• Title/Summary/Keyword: water vapour

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Micro/Nano Adhesion and Friction Properties of SAMs with Different Head and Functional Group according to the Coating Methods (코팅 방법에 따른 이종 SAMs의 관능기별 마이크로/나노 응착 및 마찰 특성)

  • Yoon Eui-Sung;Oh Hyun-Jin;Han Hung-Gu;Kong Hosung
    • Tribology and Lubricants
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    • v.21 no.3
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    • pp.107-113
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    • 2005
  • Micro/nano adhesion and friction properties of self-assembled monolayers (SAMs) with different head- and end-group were experimentally studied according to the coating methods. Various kinds of SAM having different spacer chains (C10 and C18), head-group and end-group were deposited onto Si-wafer by dipping and chemical vapour deposition (CVD) methods under atmospheric pressure, where the deposited SAM resulted in the hydrophobic nature. The adhesion and friction properties between tip and SAM surfaces under nano scale applied load were measured using an atomic force microscope (AFM) and also those under micro scale applied load were measured using a ball-on-flat type micro-tribotester. Surface roughness and water contact angles were measured with SPM (scanning probe microscope) and contact anglemeter respectively. Results showed that water contact angles of SAMs with the end-group of fluorine show higher relatively than those of hydrogen. SAMs with the end-group of fluorine show lower nano-adhesion but higher micro/nanofriction than those with hydrogen. Water contact angles of SAMs coated by CVD method show high values compared to those by dipping method. SAMs coated by CVD method show the increase of nano-adhesion but the decrease of nano-friction. Nano-adhesion and friction mechanism of SAMs with different end-group was proposed in a view of size of fluorocarbon molecule.

Preparation of highly hydrophobic PVDF hollow fiber composite membrane with lotus leaf-like surface and its desalination properties

  • Li, Hongbin;Zi, Xingchen;Shi, Wenying;Qin, Longwei;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.287-298
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    • 2019
  • Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

Physical Properties of Lightweight and Normal Weight Concretes due to Water-Cement Ratio Changes (물-시멘트비 변화에 따른 경량콘크리트와 일반콘크리트의 물리적 성질)

  • Lee, Chang-Soo;Kim, Jae-Nam;Lim, Youn;Ma, Moon-Hak
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.4
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    • pp.11-20
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    • 2009
  • By using the artificial lightweight aggregate for the natural aggregate depletes and destruction of environment and the application of lightweight concrete in structure, the lightweight concrete is manufactured. The fundamental characteristics by the waterbinder ratio was evaluated. It is suggested the method to control of pre-absorbed water of the lightweight aggregate. Lightweight concrete with pre-absorbed aggregate has similar characteristics compared to normal weight concrete regardless of water-binder ratio. According to the water-binder ratio, the drying condition, and the rebar, the unit mass of the lightweight concrete showed the reduction of 14.6${\sim}$21.0% as the range of 1,668${\sim}$1,998 $kg/m^3$ in comparison to the normal weight concrete. The lightweight aggregate pre-absorbed water showed the deferent evaporation quantity according to the water-binder ratio. As the water-binder ratio is lower, the oven dry vapour water is larger, therefore the internal curing water is increasing. In the same water-binder, comparing the normal concrete the lightweight concrete shows lower compressive strength which is due to the different strength of an aggregate. In the air dry curing, the normal weight concrete has a lower strength improvement effect in w/c 0.3 than the ratio 0.4 and 0.5. However, the strength improvement effect has increasing as the water-binder ratio was low in the light concrete.

A Study of Emulsion Fuel of Cellulosic Biomass Oil (목본계 바이오매스오일의 에멀젼 연료화 연구)

  • Kim, Moon-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.836-847
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    • 2016
  • Water soluble oil was obtained by pyrolysis of biomass. The characteristics of emulsified fuel by mixing water soluble oil and MDO(marine diesel oil) and engine emissions were studied with engine dynamometer. Saw dust was used as biomass. Water soluble oil was obtained by condensing of water and carbon content with pyrolysis of saw dust at $500^{\circ}C$. Emulsion fuel was obtained by emulsifying MDO and water soluble oil by the water soluble oil mixing ratio of 10 to 20% of MDO. Exhaust gas detection was performed with engine dynamometer. While combustion, micro-explosion took place in the combustion chamber by water in the emulsion fuel, emulsion fuel scattered to micro particles and it caused to smoke reduction. The heat produced from water vapour reduce the temperature of internal combustion chamber and it caused to inhibition of NOx production. It can be verified by the lower exhaust temperature of each ND-13 mode using emulsion fuel than that of MDO fuel. The NOx and smoke concentration were reduced by increasing water soluble oil content in the emulsion fuel. The power also decreased according to the increment of water soluble oil content of emulsion fuel because emulsion fuel has low calorific value due to high water content than MDO. As a result of ND-13 mode test with 20% bio oil content, it was achieved 25% reduction in NOx production, 60% reduction in smoke density, and 15% reduction in power loss.

Evaluation of the Wear Comfort of Outdoorwear by Skin Wettedness Analyses (Skin Wettedness 분석을 통한 아웃도어웨어의 착용 쾌적성 평가)

  • Jeong, Jeong-Rim;Kim, Hee-Eun
    • Fashion & Textile Research Journal
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    • v.11 no.6
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    • pp.947-952
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    • 2009
  • The purpose of this study is to analyze skin wettedness($w$) used as the rate index of thermal comfort, and to evaluate the wear comfort of outdoorwear. Skin wettedness is widely used to express the degree of thermal comfort. If skin wettedness exceeds a certain threshold, the body feels damp and discomfort. An experiment which consisted of rest(30 min), exercise(30 min) and recovery(20 min) periods was administered in a climate chamber with 10 healthy male participants. Two kinds of outdoorwears made of 100% cotton fabrics (Control) and specially engineered fabrics having feature of quick sweat absorbency and high speed drying fabric (Functional) were evaluated in the experiment. The condition of climate chamber was controlled according to the thermal insulation of 4 kinds of experimental ensembles(E1~E4). Total sweat loss, sweat loss absorbed into clothing and skin temperature were measured. Skin wettedness was calculated from the ratio of evaporative rate to the maximal evaporative capacity. Skin wettedness of 'Functional' was lower than 'Control' in the 3 kinds of ensembles(E1, E2, E4) because the materials of 'Functional' were composed of quick sweat absorbency and high speed drying fabrics, water vapour permeability and waterproof fabrics.

THE EFFECT OF SURFACE METEOROLOGICAL MEASUREMENTS ON GPS HEIGHT DETERMINATION

  • Huang, Yu-Wen;Wang, Chuan-Sheng;Liou, Yuei-An;Yeh, Ta-Kang
    • Proceedings of the KSRS Conference
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    • v.2
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    • pp.748-751
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    • 2006
  • Positioning accuracy by the Global Positioning System (GPS) is of great concern in a variety of research tasks. It is limited due to error sources such as ionospheric effect, orbital uncertainty, antenna phase center variation, signal multipath, and tropospheric influence. In this study, the tropospheric influence, primarily due to water vapour inhomogeneity, on GPS positioning height is investigated. The data collected by the GPS receivers along with co-located surface meteorological instruments in 2003 are utilized. The GPS receivers are established as continuously operating reference stations by the Ministry of the Interior (MOI), Central Weather Bureau (CWB), and Industrial Technology Research Institute (ITRI) of Taiwan, and International GNSS Service (IGS). The total number of GPS receivers is 21. The surface meteorological measurements include temperature, pressure, and humidity. They are introduced to GPS data processing with 24 troposphere parameters for the station heights, which are compared with those obtained without a priori knowledge of surface meteorological measurements. The results suggest that surface meteorological measurements have an expected impact on the GPS height. The daily correction maximum with the meteorological effect may be as large as 9.3 mm for the cases of concern.

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Analysis of Charcoal from Quercus phillyraeoides (졸가시나무 탄화물 분석)

  • Shin, Soo-Jeong;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.3
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    • pp.181-186
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    • 2013
  • In this work, charcoal making characteristics of Quercus phyllyaeoides (which has been known as one of best raw materials for charcoals) was investigated. Charcoal from Quercus phyllyaeoides had more than 85% of fixed carbon, which is 5~25% higher fixed carbon content than other charcoals. Also specific gravity of this charcoal was more than 1.0, which is quite higher than other black charcoals (average of commercial products: 0.52) or white charcoals (average of commercial products: 0.73). Methylene blue adsorption, pH, and adsorption of water vapour was lower than other commercial charcoals. Carolic value of this charcoal was similar to other commercial products. Far infrared ray's emission from this charcoal was higher than others. Application of charcoal from Quercus phyllyaeoides should be consider the characteristics of this product.

NEAR-WALL GRID DEPENDENCY OF CFD SIMULATION FOR A SUBCOOLED BOILING FLOW USING WALL BOILING MODEL (벽 비등모델을 이용한 과냉비등 유동에 대한 CFD 모의계산에서 벽 인접격자의 영향)

  • In, W.K.;Shin, C.H.;Chun, T.H.
    • Journal of computational fluids engineering
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    • v.15 no.3
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    • pp.24-31
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    • 2010
  • boiling flow in vertical tube. The multiphase flow model used in this CFD analysis is the two-fluid model in which liquid(water) and gas(vapour) are considered as continuous and dispersed fluids, respectively. A wall boiling model is also used to simulate the subcooled boiling heat transfer at the heated wall boundary. The diameter and heated length of tube are 0.0154 m and 2 m, respectively. The system pressure in tube is 4.5 MPa and the inlet subcooling is 60 K. The near-wall grid size in the non-dimensional wall unit for lqiuid phase ($y^+_{w,l}$) was examined from 101 to 313 at the outlet boundary. The CFD calculations predicted the void distributions as well as the liquid and wall temperatures in tube. The predicted axial variations of the void fraction and the wall temperature are compared with the measured ones. The CFD prediction of the wall temperature is shown to slightly depend on the near-wall grid size but the axial void prediction has somewhat large dependency. The CFD prediction was found to show a better agreement with the measured one for the large near-wall grid, e.g., $y^+_{w,l}$ > 300 at the tube exit.

Improvement of Permeation of Applied Multi-layer Encapsulation of Thin Films on Ethylene Terephthalate(PET) (고분자 기판위에 다층 구조의 박막형 보호층을 적용한 투습률 향상)

  • Kim Jong-Hwan;Han Jin-Woo;Kim Young-Hwan;Seo Dae-Shik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.255-259
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    • 2006
  • In this paper, the inorganic-organic thin film encapsulation layer was newly adopted to protect the organic layer from moisture and oxygen. Using the electron beam, Sputter and Spin-Coater system, the various kinds of inorganic and organic thin-films were deposited onto the Ethylene Terephthalate(PET) and their interface properties between organic and inorganic layer were investigated. In this investigation, the SiON and Polyimide(PI) layer showed the most suitable properties. Under these conditions, the WVTR(water vapour transition rate) for PET can be reduced from level of $0.57\;g/m^2{\cdot}day$ (bare subtrate) to $1{\times}10^{-5}\;g/m^2{\cdot}day$ after application of a SiON and Polyimide layer. These results indicates that the SiON/PI/SiON/PI/PET barrier coatings have high potential for flexible organic light-emitting diode(OLED) applications.

Development of OLED Passivation Method for High efficency and life time (고효율 및 장수명의 OLED Passivation 기술 개발)

  • Han, Jin-Woo;Kim, Jong-Hwan;Kim, Young-Hwan;Seo, Dae-Shik;Kim, Yong-Hoon;Moon, Dae-Gyu;Han, Jeong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.267-268
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    • 2005
  • In this paper, the inorganic-organic thin film encapsulation layer was newly adopted to protect the organic layer from moisture and oxygen. Using the electron beam, Sputter and Spin-Coater system, the various kinds of inorganic and organic thin-films were deposited onto the Ethylene Terephthalate(PET) and their interface properties between organic and inorganic layer were investigated. In this investigation, the SiON and Polyimide(PI) layer showed the most suitable properties. Under these conditions, the WVTR(water vapour transition rate) for PET can be reduced from level of 0.57 g/$m^2$/day (bare subtrate) to $1{\times}10^{-5}$ /$m^2$/day after application of a SiON and Polyimide layer. These results indicates that the SiON/PI/SiON/PI/PET barrier coatings have high potential for flexible organic light-emitting diode(OLED) applications.

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