto titanium substrate using a radio-frequency magnetron sputtering, and effects of sputtering gas and the thickness of HAp film on a crystal growth of the HAp layers were investigated. The deposition rate of the layer sputtered with water-vapour gas was slower than that of the layer sputtered with argon gas. The results of X-ray diffraction demonstrated that the about $0.8\mu\textrm{m}$ thick HAp film under water-vapour gas was an amorphous phase, the about $1.2\mu\textrm{m}$ thick film was (100) plane-oriented HAp, and the about $1.5\mu\textrm{m}$ thick film was (001)plane-oriented HAp. FT-IR analysis proved that hydroxyl group of the layer sputtered with argon gas was defected, but that of the layer sputtered with water-vapour gas was not defected. From these results, it was favorable to use water-vapour gas on the HAp coatings onto metal surface.

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Cu2O Thin Film Photoelectrode Embedded with CuO Nanorods for Photoelectrochemical Water Oxidation

  • Kim, Soyoung;Kim, Hyojin
    • 한국표면공학회지
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    • 제52권5호
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    • pp.258-264
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    • 2019
  • Assembling heterostructures by combining dissimilar oxide semiconductors is a promising approach to enhance charge separation and transfer in photoelectrochemical (PEC) water splitting. In this work, the CuO nanorods array/$Cu_2O$ thin film bilayered heterostructure was successfully fabricated by a facile method that involved a direct electrodeposition of the $Cu_2O$ thin film onto the vertically oriented CuO nanorods array to serve as the photoelectrode for the PEC water oxidation. The resulting copper-oxide-based heterostructure photoelectrode exhibited an enhanced PEC performance compared to common copper-oxide-based photoelectrodes, indicating good charge separation and transfer efficiency due to the band structure realignment at the interface. The photocurrent density and the optimal photocurrent conversion efficiency obtained on the CuO nanorods/$Cu_2O$ thin film heterostructure were $0.59mA/cm^2$ and 1.10% at 1.06 V vs. RHE, respectively. These results provide a promising route to fabricating earth-abundant copper-oxide-based photoelectrode for visible-light-driven hydrogen generation using a facile, low-cost, and scalable approach of combining electrodeposition and hydrothermal synthesis.

탈지 대두박 소재 가식성 생고분자 필름의 개발 (Defatted Soybean Meal-Based Edible Film Development)

  • 이한나;백희정;민세철
    • 산업식품공학
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    • 제15권4호
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    • pp.305-310
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    • 2011
  • 본 연구에서는 DSM을 이용하여 단백질 추출이나 정제없이 식품에 적용 가능성이 있는 가식성 필름을 개발하였다. HPH 처리는 표면이 매끄럽고 균일한 형태의 필름을 형성시켰고, 필름의 WVP값을 감소시켜 수분 방벽 효과를 높였다. 필름 내 글리세롤 농도 증가는 WVP값을 전반적으로 높였다. 농산물 가공 부산물인 DSM으로 제작된 가식성 필름은 새로운 식품 소재로서 상업적 적용 가능성을 보여주었다.

우럭 껍질 젤라틴 복합필름의 특성 (Characterization of Rockfish Skin Gelatin Composite Films)

  • 백송이;김혜리;송경빈
    • 한국식품영양과학회지
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    • 제46권3호
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    • pp.394-399
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    • 2017
  • 플라스틱 포장 폐기물로 인한 환경오염을 해결하기 위한 대안으로 생분해성 필름이 많이 연구되어 왔다. 본 연구에서는 우럭 껍질 젤라틴(RFG)과 nano-clay(Cloisite $Na^+$, 10A)의 복합필름의 특성에 관하여 연구하였다. 우럭 껍질로부터 젤라틴을 추출하여 sorbitol을 가소제로서 첨가한 단백질 필름을 제조하였고, 제조된 RFG 필름의 tensile strength(TS), water vapor permeability(WVP), water solubility(WS)는 각각 15.0 MPa, $2.70{\times}10^{-9}g\;m/m^2\;s\;Pa$, 53.8%였다. RFG에 nano-clay를 첨가한 복합필름은 TS가 증가하고 WVP와 WS는 감소하였다. XRD 분석과 SEM 측정 결과를 통하여 RFG/nano-clay 복합필름 내부에 박리형 구조를 형성함을 확인할 수 있었다. 결론적으로 본 연구 결과 RFG/nano-clay 복합필름은 생분해성 포장재로 적용될 수 있음을 시사한다.

수막두께와 속도를 고려한 도로포장면의 미끄럼저항 예측모델 개발 (A Development of Skid Resistance Prediction Model Considering Water Film Thickness and Vehicle Speed)

  • 조신행;이수형;유인균;김낙석
    • 대한토목학회논문집
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    • 제32권3D호
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    • pp.223-229
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    • 2012
  • 도로 포장면과 타이어 사이의 마찰 저항을 미끄럼 저항이라고 한다. 미끄럼 저항은 도로 안전에 매우 중요한 요소이며, 다양한 요인이 복합적으로 작용한다. 미끄럼 저항 측정법의 한계를 극복하기 위해 컴퓨터 모델링을 이용한 해석 수행 결과, 속도가 증가하거나 수막두께가 두꺼울수록 미끄럼 저항은 감소하였다. 해석 결과를 이용해 수막두께와 속도에 따라 수막 위를 주행하는 타이어에 발생하는 양력을 계산할 수 있으며, IFI(International Friction Index) 미끄럼 저항 예측모델과 실측 미끄럼 저항과의 차이를 줄이기 위해 양력을 반영한 수정 IFI 미끄럼 저항 예측모델을 개발하였다. 예측모델과 실측 데이터의 상관관계 분석 결과, 기존 IFI 예측모델의 $R^2$는 0.49로, 수정 IFI 예측모델의 $R^2$는 0.64로 나타나 수정 IFI 예측모델이 기존모델에 비해 예측 효과가 우수하였다. 포장면의 상태에 따른 수막두께를 수정 예측모델에 반영할 경우 더욱 정확한 예측모델을 얻을 수 있을 것이다.

수용성 흑색 착색제의 개발과 이의 응용 (The Development of Water-Soluble Black Coloring Agent and Its Application)

  • 김무길;정병호;문명준;김상수
    • 열처리공학회지
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    • 제15권5호
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    • pp.213-218
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    • 2002
  • In order to develop the economic and environmental water-soluble black coloring agent, some adequate chemical mixtures were mixed and this solution was applied to coat quenched and tempered 51B20 steel bolt. Some basic properties of the solution and characteristics of the coated film in addition to the corrosion resistance were investigated. The developed 100 kg of water-soluble black coloring agent solution was a chemical mixture consisted of 10 kg of aqueous coloring agent, 40 kg of surface active agent, 0.3 kg of anti-foam agent and $50{\ell}$ of water. The coated film of the bolt was composed of hard layer of about $2{\mu}m$ and the disbondable soft layer of about $4{\mu}m$ above the hard layer. Many surface active agents peaks and a few hydrophilic peaks were observed in the coated film. Surface roughness value of the coated bolt was lower than that of the non-coated bolt. Corrosion resistance of the coated bolt considerably improved and also relatively showed a good polarization resistance at test condition of $40^{\circ}C$ colorizing temperature and 5% the solution concentration in 3% NaCl anodic polarization test. Initial appearance time of the surface rust was greatly retarded owing to the coated film in salt spray test.