• Title/Summary/Keyword: water repellent

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The Effects of the Content of Hydroxyethyl Methacrylate in Fluorine-containing Acrylate Copolymers on Physical Properties (불소함유 아크릴계공중합체에서 히드록시에틸메타크릴레이트 함량에 따른 물리적 특성 변화)

  • Kim, KiSang;Shim, Sang-Yeon
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.2
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    • pp.502-508
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    • 2018
  • The acrylate copolymer having good coating, water-repellent and adhesion properties was designed and prepared. We prepared copolymers with high yield of > 95% using methyl methacrylate(MMA), 2,2,2-trifluoroethyl acrylate (FMA) and 2-hydroxyethyl methacrylate monomers(HEMA) by either bulk or emulsion polymerization techniques. The $^1H-NMR$ spectrum was used to identify chemical structure and DSC and DMA analysis were conducted. As a result, the glass transition temperature decreased by $3^{\circ}C$ as FMA content increased from 5% to 10%, and decreased by $2{\sim}8^{\circ}C$ when HEMA content increased from 5 % to 10 %. The physical properties were measured using Instron and TGA. As FMA or HEMA content increased by 10%, tensile strength decreased from 29 MPa to 22 MPa and Td decreased from $200^{\circ}C$ to $180^{\circ}C$ in both bulk and emulsion. The contact angle relatively decreased as hydrophilic HEMA content increased.

Study on Application of Urethane Materials for Hardening of Metal Artifacts (금속유물 강화처리를 위한 우레탄 수지의 적용성 연구)

  • Lee, Ho-Yeon;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.415-420
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    • 2011
  • Urethane coating agent was made up in order to prevent corrosion on metal relics. This urethane coating agent was designed to solve problems linked to gloss and discoloration caused by existing acrylic coating agent which is mainly applied to metal relics. For the purpose, the urethane coating agent was made up which has lower gloss and slight color change. This coating agent formed thinner coating layer with excellent adhesion compared to the existing agent and has outstanding resistance to the surface oxidization of metal relics and water repellent on the surface. In addition, the agent is considered a stable coating agent replacing current acrylic coating agent with showing easy dissolution in organic solvents such as acetone, toluene and xylene with excellent result in reversible reaction.

A Study on the Working Clothes for Korea Railroad -Focused on Winter Upper Garment- (한국철도공사 작업복에 관한 연구 (제1보) -동복 상의를 중심으로-)

  • Kim, Ji-Won;Choi, Hei-Sun;Ryou, Heun-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.2
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    • pp.308-318
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    • 2009
  • The purpose of this study was to develop the functionally improved winter work clothing for the Korean railroad workers. Based on the questionnaires, the sample clothing for the Korean railroad workers was produced. The design, materials, and patterns were modified to increase mobility and comfort of workers. Water-repellent treatment was added to the material in order to decrease the dirt and stains while working. Also the reflective strips were added to chest and back of the upper garment in order to increase visibility and safety of the workers. In terms of the design and pattern underarm of the sleeve and side panel of the bodice were put in together and action pleats at the back were inserted in order to decrease the pullback of the armpit and scapular area and increase mobility of the arm movement. Also the patterns of the elbows areas were modified to increase mobility of joint. The prototype was evaluated an objective assessment and subjective assessment to compare to the existing working uniform. Assessment group was consisted of 5 subject groups and 11 expert groups and evaluated external appearance and adaptability to the movements. According to the results, the prototype was evaluated better than the existing working uniform in appearance and adaptability except height of collar. A field test was conducted to compare the prototype and the existing working uniform. The field tests were performed by 6 workers in the Korean railroad. According to the results, the prototype was improved in terms of adaptability and comfort.

Effect of fabric Sound from Active Wear on Electrodiagnosis and Subjective Sensation and Sensibility (스포츠웨어용 직물의 소리특성이 근전도와 주관적 감각 . 감성에 미치는 영향)

  • 정혜진;김춘정;조길수
    • Science of Emotion and Sensibility
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    • v.6 no.1
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    • pp.27-32
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    • 2003
  • The objectives of this study the effects of fabric noise from active wear on electrodiagnosis(EMG), to examine the effects on subjective sensation, and to relate the EMG results and the subjective sensation.. Five nylon water repellent taffeta fabrics were rubbed each other and the fabric noise were recorded. EMG was done from 10 female university students and electrodes were attached on each participant's upper arm and lower am. The subjective sensation was measured by FMME(Free Modulus Magnitude Estimation). The EMG values from upper arm showed higher voltage than those from lower arm, and the differences between values with fabric sound and without were larger at upper arm than those at lower am. EMG decreased when fabric sound was evaluated soft and pleasant, however It increased in proportion as fabric sound was evaluated loud and sharp. The predicted models for subjective sensation using physical sound properties and EMG results were well explained except roughness. Pleasantness was well predicted by EMG at upper am and EMG at lower arm, as the result, it was explained that the lower the EMG, the more pleasant the participant.

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A Study on Work Clothes for Korea Railroad (Part II) - Focused on Winter Pants - (한국철도공사 작업복에 관한 연구 (제2보) - 동복 하의를 중심으로 -)

  • Kim, Ji-Won;Ryou, Heun-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.3
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    • pp.410-419
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    • 2009
  • The purpose of this study was to develop the functionally improved winter work clothing for the Korean railroad workers. Based on the questionnaires, sample clothing for the Korean railroad workers was produced. The design, materials, and patterns were modified to increase mobility and comfort for workers. Water-repellent treatment was added to the material in order to decrease the dirt and stains while working. Also, reflective strips were added to side seams and hems of the trousers in order to increase the visibility and safety of the workers. In terms of the design and pattern, a circumference of 4.5cm was added to the crotch area in order to minimize tightness on the hip and crotch areas, but no additional circumference was added to the hip area. And a 1cm width dart was inserted between the side seams and yoke in order to add activity. Also three 1.4cm width tucks were used at 2.5cm space on the knees to alleviate tightness at the knees. The prototype was evaluated objectively and subjectively to compare with the existing working uniform. The assessment group consisted of 5 subject groups and 11 expert groups to evaluate external appearance and adaptability of the movements. Subject and panels were asked to evaluate the prototype that followed an ergonomic design and pattern. According to the results, the prototype was evaluated better than the existing working uniform in appearance and adaptability. A field test was conducted to compare the prototype and the existing working uniform. The field tests were performed by 6 workers in the Korean railroad. According to the results, the prototype advanced in terms of adaptability and comfort.

Influence of Painting Materials based on Wasted Oil and Applying Timing on Carbonation and Chloride Resistances of High Volume SCM Concrete (폐유지류를 중심으로 한 도포제 종류 및 도포시기 변화가 혼화재 다량치환 콘크리트의 탄산화 및 염해저항성에 미치는 영향)

  • Han, Cheon-Goo;Choi, Young-Doo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.228-236
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    • 2015
  • In this research, the influence of painting materials and applying timing on carbonation and chloride resistances of high volume SCMs concrete was evaluated. As a durability improving method, comparative tests were conducted with painting materials of ERCO (emulsified refined cooking oil), RCO (refined cooking oil), WR (water repellent agent), and ERCO + WR and with painting timings of right after demolding, and 28 days after the wet curing. From the experiment results, in the case of carbonation and chloride resistance, the carbonation depth and chloride penetration depth were decreased when the painting materials were applied in 28 days of wet curing. Additionally, for painting materials, with the order of ERCO, RCO, ERCO+WR, and WR, the carbonation and chloride penentration was delayed. Hence it is considered that ERCO shows the most favorable performance of resistance against carbonation and chloride penetration.

A Study on the Carbonation Characteristics of ALC (ALC의 탄산화 특성에 관한 연구)

  • Seo, Sung Kwan;Chu, Yong Sik;Park, Soo Hyun;Song, Hun;Lee, Jong Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.70-76
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    • 2012
  • For Analysis and evaluation of ALC carbonation, ALC with various specific gravity was fabricated and silicate and siloxane were used for spraying on ALC surface. Silicon oil of water repellent was added to ALC slurry. ALC carbonation related with specific gravity and carbonation degree was decreased with specific gravity. It was guessed that permeation of $CO_2$ gas reduced depend on compact structure of ALC. ALC which sprayed silicate and siloxane represented more excellent carbonation resistance than Ref. ALC. ALC added silicon oil represented most excellent carbonation resistance.

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Conservation Study of Stones by Using Acrylic Monomer (아크릴계 단량체를 이용한 석조물의 보존처리 연구)

  • Kang, Sang-Yong;Suh, Man-Cheol;Kim, Un-Young;Kim, Hyung-Joong
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.213-218
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    • 2008
  • About 17% of historical properties in Korea were made of stones and most of them are exposed to weathering, as such that discoloring, cracking, and shattering occur from physical, chemical, mechanical, and biological effects due to outdoor placement. Proper treatments for conservation are necessary to prevent the weathering damage and to retain the original shape of stones. MMA, an acrylic monomer having low viscosity can be impregnated deep inside stones by consecutive compression and decompression process in a pressurized vessel. After the polymerization of MMA impregnate, the space inside of the stone was filled with PMMA. It is expected that water repellent and weather resistant properties will be improved because of the improved bonding of constituent materials in stones. In this study, moisture absorption, chemical resistance, and mechanical property of two domestic granites were examined after treating them with MMA for the purpose of determining the conservation value of this method that was possibly useful to the conservation of stone cultural assets.

Microstructure Analysis of Cement Composite containing PMHS Emulsion to Improve Hydrophobic (소수성 증진을 위한 PMHS 유액 혼입 시멘트 복합체의 미세구조 분석)

  • Kim, Younghwan;Oh, Hongseob
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.25-32
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    • 2021
  • For developing the durable eco-concrete, water-repellent and hydrophobic emulsion were prepared by stirring and mixing polymethyl hydrosiloxane and polyvinyl alcohol. After adding the PMHS emulsion cement paste, the hydration reaction characteristics and the change in chemical composition were analyzed through BSE and EDS analysis, and the micropores were evaluated by MIP test. Cement mixed with PMHS emulsion was analyzed to increase the hydration reactivity and to decrease the capillary porosity, but it was found that the capillary porosity varies depending on the degree of dispersion of the emulsion in the cement paste. In the case of the emulsion containing metakaolin, there was little difference in hydration degree and porosity from the case of using only the PMHS emulsion. However, when the cement surface was coated with PMHS emulsion, the contact angle was found to increase significantly compared to OPC, and it was analyzed that especially when PVA fiber was used together, it changed to a hypohydrophobic surface.

Case Study on the Treatment of Acid Rock Drainage from an Embankment with Pyrite Rocks (황철석 암버럭을 이용한 고속도로 성토체의 산성배수 처리 사례 연구)

  • Gong, Jeong-Sik;Kim, Tae-Hyung;Song, Young-Suk
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.523-532
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    • 2021
  • The treatment of acid rock drainage was reviewed and evaluated for the case of pyrite rocks distributed in a highway embankment. During the highway's construction, neutralization using alkaline water repellent was applied to the embankment section to prevent acid rock drainage. However, it still occurred long after the construction was completed owing to rain infiltration, and the acid rock drainage polluted the surrounding soils and streams. To solve this problem, treatment facilities such as SAPS (Successive Alkalinity Producing Systems) or ecological wetlands and sand filtration were installed. After the installation of the treatment facilities, the effluent and soils contaminated by acid rock drainage nearby the outlet of the facilities were analyzed and evaluated for a period of years. Measurements of the pH of the effluent and analysis of the heavy metal contamination of the soils confirmed that the neutralization treatment for acid rock drainage is being performed properly and that contamination of heavy metals in the acid rock drainage is also being stably controlled by the treatment facilities.