• 제목/요약/키워드: water swelling

검색결과 814건 처리시간 0.03초

CHEMICAL COMPATIBILITY OF SOIL-BENTONITE CUT-OFF WALL FOR IN-SITU GEOENVIRONMENTAL CONTAINMENT

  • Inui, Toru;Takai, Atsushi;Katsumi, Takeshi;Kamon, Masashi;Araki, Susumu
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 추계 학술발표회 3차
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    • pp.135-139
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    • 2010
  • A construction technique to install the soil-bentonite (SB) cut-off wall for in-situ geoenvironmental containment by employing the trench cutting and re-mixing deep wall method is first presented in this paper. The laboratory test results on the hydraulic barrier performance of SB in relation to the chemical compatibility are then discussed. Hydraulic conductivity tests using flexible-wall permeameters as well as swell tests were conducted for SB specimens exposed to various types and concentrations of chemicals (calcium chloride, heavy fuel oil, ethanol, and/or seawater) in the permeant and/or in the pore water of original soil. For the SB specimens in which the pore water of original soil did not contain such chemicals and thus the sufficient bentonite hydration occurred, k values were not significantly increased even when permeated with the relatively aggressive chemical solutions such as 1.0 mol/L $CaCl_2$ or 50%-concentration ethanol solution. In contrast, the SB specimens containing $CaCl_2$ in the pore water had the higher k values. The excellent linear correlation between log k and swelling pressure implies that the swelling pressure can be a good indicator for the hydraulic barrier performance of the SB.

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Synthetic Hydrotalcite가 클로로프렌 고무 발포체의 내염수성에 미치는 영향 연구 (Effect of Synthetic Hydrotalcite on Salt Water Resistance of Chloroprene rubber Foam)

  • 박은영;서은호;임성욱
    • 한국염색가공학회지
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    • 제31권3호
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    • pp.177-186
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    • 2019
  • In this study, we investigated for synthetic hydrotalcite in chloroprene rubber foam. Experiments were carried out to find the optimum content ratio by controlling the contents of MgO and Hydrotalcite. Swelling test in toluene immersion was made to measure the crosslinking density of CR foams, and the cure properties were investigated with flat die rheometer and Mooney viscosity. The difference of hardness, tensile strength and elongation at break were observed after immersing in 7% NaCl or 21% NaCl solutions for a day and four days. In addition, the volume change and water content remaining in CR foam were measured after immersing NaCl solution. As content of MgO increased, the value of the cure torque tended to increase, but it was almost constant above 2phr of MgO. However, the Mooney viscosity decreased with increasing MgO content. The crosslinking density, determined by the swelling ratio, showed that the CR compound without MgO showed a higher degree of swelling. When the content of hydrotalcite/MgO was 3:2, it was the lowest volume change of CR form. Also, As the content of hydrotalcite decreased, the difference of mechanical properties before and after immersion NaCl solution increased.

국산 압축벤토나이트 완충재의 온도에 따른 팽윤압 특성 연구 (Temperature Effect on the Swelling Pressure of a Domestic Compacted Bentonite Buffer)

  • 이지현;이민수;최희주;최종원
    • 방사성폐기물학회지
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    • 제8권3호
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    • pp.207-213
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    • 2010
  • 국산 칼슘 벤토나이트를 대상으로 온도가 팽윤압에 미치는 영향을 관찰하였다. 벤토나이트를 건조밀도 1.6 g/$cm^3$으로 압축하고, 0.69 MPa의 일정한 수압으로 증류수를 공급하여 팽윤압을 측정하였다. 온도 영향 실험은 $25^{\circ}C$, $30^{\circ}C$, $40^{\circ}C$, $50^{\circ}C$, $60^{\circ}C$, $70^{\circ}C$, respectively. The Ca-bentonite showed a sufficiently high swelling pressure of 5.3 MPa에서 승온조건과 감온조건으로 수행하였다. 압축 벤토나이트가 물과 접촉하여 상온에서 5.3 MPa의 충분히 높은 팽윤압이 작용하는 것을 실험적으로 확인하였다. 팽윤압은 온도가 높을수록 감소하는 것으로 나타났다. 승온조건과 감온조건에서의 온도에 따른 팽윤압 거동에 차이를 보이며, 승온조건에서 온도에 따른 변화가 심하게 나타났다. 향후 온도 조건 외에 벤토나이트의 압축밀도 변화, 지하수 조성에 따라 팽윤압 특성이 어떻게 변화하는지에 대해 평가한다면, 앞으로 국내 고준위 폐기물 처분장의 개념 설계에 유용하게 활용될 수 있을 것으로 본다.

Ellipsometry를 이용한 193 nm photoresist에서의 물의 흡수 연구 (An Ellipsometry Study of Water Absorption in the 193 nm photoresist)

  • 이형주;이정환;서주빈;경재선;안일신
    • 반도체디스플레이기술학회지
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    • 제5권2호
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    • pp.37-39
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    • 2006
  • We employed in-situ spectroscopic ellipsometry(SE) and imaging ellipsometry(IE) to study the interaction of water and photoresist(PR) in 193 immersion lithography. Real time measurement of SE showed thickness increase when PR was immerged in water indicating swelling effect. From the temporal evolution we could observe its reaction-limited behavior. Meanwhile, IE could identify the modification of PR surface by contact of water even for a short period of a second.

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Pervaporation Separation of Water-Acetic Acid Mixtures Through Poly(vinyl alcohol) Membranes Crosslinked with Glutaraldehyde

  • Yeom, Choong-Kyun;Lee, Kew-Ho
    • 한국막학회:학술대회논문집
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    • 한국막학회 1994년도 추계 총회 및 학술발표회
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    • pp.32-33
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    • 1994
  • Poly(vinyl alcohol)(PVA) membranes crosslinked with Glutaraldehyde (GA) were prepared for the separation of acetic acid-water mixtures. For the preparation of the crosslinked membranes, dry PVA films were immersed for 2 days at 40$\circ$C in reaction solutions which contain different content of GA solution(25% GA in water), aceton and a catalyst, HCl. IR spectroscopy was employed to characterize the crosslinking reaction between hydroxyl groups in PVA and aldehyde groups in GA. Swelling measurements of the crosslinked membranes were carried out in both water and acetic acid to investigate the crosslinking density and swelling behaviour of the membranes.

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Improvement of Dimensional Stability of Acacia mangium Wood by Heat Treatment: A Case Study of Vietnam

  • Tran, Van Chu
    • Journal of Forest and Environmental Science
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    • 제29권2호
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    • pp.109-115
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    • 2013
  • Fast-grown wood generally contains a high proportion of juvenile wood that results in inferior dimensional stability and durability against biological deteriorations. In the present research, the Acacia mangium wood from plantation forests in Vietnam was treated with high temperature in air. The effects of heat treatment on physical properties of Acacia mangium wood, including mass loss (ML), water absorption (WA), water-repellent effectiveness (WRE) and anti-swelling efficiency (ASE) were examined. The results showed that the dimensional stability and the water-repellent effectiveness are increased by about 15-46% and 8-18%, respectively. However, the mass and dimension of wood are decreased. The results also indicated that both treatment temperature and treatment duration significantly affect the wood properties of Acacia mangium. It is thus concluded that heat treatment demonstrates an interesting potential to improve the wood quality of Acacia mangium for solid timber products. This technology provides an environmentally safe method of protecting sustainable common woods to give a new generation of value-added biomaterials with increased stability without the use of toxic chemicals.

Physical and Mechanical Properties of Sawdust Board Made of Thinning Logs (II) - The Effect of Density and Additive Quantity of Powder Phenolic Resin -

  • Oh, Seung-Won
    • Journal of the Korean Wood Science and Technology
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    • 제31권3호
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    • pp.17-23
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    • 2003
  • As a fundamental study of developing sawdust board from thinning softwood logs from three species (Pinus densiflora S. et Z., Larix leptolepis G. and Pinus koraiensis S. et Z.), this study examined the effect of board density and resin content on physical and mechanical properties of sawdust board. As the board density increase, thickness swelling, bending strength, and Brinell hardness increased while water absorption decreased. With increasing the resin content, the bending strength and hardness increased while water absorption and thickness swelling decreased. The board made of L. leptolepis was slightly low in its water absorption, and the one made of P. koraiensis was a little high in its bending strength, while there was no definite difference between each kind of trees in their hardness values.

미고결된 이암층의 Swelling 방지 그라우팅에 대한 연구 (A Study on the Grouting Using a Anti-Swelling of mud stone)

  • 천병식;정경식;도종남;이중재;김창근;김종호
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2006년도 춘계 학술발표회 논문집
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    • pp.1204-1209
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    • 2006
  • Grouting operate to reinforce expanded clay ground. Cement grouting is one of the most frequently used techniques for underground construction. This work is going to use to add an electrolytic ion to boring water for expanded reduction. To construct underground structures on expanded clay ground is operated pre-grouting that it is the barrier wall previous excavation to prevent an accident. Grouting for early compressive strength development is made a type of suspension. That grouting aims to prevent the swelling magnification in length of time. From now on, grouting is became a type of higher strength suspension to develop early compressive strength.

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생체고분자의 팽윤현상연구를 위한 핵자기공명 현미영상법의 응용 (Application of NMR Microscopy for the Study of the Swelling Effect in Biopolymers)

  • 이동훈;김승수
    • 대한의용생체공학회:의공학회지
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    • 제18권2호
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    • pp.167-172
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    • 1997
  • Novel measurement method has been performed for the noninvasive study of the swelling effect detected in hydrophilic polymers using Magnetic Resonance Microscopy. iN NMR images were acquired to measure geometric changes due to the swelling effect occurred in the polymer specimens. In addition to the geometric changes, the water ingress process was visualized noninvgsively. The measurement method performed .in the present study utilized some of NMR's valuable properties, both noninvasiveness and parameter selectivity. It is believed that the method used in the present study may be applicable to the study of biopolymers in which noninvasiveness is particularly important.

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가교된 폴리 알킬렌 옥사이드 하이드로겔의 약물방출 특성 (Drug Release Characteristics of Crosslinked Poly(alkylene oxide) Hydrogels)

  • 김신정;이승진
    • Journal of Pharmaceutical Investigation
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    • 제21권2호
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    • pp.91-95
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    • 1991
  • Polyethylene glycol, polypropylene glycol and block copolymer of ethylene glycol and propylene glycol were crosslinked by triisocyanate to form water swellable, rubbery polymer. The equilibrium swelling of the hydrogels ranged from 3% to 60% according to the hydrophobic-hydrophilic properties of the prepolymers. Model drugs, sodium salicylate and prednisolone were incorporated in the polymer matrices by swelling loading. Physical properties of the drugs affected the drug release mechanisms due to the change in the swelling behaviors of the polymeric devices. Zero order release was observed in the case of relatively hydrophobic polymer matrices.

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