• Title/Summary/Keyword: water stable isotope

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Characteristics of Distribution and Potential Route of Contaminants at Waste Disposal Site (폐기물매립지 주변의 오염물질 분포 및 이동 특성)

  • 박성원;황세호;이평구;박인화;신성천;이상규
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.144-148
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    • 2001
  • A geophysical and geochemical study was performed to verify the depth of landfill as well as the horizontal/vertical distribution of leachate at the landfill site located in Gongju. The electrical resistivity, with dipole-dipole array and dipole spacing of 5m, was applied along the nine survey lines and electromagnetic induction survey was conducted along the perimeter traverse surrounding the landfill. Cations, anions and stable isotope ($\delta$D and $\delta$$^{18}$ O) analyses were performed on about 63 water and leachate samples collected in dry and rainy seasons at 31 sites. The result of electromagnetic induction survey make it possible to derive the potential route of leachate in the past or present. The imaging of processed resistivity field data show that the possible route of leachate doesn't exist except the survey line 7. The weak zone traversing the landfill, however, is revealed by the electrical resistivity imaging, which may be the potential route of leachate toward the deep ground. The geochemical data agree well with geophysical data for deducing possible route of leachate of the site.

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Assessment of Organic Matter Sources in the Singil Stream Flowing into Lake Shihwa, South Korea

  • Kim, Dahae;Kim, Jung-Hyun;Kang, Sujin;Kim, Min-Seob;Shin, Kyung-Hoon
    • Korean Journal of Ecology and Environment
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    • v.53 no.2
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    • pp.138-147
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    • 2020
  • The Singil Stream, flowing into an artificial lake, Lake Shihwa (South Korea), experiences a strong anthropogenic pressure with continuous organic matter (OM) inputs from rural, urban, and industrial areas. In this study, we investigated suspended particulate matter (SPM) and streambed sediments collected along the Singil Stream in 2014 and 2016, by applying a dual element approach (δ13C and δ15N) to identify OM sources. The SPM and streambed sediment samples from the indusrial area showed higher organic carbon and nitrogen concentrations (or contents) than those from the other areas, with distinctively lower δ15N values. Accordingly, our dual element approach indicates that the industrial area was the predominant OM source influencing OM quality and thus water quality of the Singil Stream flowing into Lake Shihwa during the study periods. However, further studies are necessary to better constrain OM sources in the Singil Stream since OM sources from the industrial area appear to be complex.

Spatial and Temporal Variations of δ13C and C/N in Suspended Particulate Organic Matter in the Gangneung Namdae Stream, Korea (강릉 남대천 부유입자유기물의 탄소안정동위원소 비와 C/N 비의 시·공간 변동)

  • Kwak, Jung Hyun;Park, Hyun Je
    • Journal of Environmental Science International
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    • v.29 no.5
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    • pp.531-539
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    • 2020
  • To understand the composition, quantity, and quality of Suspended Particulate Organic Matter (SPOM) in the Gangneung Namdae Stream, Korea, we examined spatiotemporal variations in water temperature, salinity, chlorophlly a (Chl a), Particulate Organic Carbon (POC) and nitrogen (PON), and carbon stable isotope (δ13C) of SPOM at six stations in June (pre-monsoon), July (monsoon), and September (post-monsoon) 2017. With increasing precipitation, the average POC and C/N values increased significantly in July than in June. In September, the values decreased with decreasing precipitation. The δ13C values showed irregular spatiotemporal fluctuations among the stations and periods, thereby suggesting a greater contribution of autochthonous organic matter to the pool of SPOM than that of allochthonous organic matter derived from upstream. In addition, the large and irregular changes in POC, C/N ratio, C:Chl a, and δ13C compared to that of PON were observed for all periods among the stations, indicating a serial discontinuity of the stream. Our results suggest that the Gangneung Namdae Stream is significantly influenced by the increase in freshwater discharge caused by heavy rainfalls during the summer monsoon and post-monsoon periods.

Improvement of Oxygen Isotope Analysis in Seawater samples with Stable Isotope Mass Spectrometer (질량분석기를 이용한 해수 중 산소안정동위원소 분석법의 개선)

  • Park, Mi-Kyung;Kang, Dong-Jin;Kim, Kyung-Ryul
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.4
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    • pp.348-353
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    • 2008
  • Oxygen isotope has not been used actively in water mass studies because of difficulties on the analysis though it has advantages as a water mass tracer. The most popular method to analysis the oxygen isotope ratio in water samples is equilibration method: isotopic equilibrium of water with $CO_2$ at constant temperature. The precision of oxygen isotope analysis using commercial automatic $H_2O/CO_2$ equilibrator is ${\pm}0.1%o$. This value is not sufficient for studies in open ocean. The object of this study is to improve the analytical precision enough to apply open ocean studies by modification of the instrument. When sample gas is transferred by the pressure difference, the fractionation which is preferential transportation of light isotope can be occurred since the long transportation path between the equilibrator and mass spectrometer. And the The biggest source of error during the analysis is long distance and large volume of the pathway of sample gas between. Therefore, liquid nitrogen trap and high vacuum system are introduced to the system. The precisions of 14 time analysis of same seawater sample are ${\pm}0.081%o$ and ${\pm}0.021%o$ by built-in system and by modified system in this study, respectively.

Stable Isotope Ratio Analysis for Tracing thee Major Pollution Source in Agricultural Watersheds (농촌하천 유역의 주 오염원 추적을 위한 안정성 동위원소 질량비 분석)

  • 홍영진;김철성;권순국
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.777-782
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    • 1999
  • It has been acknowledged that fertilizer and animal waste have different ratio of \ulcornerN/\ulcornerN which is presented as a symbol of $\delta$\ulcornerN, and that the values of $\delta$\ulcornerN for fertilizer and animal waste are placed less than +8 $\textperthousand$ and higher than +10$\textperthousand$, respectively. By this reason, the demarcation range for the source nitrogen mass ratio is between +8$\textperthousand$ and +10$\textperthousand$. In this study, we would suggest a possible method to trace the major pollution basis using the nitrogen isotope analysis method for management of water quality.

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Long term activity measurement of the primary circuit water on the LVR-15 research reactor

  • Ladislav Viererbl;Vit Klupak;Hana Assmann Vratislavska
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1250-1253
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    • 2024
  • Activity measurement of the primary circuit water of fission reactors is one method that can provide early detection of a damaged fuel assembly in the reactor core. This is an important aspect in the safe operation of the reactor and for radiation protection of staff. Radionuclides in the primary circuit water are produced by the activation of stable nuclides and the fission of fissile nuclides, mainly the isotope 235U. In the LVR-15 research reactor, measurement of the activity of the primary circuit water has been regularly undertaken since 1996. A water sample is taken from the primary circuit every week and the activities are measured four days later using gamma spectrometry. The results of these long-term measurements from 1996 to 2022 are presented. The activity time dependences of the individual radionuclides are discussed in relation to fuel assembly damage and for events connected to contamination of the water by objects inserted into the primary circuit during experiments carried out near the reactor core.

Stable Isotope and Fluid Inclusion Studies of the Manjang Copper Mine, South Korea (만장동광산(萬藏銅鑛山)에 대(對)한 유체포유물(流體包有物) 및 안정동위원소분석(安定同位元素分析) 연구(硏究))

  • Kim, Kyu Han;Shin, Jeung Sook
    • Economic and Environmental Geology
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    • v.20 no.3
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    • pp.169-177
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    • 1987
  • The Manjang copper magnetite-fluorite orebodies are imbedded within the limestone beds of the Hwajonri Formation. The ore deposits are characterized by magnetite-fluorite bearing skarn orebody in the west orebody and copper sulfide veins of the central and main orebodies. This study includes fluid inclusion geothermometry, salinity analysis, stable isotope analysis, and application of phase rule to mineral associations in skarn ore. Ore minerals are closely associated with the skarn silicates such as garnet, wollastonite and epidote. Magnetite and fluorite are remarkable in the west orebody whereas chalcopyrite is dominate in the central and main orebodies where pyrite and pyrrhotite also appear as sulfide gangues. Homogenization temperature and salinity of fluid inclusions are measured ranging between $240^{\circ}C$ and $350^{\circ}C$, 6.3~12.9 wt. percent in quartz and $220^{\circ}C$ and $350^{\circ}C$, 8.5~9.9wt. percent in fluorite, respectively. This indicates that the filling temperature and salinity are higher in quartz than in fluorite with the tendency of both to be linearly decreased suggesting an attribution of meteoric water to the mineralization. $T-fo_2$ diagram in the Ca-Fe-Si system at 1 kb and $Xco_2$=0.02 shows that the mineral assemblages with decreasing temperature are andradite-hedenbergite-calcite, hedenbergite-andradite-quartz, magnetite-andradite-quartz, and magnetite-quartz-calcite, indicating that magnetite crystallizes mostly late skarn stage at lower temperature. According to the carbon and oxygen isotopic values of the host limestone and calcite in ores, the sourec of carbon might be mixture of host limestone and deep seated carbons. Sulfur isotope data imply that ore fluids be relatively homogeneous in sulfur isotopic composition, mainly derived from igneous source.

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Application of Stable Isotopic Niche Space to Large River Monitoring: Analysis of Benthic Macroinvertebrates of the Seongchon Wier (안정동위원소비를 활용한 생태지위면적 분석의 수생태계 평가 가능성 분석: 영산강 승촌보의 저서성 대형무척추동물을 대상으로)

  • Seo, Dong-Hwan;Oh, Hye-Ji;Jin, Mei-Yan;Oda, Yusuke;Kim, Hyun-Woo;Jang, Min-Ho;Choi, Bohyung;Shin, Kyung-Hoon;Lee, Kyung-Lak;Lee, Su-Woong;Chang, Kwang-Hyeon
    • Journal of Environmental Impact Assessment
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    • v.27 no.6
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    • pp.685-694
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    • 2018
  • We measured ecological niche space (ENS) using carbon and nitrogen stable isotope ratios of benthic macroinvertebrates to estimate its applicability for large river assessment. In particular, we compared ENSs of selected macroinvertebrates between upper and lower area of Seungchon Weir in Yeongsan River to estimate the impact of weir on biological community. We also measured basic water quality and community indices including benthic macroinvertebrates index (BMI) to estimate their correlations with calculated ENS. ENS was calculated using the Bayesian Stable Isotope in R statistics (package "SIBER"). The results showed that seasonal variations in water quality and community indices were found, but there was no apparent tendency between upper and lower area of the Seungchon Weir in June (before rainy season) and August (after rainy season). However, ENS of benthic macroinvertebrates markedly decreased across the weir in both June and August regardless of changes in water quality. This means the physical change of the stream due to the weir cause decrease of ecological isotopic niche space of benthic macroinvertebrates regardless of water quality, suggesting physical modification by the weir can affect the interaction between habitat condition and macroinvertebrates. Therefore, the ecological isotopic niche space can be a useful supplementary indicator for the river ecosystem assessment.

Genesis of the Ogcheon Gold-silver Deposit in Republic of Korea: Ore Minerals, Fluid Inclusion and Stable Isotope Studies (옥천 금-은광상의 생성환경: 광석광물, 유체포유물 및 안정동위원소 연구)

  • Yoo, Bong Chul
    • Economic and Environmental Geology
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    • v.46 no.2
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    • pp.153-163
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    • 2013
  • The Ogcheon Au-Ag deposit consists of two quartz veins that fill the NE or NW-trending fissures in the metasedimentary rocks of unknown age. The quartz veins occur mainly in the massive type with partially breccia and cavity. They can be found along the strike for about minimum 50 m and varied in thickness from 0.1 to 0.3 m. The mineralogy of quartz veins from the Ogcheon deposit is mainly composed of hydrothermal alteration minerals such as pyrite, quartz, sericite, chlorite, clay minerals and sulfides including pyrite, pyrrhotite, arsenopyrite, sphalerite, chalcopyrite and galena. Fluid inclusion data from quartz indicate that homogenization temperatures and salinity of mineralization range from 184 to $362^{\circ}C$ and from 0.0 to 6.6 wt.% eq. NaCl, respectively. These suggest that ore forming fluids were progressively cooled and diluted from mixing with meteoric water. Sulfur(${\delta}^{34}S$: 0.4~8.4‰) isotope composition indicates that ore sulfur was derived from mainly magmatic source although there is a partial derivation from the host rocks. The calculated oxygen(${\delta}^{18}O$: 4.9~12.1‰) and hydrogen(${\delta}D$: -92~-74‰) isotope compositions suggest that magmatic and meteoric ore fluids were equally important for the formation of the Ogcheon deposit and then overlapped to some degree with another type of meteoric water during mineralization.

Preliminary Study on the Paleoenvironment Reconstruction using a Bivalve from Sangmori Shell Mound (상모리패총에서 산출되는 이매패류 패각을 이용한 고환경 복원 예비연구)

  • Kim, Jeong-Suk;Woo, Kyung-Sik;Hong, Wan;Kang, Chang-Hwa
    • The Korean Journal of Quaternary Research
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    • v.24 no.2
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    • pp.35-48
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    • 2010
  • The purpose of this study is to investigate paleoenvironmental conditions of the shallow sea around Jeju Island during the Late Holocene using geochemical contents of the bivalve (Glycymeris albolineata) collected from the Sangmori Shell Mound. The bivalve shell used shows the archaeological age of 2,300 yr BP. Stable carbon and oxygen isotope compositions show that growth rates decreased with aging. Coeval trends of both isotope compositions can be observed: heavier values during winters and lighter values summers except for their young and old growth stages. The seasonality of bivalve shell appear to reflect seasonal variations of paleotemperature as well as paleosalinity. Especially China Coastal Water with low salinity was transported into the southern Jeju Strait from Changjiang River during summer periods. Heavier carbon isotope values during winter indicate higher productivity, and this is supported by high density of phytoplanktons and higher chlorophyll contents during winter time. For accurate interpretation, monitoring of present-day conditions of shallow marine water as well as additional geochemical analysis of the same Recent bivalve may be necessary.

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