Conventional paints for conversion coating applications in steel production derived mainly from water-based polymer dispersions containing several additives actually show good general performance, but suffer from poor scratch and abrasion resistance during use. The reason for this is because the relatively soft organic binder matrix dominates the mechanical surface properties. In order to maintain the high quality and decorative function of coated steel sheets, the mechanical performance of the surface needs to be improved significantly. In fact the wear resistance should be enhanced without affecting the optical appearance of the coatings by using appropriate nanoparticulate additives. In this direction, nanocomposite coating compositions (Nanomer$^{(R)}$) have been derived from water-based polymer dispersions with an increasing amount of surface-modified nanoparticles in aqueous dispersion in order to monitor the effect of degree of filling with rigid nanoparticles. The surface of nanoparticles has been modified for optimum compatibility with the polymer matrix in order to achieve homogeneous nanoparticle dispersion over the matrix. This approach has been extended in such a way that a more expanded hybrid network has been condensed on the nanoparticle surface by a hydrolytic condensation reaction in addition to the quasi-monolayer type small molecular surface modification. It was expected that this additional modification will lead to more intensive cross-linking in coating systems resulting in further improved scratch-resistance compared to simple addition of nanoparticles with quasi-monolayer surface modification. The resulting compositions have been coated on zinc-galvanized steel and cured. The wear resistance and the corrosion protection of the modified coating systems have been tested in dependence on the compositional change, the type of surface modification as well as the mixing conditions with different shear forces. It has been found out that for loading levels up to 50 wt.-% nanoparticles, the mechanical wear resistance remains almost unaffected compared to the unmodified resin. In addition, the corrosion resistance remained unaffected even after $180^{\circ}$ bending test showing that the flexibility of coating was not decreased by nanoparticle addition. Electron microscopy showed that the inorganic nanoparticles do not penetrate into the organic resin droplets during the mixing process but rather formed agglomerates outside the polymer droplet phase resulting in quite moderate cross linking while curing, because of viscosity. The proposed mechanisms of composite formation and cross linking could explain the poor effect regarding improvement of mechanical wear resistance and help to set up new synthesis strategies for improved nanocomposite morphologies, which should provide increased wear resistance.
One of the most important issues for projecting future water resources and establishing climate change adaptation strategies is 'uncertainty'. In Korea, climate change research results were very heterogeneous even in a same basin, but there have been few climate change studies dealt with the uncertainty reduction. This is because emission scenarios, GCMs, downscaling, and rainfall-runoff models that were used in the previous studies were almost all different. In this research, fifty one GCM scenarios based A and B emission scenarios were downloaded and then compared with the observed values for a period from January 2001 to December 2008. The downloaded GCM scenarios in general simulated well the observed but did not simulated well the observed precipitation especially for the flood season in Korea. The accuracy of each GCM scenario was measured with the model efficiency, PDF-based, and Relative Entropy methodology. Among the selected GCM scenarios with three methodologies, the four common GCM scenarios(CGCM2.3.2(MRI-M, B1), MIROC3.2medress(NIES, B1), CGCM2.3.2(MRI-M, A2), CGCM2.3.2(MRI-M, A1B) were finally selected. Results of the four selected GCMs were heterogeneity and projected increases of precipitation for the Korean Peninsula by from 27.36% to 12.49%, respectively. It seems very risky to rely a water planning or a management policy on use of a single climate change scenario and from this research results. Therefore, the four selected GCM scenarios proposed quantitatively were considered firstly for the water supply in the dry season and the drought management strategy in the Korean Peninsula for the future.
Journal of the Korean Society for Marine Environment & Energy
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v.11
no.1
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pp.55-62
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2008
This study investigated the status and problems of marine-related environmental impact assessment and a utilization-consultation system in Korea and suggested improvement of the review organization. Also, it conducted SWOT analysis based on evaluation of functions, roles and performance of the marine environmental impact assessment center and proposed development strategies of the center through introduction of expert opinions and advanced systems. The performance statement-review by the center in 2007 included 358 cases in total; 165 (46.1%) for consultation on utilization of sea area, 104 for environmental impact assessment (29.0%), and 89 (24.9%) for prior environmental review. The consultation on utilization of sea area can be divided into that for public water surface-use (41%) and reclamation (32%), and sea aggregate extraction process (21%). Although bad impacts on marine environment are reducing under the current system, there are some limits and problems to supplement it in terms of content, system and operation. Review system on sea area utilization-impact(marine environmental impact assessment center) by marine environmental management law needs to obtain expertise, fairness and efficiency and, to do so, have operational supports and institutional improvement to maximize its own functions and roles. At the same time, it is necessary for the center to establish identity and the status as a professional review organization by setting active development strategies inside the center. Finally, it should strengthen an consultation system of marine environmental impact assessment led by the related ministry to achieve effective coastal management.
Many organic solvent-tolerant bacteria have been isolated from all environments such as soil, waste-water, even deep sea after first isolation report of organic solvent-tolerant bacterium. Most organic solvent- tolerant isolates have been determined to be Gram-negative bacteria, because Gram-negative bacteria have inherent tolerance property toward hostile organic solvents more than Gram-positive bacteria. The mechanisms of organic solvent tolerance have been elucidated extensively using mainly organic solvent-tolerant Gram-negative bacteria. The solvent-tolerance mechanisms in Gram-positive bacteria can be found in comparatively recent research. Organic solvents exhibited different toxicity depending on the solvent, and the tolerance levels of organic solvent-tolerant bacteria toward organic solvents were also highly changeable among species and strains. Therefore, organic solvent-tolerant bacteria could coped with solvent toxicity and adapted to solvent stress through the multifactorial and multigenic adaptative strategies. They could be survived even in the hyper concentrations of organic solvents by mechanisms which include: changes in cell morphology and cell behaviour, cell surface modifications, cell membrane adaptations, solvent excretion pumps, chaperones and anti-oxidative response. The aim of this work is to review the representative solvent tolerant bacteria and the adaptative and tolerance strategies toward organic solvents in organic solvent-tolerant bacteria, and their potential industrial and environmental impact.
Journal of the Korean Society of Environmental Restoration Technology
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v.22
no.5
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pp.27-43
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2019
This study applied the LANDIS-II model to the forest vegetation of the study area in Yeongdong-gun, Korea to identify climate effects on ecosystems of forest vegetation. The main purpose of the study is to examine the long-term changes in forest aboveground biomass(AGB) under three different climate change scenarios; The baseline climate scenario is to maintain the current climate condition; the RCP 4.5 scenario is a stabilization scenario to employ of technologies and strategies for reducing greenhouse gas emissions; the RCP 8.5 scenario is increasing greenhouse gas emissions over time representative with 936ppm of $CO_2$ concentration by 2100. The vegetation survey and tree-ring analysis were conducted to work out the initial vegetation maps and data for operation of the LANDIS model. Six types of forest vegetation communities were found including Quercus mongolica - Pinus densiflora community, Quercus mongolica community, Pinus densiflora community, Quercus variabilis-Quercus acutissima community, Larix leptolepis afforestation and Pinus koraiensis afforestation. As for changes in total AGB under three climate change scenarios, it was found that RCP 4.5 scenario featured the highest rate of increase in AGB whereas RCP 8.5 scenario yielded the lowest rate of increase. These results suggest that moderately elevated temperatures and $CO_2$ concentrations helped the biomass flourish as photosynthesis and water use efficiency increased, but huge increase in temperature ($above+4.0^{\circ}C$) has resulted in the increased respiration with increasing temperature. Consequently, Species productivity(Biomass) of trees decrease as the temperature is elevated drastically. It has been confirmed that the dominant species in all scenarios was Quercus mongolica. Like the trends shown in the changes of total AGB, it revealed the biggest increase in the AGB of Quercus mongolica under the RCP 4.5 scenario. AGB of Quercus mongolica and Quercus variabilis decreased in the RCP 4.5 and RCP 8.5 scenarios after 2050 but have much higher growth rates of the AGB starting from 2050 under the baseline scenario. Under all scenarios, the AGB of coniferous species was eventually perished in 2100. In particular they were extinguished in early stages of the RCP 4.5 and RCP 8.5 scenarios. This is because of natural selection of communities by successions and the failure to adapt to climate change. The results of the study could be expected to be effectively utilized to predict changes of the forest ecosystems due to climate change and to be used as basic data for establishing strategies for adaptation climate changes and the management plans for forest vegetation restoration in ecological restoration fields.
Junseop Oh;Jaehoon Choi;Hyunsoo Seo;Ho-Rim Kim;Hyun Tai Ahn;Seong-Taek Yun
Economic and Environmental Geology
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v.57
no.2
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pp.271-280
/
2024
This study examines the European Union (EU)'s policies on managing nitrate contamination in groundwater and provides implications for the future groundwater management in South Korea. Initiated by the 1991 Nitrate Directive, the EU has pursued a multifaceted approach to reduce agricultural nitrate pollution through sustainable ('good') farming practices, regular nitrate level monitoring, and designating Nitrate Vulnerable Zones. Further policy integrations, like the Water Framework Directive and Groundwater Directive, have established comprehensive protection strategies, including the use of pollutant threshold values. Recently, the 2019 Green Deal escalated efforts against nitrates, aligning with broader environmental and climate objectives. This review aims to explore these developments, highlighting key mitigation strategies against nitrate pollution, and providing valuable insights for the future sustainable groundwater nitrate management in South Korea, emphasizing the importance of preventive measures and collaborative efforts to restore and improve groundwater quality.
Kim, Pil-Geun;Park, Maeng-Eon;Lee, In-Won;Chun, Ho-Hwan;Park, Hyun
Journal of the Korean Society of Marine Environment & Safety
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v.16
no.4
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pp.361-367
/
2010
The use of antifouling(AF) paints is the effective method for the protection of underwater structures from the development of marine fouling organisms. The ban on harmful substances in antifouling paints requires the development of new antifouling strategies although Tributyitin (TBT) compound had been used extensively as an active ingredient Alternatives should be as effective as conventional paints but have lower toxicity. In the present study, a TBT-free self-polishing (Cu SPC) AF paint containing $Cu_2O$, a Cu free SPC AF paint, and a Foul-release silicone AF paint, which were commercially available, were examined to investigate environmental erects of leakage waters employing Sebastes shlegeli and Artemia. Survival rates were inversely proportional to the concentration of leakage waters from AF paints and the acute toxicity of SPC AF paints was relatively higher than that of foul release AF paints.
This paper analyzes optimal watershed management focusing on reservoir-level sediment removal techniques. Although dams and reservoirs provide several benefits, sedimentation may reduce their storage capacity. As of today, the Aswan High Dam (AHD) in Egypt faces approximately 76% reduced life of the reservoir. Since the AHD is the major fresh water source in Egypt, sustainable use of this resource is extremely important. A model is developed to simultaneously determine optimal sediment removal strategies for upstream soil conservation efforts and reservoir-level sediment control. Two sediment removal techniques are considered: mechanical dredging and hydro-suction sediment removal system (HSRS). Moreover, different levels of upstream soil conservation efforts have introduced to control soil erosion, which is a major contributor of reservoir storage capacity reduction. We compare a baseline case, which implies no management alternative, to non-cooperative and social planners' solution. Our empirical results indicate that the socially optimal sediment removal technique is a mechanical dredging with unconstrained amount with providing a sustainable life of the reservoir. From the empirical results, we find that social welfare can be as high as $151.01 billion, and is sensitive to interest rates and agricultural soil loss.
Purpose: We accessed epidemioloy of 908 acute burns (7 years) in the military, of injuries and propose proper educational programs to suit community. Methods: We surveyed burn demographics, circumstances of injuries, size, result of treatment. Results: The mean age was 20.6 years. The flame burns (FB) (325, 35.8%) were most common, followed scald (SB) (305, 33.6%), contact (CB) (219, 24.1%), electric (EB) (45, 5.0%) and chemical burns (ChB) (14, 1.5%). The more occurred during winter (29.7%). SB had mean 3.9% total body surface area (TBSA). The 251 (82.3%) had superficial burns by spillage of hot water/food on lower limbs (45.6%), feet (33.8%) in summer (34.8%), treated with simple dressing (92.8%). Morbidity rate was 5.6%; post traumatic stress disease (PTSD) (0.7%). FB had large wound (9.3% TBSA). The 209 (64.3%) had superficial burns by ignition to flammable oils (31.7%) and bomb powders (29.2%) on head/neck (60.3%), hands (58.6%) in summer (31.7%), autumn (30.2%). They underwent simple dressing (83.4%) and skin graft (16.0%). Morbidity rate was 18.8%; PTSD (10.5%), inhalation injuries (4.0%), corneal injury (3.7%), amputations (0.9%), and mortality rate (1.2%). CB had small (1.1% TBSA), deep burns (78.5%) by hotpack (80.4%) on lower limbs (80.4%). The more (59.8%) underwent skin graft. EB had 6.8% TBSA. The 29 (64.4%) had superficial burns by touching to high tension cable (71.1%) on hand (71.1%), upper limbs (24.4%) in autumn (46.8%). They underwent simple dressing (71.1%) and skin graft (24.4%). They showed high morbidity rate (40.0%); loss of consciousness (13.3%), nerve injuries (11.1%), neuropathy (8.9%), amputations (2.2%), and mortality rate (2.2%). Conclusions: The cook should wear apron over the boots during work. The lighter or smoking should be strictly prohibited during work with flammable liquids or bomb powders. Don't directly apply hotpack to skin for a long time. Use insulating glove during electric work. Keep to the basic can prevent severe injury and proper education is important.
Proceedings of the Korean Reliability Society Conference
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2000.04a
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pp.239-246
/
2000
This paper presents a new dynamic approach for assessing feasibility associated with the implementation of accident management strategies by the operators. This approach includes the combined use of both the concept of reliability physics and a dynamic event tree generation scheme. The reliability physics is based on the concept of a comparison between two competing variables, i.e., the requirement and the achievement parameter, while the dynamic event tree generation scheme on the continuous generation of the possible event sequences at every branch point up to the desired solution. This approach is applied to a cavity flooding strategy in a reference plant, which is to supply water into the reactor cavity using emergency fire systems in the station blackout sequence. The MAAP code and Latin Hypercube sampling technique are used to determine the uncertainty of the requirement parameter. It has been demonstrated that this combined methodology may contribute to assessing the success likelihood of the operator actions required during accidents and therefore to developing the accident management procedures.
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